| Identification | More | [Name]
2-Indanone | [CAS]
615-13-4 | [Synonyms]
2-INDANONE
2-OXOINDANE
BETA-HYDRINDONE
Indan-2-one
INDANONE(2-)
1,3-dihydro-2h-inden-2-on
1,3-Dihydro-2H-inden-2-one
2H-Inden-2-one,1,3-dihydro-
2-Hydrindone
2-Oxohydrindene
2-lndanone
2-Indanone,98%
Indan-2-one 98%
1H-inden-2(3H)-one
2-INDANONE pure | [EINECS(EC#)]
210-410-3 | [Molecular Formula]
C9H8O | [MDL Number]
MFCD00003792 | [Molecular Weight]
132.16 | [MOL File]
615-13-4.mol |
| Chemical Properties | Back Directory | [Appearance]
Wet crystalline aggregates | [Melting point ]
51-54 °C (lit.) | [Boiling point ]
218°C | [density ]
1.0712 | [refractive index ]
1.5380 (estimate) | [Fp ]
212 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Crystals or Powder | [color ]
Light yellow to yellow-brown | [Specific Gravity]
1.07 (liquid) | [Odor]
moderately tenacious odor | [Odor Threshold]
0.00036ppm | [Water Solubility ]
insoluble | [Sensitive ]
Hygroscopic | [BRN ]
636550 | [InChI]
1S/C9H8O/c10-9-5-7-3-1-2-4-8(7)6-9/h1-4H,5-6H2 | [InChIKey]
UMJJFEIKYGFCAT-UHFFFAOYSA-N | [SMILES]
O=C1Cc2ccccc2C1 | [LogP]
1.230 (est) | [CAS DataBase Reference]
615-13-4(CAS DataBase Reference) | [NIST Chemistry Reference]
2H-inden-2-one, 1,3-dihydro-(615-13-4) | [EPA Substance Registry System]
615-13-4(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H315-H319-H335 | [Precautionary statements ]
P261-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [RTECS ]
NK7535500
| [F ]
3 | [Hazard Note ]
Irritant | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29143900 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
Wet crystalline aggregates or needle-like crystals (formed by ethanol or ether) evaporate when in contact with water vapor. These crystals have a melting point range of 58-61 ℃ and a flash point of 100 ℃. Indene compounds are commonly found in numerous natural products, exhibiting diverse physiological activities and serving as crucial intermediates in organic synthesis processes. | [Uses]
2-Indanone(615-13-4) undergoes TiCl4-Mg mediated coupling with CHBr3 to yield dibromomethyl carbinol. It reacts with 5,5-dimethyl-3-pyrazolidinone to yield 5,5-dimethyl-2-(1H-indenyl-2)-3-pyrazolidinone. On photolysis by 266-nm one-photon excitation yields o-xylylene. It was used as starting reagent in the synthesis of indene-fused porphyrins.
| [Application]
2-Indanone is mentioned mainly for the completion and illustration of the series in which dpila- and be{u-Hydrindone have been emphasized as having potential interest in the perfume industry. It is the author's impression that the two materials are not used in perfumes or flavors.
| [Definition]
ChEBI: 2-Indanone is an indanone with an oxo substituent at position 2. It is a metabolite of indane. It has a role as a xenobiotic metabolite. 2-Indanone is an intermediate for the preparation of aprindine hydrochloride and ceforanide. It is an important intermediate in organic synthesis. | [Preparation]
2-Indanone is prepared by using acetic acid as solvent, acetic anhydride as catalyst and through hydrogen peroxide oxidation into 1, 2-indenediol, which reacted with dilute sulfuric acid solution in order to obtain crude 2-indanone. Finally, vacuum sublimation to obtain 2-indanone with high-purity, the total yield is 89%. | [Synthesis Reference(s)]
Chemistry Letters, 11, p. 325, 1982
Organic Syntheses, Coll. Vol. 5, p. 647, 1973
Tetrahedron Letters, 15, p. 3789, 1974 DOI: 10.1016/S0040-4039(01)92010-6 | [General Description]
2-Indanone undergoes TiCl4-Mg mediated coupling with CHBr3 to yield dibromomethyl carbinol. It reacts with 5,5-dimethyl-3-pyrazolidinone to yield 5,5-dimethyl-2-(1H-indenyl-2)-3-pyrazolidinone. 2-Indanone on photolysis by 266-nm one-photon excitation yields o-xylylene. |
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