ChemicalBook--->CAS DataBase List--->74115-24-5

74115-24-5

74115-24-5 Structure

74115-24-5 Structure
IdentificationMore
[Name]

Clofentezine
[CAS]

74115-24-5
[Synonyms]

3,6-BIS(2-CHLOROPHENYL)-1,2,4,5-TETRAZINE
ACARISTOP(R)
APOLLO
APOLLO(R)
CLOFENTEZIN
CLOFENTEZINE
4,5-tetrazine,3,6-bis(2-chlorophenyl)-2
acaristop
apollo50w
apolo
appollo50sc
bisclofentazin
bisclofentazine
nc21314
Apollo? Apollo SC
Bis(2-chlorophenyl)-1,2,4,5-tetrazine
Panatac
3,6-bis(o-chlorophenyl)-1,2,4,5-tetrazine
Apollo(FBC)
CLOFENTEZIN PESTANAL (3,6-BIS(2-CHLOROP
[EINECS(EC#)]

277-728-2
[Molecular Formula]

C14H8Cl2N4
[MDL Number]

MFCD00143998
[Molecular Weight]

303.15
[MOL File]

74115-24-5.mol
Chemical PropertiesBack Directory
[Appearance]

Magenta crystalline solid
[Melting point ]

182-185 °C(lit.)
[Boiling point ]

457.37°C (rough estimate)
[density ]

1.3727 (rough estimate)
[refractive index ]

1.6300 (estimate)
[storage temp. ]

0-6°C
[solubility ]

Chloroform: Slightly Soluble
[form ]

neat
[pka]

-1.68±0.31(Predicted)
[color ]

Light yellow to yellow
[Water Solubility ]

2.522ug/L(temperature not stated)
[Merck ]

13,2398
[BRN ]

7137128
[Henry's Law Constant]

2.5×104 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
[Major Application]

agriculture
environmental
[InChI]

1S/C14H8Cl2N4/c15-11-7-3-1-5-9(11)13-17-19-14(20-18-13)10-6-2-4-8-12(10)16/h1-8H
[InChIKey]

UXADOQPNKNTIHB-UHFFFAOYSA-N
[SMILES]

Clc1ccccc1-c2nnc(nn2)-c3ccccc3Cl
[LogP]

3.100
[CAS DataBase Reference]

74115-24-5(CAS DataBase Reference)
[EPA Substance Registry System]

74115-24-5(EPA Substance)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

UN 3077 9 / PGIII
[WGK Germany ]

3
[RTECS ]

XF6860000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 1
[Toxicity]

LD50 in rats, mice (mg/kg): >3200 orally; LC50 (96 hr) in rainbow trout: 100 mg/l (Bryan)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Tetrahydrofuran-->Acetic acid-->Sodium nitrite-->Hydrogen peroxide-->Chlorine-->Hydrazinium hydroxide solution-->Phenylhydrazine-->2-Chlorobenzaldehyde-->2-Chlorobenzoyl chloride
Hazard InformationBack Directory
[Potential Exposure]

Tetrazine miticide used on a wide variety of cropsfruit, cereals, rangeland, ornamentals, etc. An EPA Restricted Use Pesticide (RUP).
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required
[Incompatibilities]

Oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); strong acids. Decomposes above 185°C
[Description]

Clofentazine is a selective insecticide used to control mites. It has a low aqueous solubility and is not volatile. It is moderately persistent in soil systems but tends not to be in aquatic systems. Based on its physico-chemical properties it is not expected to leach to groundwater. Clofentazine is highly toxic to birds and fish and moderately toxic to aquatic invertebrates, honeybees and earthworms. It has a low mammalian toxicity.
[Chemical Properties]

Magenta crystalline solid
[Waste Disposal]

Do not discharge into drains or sewers. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Uses]

Clofentezine is a mite growth regular and an tetrazine based acaricide. Clofentezine is used in agriculture for the protection of ornamentals, food and non-food crops in the field.
[Uses]

Pesticide.
[Definition]

ChEBI: A tetrazine that is 1,2,4,5-tetrazine in which both of the hydrogens have been replaced by o-chlorophenyl groups.
[Production Methods]

Clofentezine is produced commercially through a multi-step chemical synthesis involving chlorination, oxidation, and condensation reactions. The process typically begins with the chlorination of an aromatic precursor to introduce chlorine atoms at specific positions. This is followed by an oxidation step to prepare the intermediate compounds necessary for the final condensation reaction. The condensation step involves combining these intermediates under controlled conditions to form clofentezine.
[Agricultural Uses]

Miticide: A U.S. EPA restricted Use Pesticide (RUP). Used on a wide variety of crops – fruit, cereals, rangeland, ornamentals, etc
[Trade name]

APOLLO®; OVATION®
[Mechanism of action]

Specific with contact action and long residual activity. Mite growth inhibitor affecting CHS1.
[storage]

Store at -20°C
[Pesticide Type]

Acaricide; Insecticide
Spectrum DetailBack Directory
[Spectrum Detail]

Clofentezine(74115-24-5)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

74115-24-5(sigmaaldrich)
74115-24-5 suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Chemsky(shanghai)International Co.,Ltd.  
Telephone: 021-50135380
Website: www.shchemsky.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Chengdu Ai Keda Chemical Technology Co., Ltd.  
Telephone: 4008-755-333 18080918076
Website: http://www.aikeshiji.com
Company Name: Haoyuan Chemexpress Co., Ltd.  
Telephone: 021-58950125
Website: http://www.chemexpress.com.cn
Company Name: 9ding chemical ( Shanghai) Limited  
Telephone: 4009209199
Website: www.9dingchem.com
Company Name: Shanghai Aladdin Bio-Chem Technology Co.,LTD  
Telephone: 400-6206333 13167063860
Website: www.aladdin-e.com/
Company Name: The future of Shanghai Industrial Co., Ltd.  
Telephone: 021-61552785
Website: www.jonln.com
Company Name: Nanjing Sunlida Biological Technology Co., Ltd.  
Telephone: 025-57798810 18652991625
Website:
Company Name: TargetMol Chemicals Inc.  
Telephone: 021-021-33632979 15002134094
Website: https://www.targetmol.cn/
Company Name: Shanghai JONLN Reagent Co., Ltd.  
Telephone: 400-0066400 13621662912
Website: http://www.jonln.com
Company Name: Alta Scientific Co., Ltd.  
Telephone: 022-6537-8550 15522853686
Website: http://www.altascientific.cn
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.  
Telephone: 551-65418679 15856988503;15837135945
Website: https://www.tnjchem.com
Company Name: Shanghai Xilong Biochemical Technology Co., Ltd.  
Telephone: 021-52907766-8042
Website: www.chemicalbook.com/ShowSupplierProductsList19329/0_EN.htm
Company Name: Guangzhou QiYun Biotechnology Co., Ltd.  
Telephone: 020-61288194 61288195
Website: www.gzqiyun.com
Company Name: Shanghai YuanYe Biotechnology Co., Ltd.  
Telephone: 15026964105
Website: www.shyuanye.com
Company Name: Shandong Xiya Chemical Co., Ltd.  
Telephone: 4009903999 13395398332
Website: http://www.xiyashiji.com
Tags:74115-24-5 Related Product Information
768-33-2 58-93-5 76-83-5 41083-11-8 29104-30-1 74115-24-5