| Identification | More | [Name]
2-Methyl-3-nitroaniline | [CAS]
603-83-8 | [Synonyms]
1-AMINO-2-METHYL-3-NITROBENZENE
2-AMINO-6-NITROTOLUENE
2-METHYL-3-NITROANILINE
2-NITRO-6-AMINOTOLUENE
3-NITRO-O-TOLUIDINE
6-NITRO-2-AMINO TOLUENE
BENZENAMINE, 2-METHYL-3-NITRO-
LABOTEST-BB LTBB000622
2-Methy-3-nitroaniline
o-Toluidine, 3-nitro-
2-Methyl-3-nitro-phenylamine
ORTHO-TOLUIDINE,3-NITRO-
3-NITRO-ORTHO-TOLUIDINE
2-methyl-3-nitro-benzenamin
3-nitro-o-toluidin
2-METHYL-3-NITROANILINE/2-AMINO-6-NITROTOLUENE
3-Nitro-o-toluidine (NH2=1)
2-methyl-3-nitrobenzenamine
1-AMINIO-2METHYL-3-NITROBENZENE
2-Amino-6-nitrotoluene, 3-Nitro-o-toluidine | [EINECS(EC#)]
210-059-6 | [Molecular Formula]
C7H8N2O2 | [MDL Number]
MFCD00007731 | [Molecular Weight]
152.15 | [MOL File]
603-83-8.mol |
| Chemical Properties | Back Directory | [Appearance]
YELLOW TO GREENISH-YELLOW CRYSTALLINE POWDER | [Melting point ]
88-90 °C (lit.) | [Boiling point ]
305 °C (lit.) | [density ]
1.378 | [refractive index ]
1.6394 (estimate) | [Fp ]
305°C | [storage temp. ]
Store below +30°C. | [solubility ]
<1mg/l | [form ]
Crystalline Powder | [pka]
2.31±0.10(Predicted) | [color ]
Yellow to greenish-yellow | [Water Solubility ]
<0.1 g/100 mL at 23 ºC | [BRN ]
388393 | [InChI]
1S/C7H8N2O2/c1-5-6(8)3-2-4-7(5)9(10)11/h2-4H,8H2,1H3 | [InChIKey]
HFCFJYRLBAANKN-UHFFFAOYSA-N | [SMILES]
Cc1c(N)cccc1[N+]([O-])=O | [CAS DataBase Reference]
603-83-8(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Methyl-3-nitroaniline(603-83-8) | [EPA Substance Registry System]
603-83-8(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS06,GHS08,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H301+H311+H331-H373-H410 | [Precautionary statements ]
P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314 | [Hazard Codes ]
T,N | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2660 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
XU8200000
| [Hazard Note ]
Toxic | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29214300 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 2
STOT RE 2 |
| Hazard Information | Back Directory | [General Description]
Yellow rhombic needles (from water) or bright yellow powder. | [Reactivity Profile]
2-METHYL-3-NITROANILINE(603-83-8) is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers. | [Air & Water Reactions]
This chemical may be sensitive to prolonged exposure to air. Insoluble in water. | [Fire Hazard]
Flash point data for this chemical are not available; however, 2-METHYL-3-NITROANILINE is probably combustible. | [Chemical Properties]
YELLOW TO GREENISH-YELLOW CRYSTALLINE POWDER | [Uses]
2-Amino-6-nitrotoluene (2-Methyl-3-nitroaniline) has been used as a standard while evaluating the potential for degradation of nitroaromatic compounds by indigenous microorganisms. | [Production Methods]
6-Nitro-o-toluidine is produced by sulfide reduction of 2,6-dinitrotoluene in a process similar to that for 3-nitroaniline or by controlled hydrogenation of 2,6-dinitrotoluene with palladium on a carbon catalyst. | [Purification Methods]
Crystallise the nitrotoluidine from EtOH or *C6H6. It is steam volatile. The acetyl derivative crystallises from aqueous EtOH and has m 164o. [Beilstein 12 I 395, 12 II 460, 12 III 1944, 2 IV 1811.] |
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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