| Identification | More | [Name]
Triisopropyl borate | [CAS]
5419-55-6 | [Synonyms]
BORIC ACID TRIISOPROPYL ESTER
BORON ISOPROPOXIDE
BORON TRI-I-PROPOXIDE
ISOPROPYL BORATE
TIPB
TRI-I-PROPYLBORATE
TRIISOPROPOXYBORANE
TRIISOPROPYL BORATE
Boric acid (H3BO3), triisopropyl ester
Boric acid, tris(1-methylethyl) ester
boricacid(h3bo3),tris(1-methylethyl)ester
boricacid,tris(1-methylethyl)ester
boricacidtrilsopropylester
boricacidtris(1-methylethyl)ester
borontriisopropoxide
Isopropyl borate, ((C3H7O)3B)
Triisopropoxyboron
triisopropylorthoborate
trisisopropoxyborane
Boric acid triisopropyl ester~Isopropyl borate | [EINECS(EC#)]
226-529-9 | [Molecular Formula]
C9H21BO3 | [MDL Number]
MFCD00008872 | [Molecular Weight]
188.07 | [MOL File]
5419-55-6.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless liquid | [Melting point ]
-59 °C
| [Boiling point ]
139-141 °C (lit.) | [density ]
0.815 g/mL at 25 °C(lit.)
| [vapor pressure ]
76 mm Hg ( 75 °C)
| [refractive index ]
n20/D 1.376(lit.)
| [Fp ]
62.6 °F
| [storage temp. ]
Flammables area | [solubility ]
Miscible with ether, ethanol, isopropanol and benzene. | [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
0.815 | [Water Solubility ]
decomposes | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [Detection Methods]
GC,NMR | [BRN ]
1701469 | [InChI]
1S/C9H21BO3/c1-7(2)11-10(12-8(3)4)13-9(5)6/h7-9H,1-6H3 | [InChIKey]
NHDIQVFFNDKAQU-UHFFFAOYSA-N | [SMILES]
CC(C)OB(OC(C)C)OC(C)C | [CAS DataBase Reference]
5419-55-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Boric acid (h3bo3), tris(1-methylethyl) ester(5419-55-6) | [Storage Precautions]
Moisture sensitive;Store under nitrogen | [EPA Substance Registry System]
5419-55-6(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Danger | [Hazard statements ]
H225 | [Precautionary statements ]
P210-P233-P240-P241-P242-P243 | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable. | [Safety Statements ]
S7:Keep container tightly closed .
S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S33:Take precautionary measures against static discharges .
S9:Keep container in a well-ventilated place . | [RIDADR ]
UN 2616 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
ED5950000
| [F ]
10-21 | [TSCA ]
T | [REACH Registrations]
Active | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29209085 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 2 |
| Hazard Information | Back Directory | [General Description]
A colorless liquid. Flash point 93°F. Less dense than water and insoluble in water. Vapors heavier than air. Used to make other chemicals. | [Reactivity Profile]
Borates, such as TRIISOPROPYL BORATE(5419-55-6), behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides. | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Health Hazard]
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | [Chemical Properties]
clear colourless liquid | [Uses]
Triisopropyl borate is used as reagent in Pd-catalyzed coupling reaction with aryl halides such as Suzuki reaction. It is used as a reagent for the preparation of the boronic acids and esters; as a Lewis acid catalyst and involved in the ortho-borylation of 1-substituted naphthalenes. Furthermore, it plays an important role as a catalyst for the production of resins, waxes, paints and varnishes. | [Synthesis]
Triisopropyl borate is produced by reacting sodium borohydride and isopropyl alcohol with carbon dioxide in a trickle-bed reactor, followed by distillation to obtain a pure product stream[1]. | [References]
[1]Geranios, K., Everett, P., Mei, P., Roll, M., & Bernards, M. (2022). Carbon Dioxide Conversion to Sodium Formate and Valuable Byproduct. 2022 Waste-management Education Research Conference (WERC), 3, 1–11. https://doi.org/10.1109/werc54916.2022.9851364
|
|
| Company Name: |
MINS GROUP CO.,LIMITED Gold
|
| Telephone: |
0533-4915568 18653327685 |
| Website: |
http://www.minschem.com |
| Company Name: |
shandongxinheng Gold
|
| Telephone: |
1526-9161022 15269161022 |
| Website: |
https://www.chemicalbook.com/supplier/25741341/ |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|