ChemicalBook--->CAS DataBase List--->72178-02-0

72178-02-0

72178-02-0 Structure

72178-02-0 Structure
IdentificationMore
[Name]

Fomesafen
[CAS]

72178-02-0
[Synonyms]

5-[2-CHLORO-4-(TRIFLUOROMETHYL)PHENOXY]-N-(METHYLSULFONYL)-2-NITROBENZAMIDE
5-[2-Chloro-4-(trifluoromethyl)phenoxy]-N-(methylsulphonyl)-2-nitrobenzamide
FLEX
FLEX(R)
FLEXSTAR
FOMESAFEN
REFLEX
REFLEX(R)
5(2-chloro-alpha,alpha,alpha-trifluoro-p-tolyloxy)-n-mesyl-2-nitrobenzamide
5(2-chloro-alpha,alpha,alpha-trifluoro-p-tolyloxy)-n-methylsulfonyl-2-nitrobenz
amide
fomesafene
formesafen
pp021
5-(2-Chloro-4-trifluoromethylphenyloxy)-N-methylsulfonyl-2-nitrobenzoylamide
PP021(ICI)
fomesafen (ansi,bsi,iso)
Fomesafen
5-[2-chloro-4-(trifluoromethyl)phenoxy]-N-(methylsulphonyl)-2-nitrobenzamide fomesafen
Fomesafen aqua
[EINECS(EC#)]

276-439-9
[Molecular Formula]

C15H10ClF3N2O6S
[MDL Number]

MFCD01632756
[Molecular Weight]

438.76
[MOL File]

72178-02-0.mol
Chemical PropertiesBack Directory
[Appearance]

White crystalline solid or powder.
[Melting point ]

220-221°C
[density ]

1.7075 (rough estimate)
[refractive index ]

1.5660 (estimate)
[storage temp. ]

0-6°C
[solubility ]

Acetonitrile (Slightly), DMSO
[form ]

neat
[pka]

23-25(at 25℃)
[color ]

White to Off-White
[BRN ]

8165046
[CAS DataBase Reference]

72178-02-0(CAS DataBase Reference)
[EPA Substance Registry System]

72178-02-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
[Safety Statements ]

S2:Keep out of the reach of children .
[WGK Germany ]

1
[RTECS ]

CV2475000
[HS Code ]

29350090
[Hazardous Substances Data]

72178-02-0(Hazardous Substances Data)
[Toxicity]

LD50 orally in male, female rats (mg/kg): 1250-2000, 1600; LC50 (48, 96 hr.) in rainbow trout and bluegill (mg/l): 830, 680, 6740, 6030 (Colby)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Thionyl chloride-->Toluene-->Nitric acid-->Potassium carbonate-->Potassium hydroxide-->Ammonia-->Hydrogen peroxide-->Dimethyl sulfate-->Hydrogen fluoride-->Sodium thiosulfate-->Diphenyl ether-->PHOSGENE-->Sodium thiosulfate pentahydrate-->4-Chlorotoluene-->3-Hydroxybenzoic acid-->4-Chlorobenzotrifluoride-->2-Chlorobenzotrifluoride-->Acifluorfen-->3,4-Dichlorobenzotrifluoride-->cyanic acid-->5-Hydroxyanthranilic acid-->4-Chlorobenzotrichloride-->Methanesulfonamide-->2-Nitrobenzoic acid
Hazard InformationBack Directory
[General Description]

White crystalline solid. Used as an herbicide.
[Reactivity Profile]

FOMESAFEN is incompatible with acids.
[Potential Exposure]

Chlorophenoxy herbicide. After July 25, 2003, flumesafen was not permitted in many countries to be used as an active ingredient on crops except to con trol weeds in soybean crops, and white, kidney and snap beans. Limited use allowed in some European countries. Incompatibilities: Slowly hydrolyzes in water, releasing ammonia and forming acetate salts.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Do not induce vomiting when formulations containing petroleum solvents are ingested. Otherwise, give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Chemical Properties]

White crystalline solid or powder.
[Waste Disposal]

Do not discharge into drains or sewers. Dispose of waste material as a hazardous waste in a landfill approved and licensed for the disposal of pesti cides. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Uses]

Fomesafen is a protoporphyrinogen oxidae (PPO) inhibitor.
[Definition]

ChEBI: Fomesafen is an N-sulfonylcarboxamide that is N-(methylsulfonyl)benzamide in which the phenyl ring is substituted by a nitro group at position 2 and a 2-chloro-4-(trifluoromethyl)phenoxy group at position 5. A protoporphyrinogen oxidase inhibitor, it was specially developed for use (generally as the corresponding sodium salt, fomesafen-sodium) for post-emergence control of broad-leaf weeds in soya. It has a role as a herbicide, an agrochemical and an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor. It is an aromatic ether, a N-sulfonylcarboxamide, a C-nitro compound, an organofluorine compound, a member of monochlorobenzenes and a member of phenols. It is a conjugate acid of a fomesafen(1-).
[Agricultural Uses]

Herbicide: After July 25, 2003, flumesafen was not permitted in many countries to be used as an active ingredient on crops except to control weeds in soybean crops, and white, kidney and snap beans. Not approved for use in EU countries. Registered for use in the U.S.
[Trade name]

BAS 530 04®; FASTER®; FLEX®; FLEXSTAR; FOMESAFEN® SODIUM; PP 021®; REFLEX®; REFLEX® 2LC Herbicide (sodium salt); TORNADO®[C]; TWISTE®[C]; TYPHOON®
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Fomesafen(72178-02-0).msds
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

72178-02-0(sigmaaldrich)
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