| Identification | More | [Name]
4-Methylpyridin-2-amine | [CAS]
695-34-1 | [Synonyms]
2-AMINO-4-METHYLPYRIDINE
2-AMINO-4-PICOLINE
4-METHYL-2-PYRIDYLAMINE
4-METHYLPYRIDIN-2-AMINE
4-METHYL-PYRIDIN-2-YLAMINE
AKOS 91145
AKOS BBS-00004343
AURORA 11319
OTAVA-BB BB7015122364
SODIUM BICHROMATE
SODIUM BICHROMATE DIHYDRATE
SODIUM DICHROMATE
SODIUM DICHROMATE 2H2O
SODIUM DICHROMATE-2-HYDRATE
SODIUM DICHROMATE DIHYDRATE
SODIUM DICHROMATE, HYDROUS
TIMTEC-BB SBB004354
2-amino-4-methyl-pyridin
2-amino-4-picolin
2-Amino-gamma-picoline | [EINECS(EC#)]
234-190-3 | [Molecular Formula]
Cr2H4Na2O9 | [MDL Number]
MFCD00149166 | [Molecular Weight]
298 | [MOL File]
695-34-1.mol |
| Chemical Properties | Back Directory | [Appearance]
Light yellow to brown flakes | [Melting point ]
96-99 °C (lit.) | [Boiling point ]
230 °C (lit.) | [density ]
1.0275 (estimate) | [refractive index ]
1.5560 (estimate) | [Fp ]
118 °C
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
DMF: freely soluble | [form ]
Flakes | [pka]
pK1: 7.48(+1) (25°C) | [color ]
Slightly yellow to beige or brown | [Water Solubility ]
SOLUBLE | [Sensitive ]
Hygroscopic | [Detection Methods]
HPLC,GC,NMR | [Merck ]
14,466 | [BRN ]
107066 | [CAS DataBase Reference]
695-34-1(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Pyridinamine, 4-methyl-(695-34-1) | [Storage Precautions]
Moisture sensitive | [EPA Substance Registry System]
695-34-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R45:May cause cancer.
R60:May impair fertility.
R61:May cause harm to the unborn child.
R8:Contact with combustible material may cause fire.
R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R26:Very Toxic by inhalation.
R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
R48/23:Toxic: danger of serious damage to health by prolonged exposure through inhalation .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
R33:Danger of cumulative effects.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 3086 6.1/PG 1
| [WGK Germany ]
3
| [RTECS ]
TJ5150000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29333999 | [Toxicity]
LD50 oral in rat: 200mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
Light yellow to brown flakes | [Uses]
Intermediate, medicine. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 72, p. 4554, 2007 DOI: 10.1021/jo070189y | [General Description]
2-Amino-4-methylpyridine acts as ligand and forms methoxo-bridged copper(II) complexes. | [Biochem/physiol Actions]
2-Amino-4-methylpyridine inhibits the activity of inducible NO synthase isolated from mouse RAW 264.7 cells in vitro. | [Purification Methods]
Crystallise it from EtOH or a 2:1 *benzene/acetone mixture, and dry it under vacuum as in the prevous entry. [Beilstein 22/9 V 325.] |
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