ChemicalBook--->CAS DataBase List--->6893-26-1

6893-26-1

6893-26-1 Structure

6893-26-1 Structure
IdentificationMore
[Name]

D(-)-Glutamic acid
[CAS]

6893-26-1
[Synonyms]

D-2-AMINOGLUTARIC ACID
D-2-AMINOPENTANEDIOIC ACID
D-ALPHA-AMINOGLUTARIC ACID
D-GLU
D-(-)-GLUTAMIC ACID
D-GLUTAMIC ACID
GLUTAMIC ACID, D-
H-D-GLU-OH
(R)-1-AMINOPROPANE-1,3-DICARBOXYLIC ACID
(R)-2-AMINOGLUTARIC ACID
[R]-2-AMINOPENTANEDIOIC ACID
(R)-GLUTAMIC ACID
d-glutamic
d-glutamicaci
D-Glutaminic acid
D-GLUTAMIC ACID, 99+%
(2R)-2-aminopentanedioic acid
D-Glutamate
D-Glutaminsure
D-GLUCURONOLACTONE
[EINECS(EC#)]

230-000-8
[Molecular Formula]

C5H9NO4
[MDL Number]

MFCD00063112
[Molecular Weight]

147.13
[MOL File]

6893-26-1.mol
Chemical PropertiesBack Directory
[Appearance]

White cryst. powder
[Melting point ]

200-202 °C (subl.)(lit.)
[alpha ]

-31.3 º (c=10, 2 N HCl)
[Boiling point ]

267.21°C (rough estimate)
[density ]

1.5380
[refractive index ]

1.4210 (estimate)
[storage temp. ]

Store at RT.
[solubility ]

Water (Slightly)
[form ]

Powder
[pka]

pK1:2.162(+1);pK2:4.272(0);pK3:9.358(-1) (25°C)
[color ]

White to off-white
[Water Solubility ]

7 g/L (20 ºC)
[Merck ]

14,4469
[BRN ]

1723800
[InChI]

1S/C5H9NO4/c6-3(5(9)10)1-2-4(7)8/h3H,1-2,6H2,(H,7,8)(H,9,10)/t3-/m1/s1
[InChIKey]

WHUUTDBJXJRKMK-GSVOUGTGSA-N
[SMILES]

N[C@H](CCC(O)=O)C(O)=O
[LogP]

-0.969 (est)
[CAS DataBase Reference]

6893-26-1(CAS DataBase Reference)
[NIST Chemistry Reference]

D-Glutamic acid(6893-26-1)
[EPA Substance Registry System]

6893-26-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

10
[TSCA ]

Yes
[HS Code ]

29224290
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

DL-Glutamic acid-->4-methylsulfanyl-2-oxo-butanoic acid-->3-(4-Imidazolyl)-2-oxopropionic acid-->D-Norleucine-->D(-)-Norvaline-->D-Histidine-->D-Glutamine-->D-Methionine-->2-Oxopentanoic acid-->3-Methyl-2-oxobutyric aciddiscontinued-->2-oxohexanoic acid-->D-Threonine-->L-Glutamic acid
[Preparation Products]

5-Hydroxymethylpyrrolidin-2-one-->D-Pyroglutamic acid-->2-Oxobutyric acid-->4-Methyl-2-oxovaleric acid-->2-Ketoglutaric acid-->L-Leucine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

D-2-Aminoglutaric acid(6893-26-1).msds
Hazard InformationBack Directory
[Chemical Properties]

White cryst. powder
[Uses]

D-Glutamic Acid is the unnatural (R)-enantiomer of Glutamic Acid, a non-essential amino acid. Its salt form (glutamate) is an important neurotransmitter that plays a key role in long-term potentiation and is important for learning and memory. Glutamic Acid is also a key molecule in cellular metabolism.
[Definition]

ChEBI: An optically active form of glutamic acid having D-configuration.
[General Description]

D-Glutamic acid is an essential constituent of the bacterial peptidoglycan structure. It is added to UDP-N-acetylmuramyl-L-alanine (UDP-MurNAc-L-alanine) by the enzyme D-glutamic acid-adding enzyme (murD). This is, then, incorporated into the peptidoglycan precursor. Peptidoglycan makes up the cell walls of Gram-positive and -negative bacteria. The conversion of L-glutamate to D-glutamate by glutamate racemase (GR) enzyme is an essential step in the synthesis of peptidoglycan.
[Biological Activity]

Excitatory amino acid acting at NMDA receptors; less active than the L-isomer.
[Biochem/physiol Actions]

Unnatural isomer of glutamic acid.
[storage]

Room temperature
Spectrum DetailBack Directory
[Spectrum Detail]

D(-)-Glutamic acid(6893-26-1)MS
D(-)-Glutamic acid(6893-26-1)1HNMR
D(-)-Glutamic acid(6893-26-1)IR1
D(-)-Glutamic acid(6893-26-1)IR2
D(-)-Glutamic acid(6893-26-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D(-)-Glutamic acid, 99+%(6893-26-1)
[Alfa Aesar]

D-Glutamic acid, 99+%(6893-26-1)
[Sigma Aldrich]

6893-26-1(sigmaaldrich)
[TCI AMERICA]

D-Glutamic Acid,>98.0%(T)(6893-26-1)
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