ChemicalBook--->CAS DataBase List--->699-83-2

699-83-2

699-83-2 Structure

699-83-2 Structure
IdentificationMore
[Name]

2',6'-Dihydroxyacetophenone
[CAS]

699-83-2
[Synonyms]

1-(2,6-DIHYDROXYPHENYL)ETHAN-1-ONE
1-(2,6-DIHYDROXYPHENYL)ETHANONE
2',6'-DIHYDROXYACETOPHENONE
2,6-DIHYDROXYACETOPHENONE
2,6-DIHYDROXY ACETPHENONE
2-ACETYL-1,3-DIHYDROXYBENZENE
2-ACETYLRESORCINOL
DIHYDROXYACETOPHENONE(2,6-)
1,3-Benzenediol, 2-acetyl-
1-Acetyl-2,6-dihydroxybenzene
Acetophenone, 2',6'-dihydroxy-
Acetyl-2,6-dihydroxybenzene
Ethanone, 1-(2,6-dihydroxyphenyl)-
gamma-Resacetophenone
Resorcinol, 2-acetyl-
2',6'-Dihydroxyacetophenone 1-(2,6-Dihydroxyphenyl)ethan-1-one 2,6-Dihydroxyacetophenone
2,6-DIHYDROXYACETOPHENONE, MATRIX SUB-ST ANCE FOR MALDI-MS
2',6'-DIHYDROXYACETOPHENONE, PGE. WITH10 X 10 MG
9,10-Dihydroanthracene98%
9,10-Dihydroanthracene 98%
[EINECS(EC#)]

211-833-6
[Molecular Formula]

C8H8O3
[MDL Number]

MFCD00002270
[Molecular Weight]

152.15
[MOL File]

699-83-2.mol
Chemical PropertiesBack Directory
[Appearance]

yellowish-beige powder
[Melting point ]

156-158 °C(lit.)
[Boiling point ]

234.6°C (rough estimate)
[density ]

1.2143 (rough estimate)
[refractive index ]

1.4447 (estimate)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

dioxane: 50 mg/mL, clear
[form ]

Powder
[pka]

9.65±0.10(Predicted)
[color ]

Yellow-beige
[Water Solubility ]

sparingly soluble
[BRN ]

1366061
[InChI]

InChI=1S/C8H8O3/c1-5(9)8-6(10)3-2-4-7(8)11/h2-4,10-11H,1H3
[InChIKey]

YPTJKHVBDCRKNF-UHFFFAOYSA-N
[SMILES]

C(=O)(C1=C(O)C=CC=C1O)C
[LogP]

1.922 (est)
[CAS DataBase Reference]

699-83-2(CAS DataBase Reference)
[NIST Chemistry Reference]

2',6'-Dihydroxyacetophenone(699-83-2)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[REACH Registrations]

Active
[HS Code ]

29145000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

7-Acetoxy-4-methylcoumarin-->Ethanone, 1-[2,6-bis(acetyloxy)phenyl]--->2-acetyl-3-hydroxycyclohex-2-enone-->4,5-Dihydroxycoumarin-->1,3-di(methoxymethoxy)benzene-->2-Acetyl-1,3-cyclohexanedione-->1,3-Diacetoxybenzene-->8-Acetyl-7-hydroxy-4-methylcoumarin-->2,6-Dimethoxybenzonitrile-->2',6'-Dimethoxyacetophenone-->1,2-Dichlorobenzene-->Hydrogen Sulfide
[Preparation Products]

Cromolyn Disodium Salt-->5-Hydroxyflavone-->2'-Hydroxy-6'-methoxyacetophenone-->6'-Ethoxy-2'-hydroxyacetophenone 98
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-(2,6-Dihydroxyphenyl)ethan-1-one(699-83-2).msds
Hazard InformationBack Directory
[Chemical Properties]

yellowish-beige powder
[Uses]

2'',6''-Dihydroxyacetophenone (cas# 699-83-2) is a compound useful in organic synthesis.
[Definition]

ChEBI: 2',6'-Dihydroxyacetophenone is an aromatic ketone.
[Preparation]

Preparation by hydrolysis of 8-acetyl-4-methyl-umbelliferone (8-acetyl-7-hydroxy-4-methylcoumarin) with aqueous sodium hydroxide solution at reflux (56–73%).
Spectrum DetailBack Directory
[Spectrum Detail]

2',6'-Dihydroxyacetophenone(699-83-2)MS
2',6'-Dihydroxyacetophenone(699-83-2)1HNMR
2',6'-Dihydroxyacetophenone(699-83-2)13CNMR
2',6'-Dihydroxyacetophenone(699-83-2)IR1
2',6'-Dihydroxyacetophenone(699-83-2)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2',6'-Dihydroxyacetophenone, 99%(699-83-2)
[Alfa Aesar]

2',6'-Dihydroxyacetophenone, 98+%(699-83-2)
[Sigma Aldrich]

699-83-2(sigmaaldrich)
[TCI AMERICA]

2',6'-Dihydroxyacetophenone,>97.0%(T)(699-83-2)
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