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7446-33-5

7446-33-5 Structure

7446-33-5 Structure
IdentificationMore
[Name]

YTTRIUM SULFATE OCTAHYDRATE
[CAS]

7446-33-5
[Synonyms]

YTTRIUM(III) SULFATE
YTTRIUM(III)SULFATE OCTAHYDRATE
YTTRIUM SULFATE
YTTRIUM SULFATE OCTAHYDRATE
YTTRIUM SULFATE OCTAHYDRATE, 99.9%
YTTRIUM(III) SULFATE OCTAHYDRATE 99.99&
YTTRIUM (III) SULFATE OCTAHYDRATE (99.9%-Y) (REO)
YTTRIUM (III) SULFATE, REACTON, 99.99% (REO)
Yttrium(III)sulfateoctahydrate,REacton,99.9%(REO)
yttrium(iii) sulfate octahydrate, reacton
YTTRIUMSULPHATEOCTAHYDRATE
Yttrium(III) sulfate octahydrate, REacton(R), 99.9% (REO)
Yttrium(III) sulfate hydrate, REacton(R), 99.99% (REO)
Yttrium(III) sulfate hydrate, REacton, 99.99% (REO)
[Molecular Formula]

H16O20S3Y2
[MDL Number]

MFCD00149946
[Molecular Weight]

610.12
[MOL File]

7446-33-5.mol
Chemical PropertiesBack Directory
[Appearance]

Small, reddish-white, monosymmetric crystals. D 2.558, loses 8H2O at 120C, decomposes 700C. Soluble in concentrated sulfuric acid; sparingly soluble in water; insoluble in alkalies.
[density ]

2.5 g/mL at 25 °C(lit.)
[form ]

Crystalline
[color ]

White to pale yellow
[Specific Gravity]

2.558
[Water Solubility ]

Water solubility decreases with increasing temperature. Soluble in water.
[Merck ]

14,10107
[CAS DataBase Reference]

7446-33-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[TSCA ]

Yes
Questions And AnswerBack Directory
[Uses]

Yttrium Sulfate, also called Yttrium Sulphate, is applied in ceramics, glass, and electronics. Yttrium Sulfate is a moderately water and acid soluble Yttrium source for uses compatible with sulfates. Yttrium is used in the production of a large variety of synthetic garnets, and Yttria is used to make Yttrium-Iron-Garnets, which are very effective microwave filters.
Hazard InformationBack Directory
[Description]

Yttrium(III) sulfate octahydrate, with the chemical formula Y2(SO4)3-8H2O, consists of infinite layers parallel to (10\overline 1), with [Y(H2O)4(SO4)3/2] being the only repeating unit. The layers are connected to each other using only moderately strong hydrogen bonds. The trivalent yttrium cation is coordinated by eight O-atoms from four sulfate groups and four water molecules in a distorted square antitetrahedron [YO8]. It is of the same structural type as the rare earth sulfate octahydrate[1].
YTTRIUM SULFATE OCTAHYDRATE
Figure 1. View perpendicular to the (10 1) layer of the title compound, with [Y(H 2 O) 4/1 (SO 4 (1)) 3/3 (SO 4 (2)) 1/2 ] as the repeat unit. Key: [SO 4 ] tetrahedra (yellow), [YO 8 ] antiprisms (red), oxygen (blue) and hydrogen (light grey) atoms.
[Chemical Properties]

Small, reddish-white, monosymmetric crystals. D 2.558, loses 8H2O at 120C, decomposes 700C. Soluble in concentrated sulfuric acid; sparingly soluble in water; insoluble in alkalies.
[Physical properties]

Red monoclinic crystals; density 2.59 g/cm3; loses all its water molecules at 120°C; decomposes at 700°C; sparingly soluble in water, less soluble in hot water; dissolves in concentrated sulfuric acid forming Y(HSO4)3; insoluble in alkalis; forms double salts with alkali sulfates.
[Preparation]

Yttrium sulfate is produced as an intermediate in recovering yttrium from monazite or xenotime (see Yttrium, Recovery). Rare earth sulfates are separated on a cation exchange resin bed. Yttrium fraction is purified by fractional crystallization. Alternatively, yttrium sulfate may be prepared by reacting yttrium oxide with sulfuric acid.
[References]

[1] PETER HELD; Ma-thias W. Yttrium(III) sulfate octahydrate[J]. Acta crystallographica. Section E, Structure reports online, 2004. DOI:10.1107/S1600536803012182.
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Yttrium(III) sulfate octahydrate, REacton, 99.9% (REO)(7446-33-5)
[Sigma Aldrich]

7446-33-5(sigmaaldrich)
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