| Identification | Back Directory | [Name]
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | [CAS]
72287-26-4 | [Synonyms]
PDCL2(DPPF)
(dppf)2PdCl2
dichloropalladiuM
[1,1′-Bis(diphenylph
(II)dichloromethane adduct
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropall
[1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI
-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
[1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium
[bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane
1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II)
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ)
1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride
[1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II)
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)
Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE
1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride
1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98%
1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99%
[1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9%
1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9%
1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd
(1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2
[1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
PdCl2(dppf)
1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2]
(1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL
Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)-
Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2
Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add
-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex
DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT
1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE
1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane
[1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II),
coMplex with dichloroMethane
[1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1)
dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1)
[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1)
1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane | [EINECS(EC#)]
460-040-3 | [Molecular Formula]
C34H28Cl2FeP2Pd 10* | [MDL Number]
MFCD00015757 | [MOL File]
72287-26-4.mol | [Molecular Weight]
731.7 |
| Chemical Properties | Back Directory | [Melting point ]
275-280 °C(lit.)
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Soluble in dichloromethane. | [form ]
powder | [color ]
red to very dark red | [Stability:]
Hygroscopic | [InChI]
InChI=1S/2C17H11P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2 | [InChIKey]
LMSWLYFMTLONFK-UHFFFAOYSA-L | [SMILES]
[Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-] |
| Questions And Answer | Back Directory | [Uses]
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors. |
| Hazard Information | Back Directory | [Chemical Properties]
Red solid | [Usage]
suzuki reaction | [Application]
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes. | [reaction suitability]
reagent type: catalyst
reaction type: Cross Couplings | [Mechanism of action]
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
R = usually sp2
hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed
| [Synthesis]
A method for the preparation of 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II (dppfPdCl2) comprising the steps of:
(a) adding palladium chloride to concentrated hydrochloric acid, heating to 40-80°C to dissolve, the amount of |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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