| Identification | More | [Name]
Ethyl 4-bromobenzoate | [CAS]
5798-75-4 | [Synonyms]
4-BROMOBENZOIC ACID ETHYL ESTER
ETHYL 4-BROMOBENZOATE
ETHYL P-BROMOBENZOATE
RARECHEM AL BI 0075
4-bromo-benzoicaciethylester
Benzoic acid, p-bromo-, ethyl ester
p-(Ethoxycarbonyl)phenyl bromide
Ethyl 4-bromobenzoate, 98+%
Ethyl 4-bromobenzoate 99+%
4-BROMOBENZOIC ACID ETHYL ESTER 98+%
4-(Ethoxycarbonyl)phenyl bromide | [EINECS(EC#)]
227-347-2 | [Molecular Formula]
C9H9BrO2 | [MDL Number]
MFCD00016329 | [Molecular Weight]
229.07 | [MOL File]
5798-75-4.mol |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Benzoic acid, 4-[[(trifluoromethyl)sulfonyl]oxy]-, ethyl ester-->2-(4-Bromophenyl)-2-oxoacetic acid-->4-Bromobenzyl alcohol-->(4-Bromo-phenyl)-oxo-acetaldehyde-->Benzenediazonium, 4-(ethoxycarbonyl)-, tetrafluoroborate(1-)-->1-Carbethoxyimidazole-->potassium ethyl oxalate-->4-Bromobenzaldehyde diethyl acetal | [Preparation Products]
Ethyl 4-acetylbenzoate-->4-Ethynyl-benzoic acid-->Ethyl 4-(5-formyl-2-furyl)benzoate-->2-(4-bromophenyl)-1,3,4-oxadiazole-->Ethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate-->4,4'-Bis(hydroxymethyl)biphenyl-->Ethyl 4-etoxybenzoate-->1,1,1-Trifluoro-2-hexanone |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to yellow liquid | [Uses]
Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported. | [Synthesis Reference(s)]
Synthetic Communications, 22, p. 1851, 1992 DOI: 10.1080/00397919208021316
Synthesis, p. 191, 1983 | [General Description]
Ethyl 4-bromobenzoate is an ester having electron-withdrawing substituent. It undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported. |
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