| Identification | More | [Name]
2-Amino-4-methoxy-6-methylpyrimidine | [CAS]
7749-47-5 | [Synonyms]
2-AMINO-4-METHOXY-6-METHYLPYRIMIDINE
2-AMINO-4-METHYL-6-METHOXYPYRIMIDINE
TIMTEC-BB SBB006744
2-AMINO-4-METHOXY-6-METHYLPYRIMIDINE, 98 %
4-METHOXY-6-METHYL-2-PYRIMIDINAMINE
2-Pyrimidinamine, 4-methoxy-6-methyl-(9CI)
2-Amino-4-methoxy-6-methylpyrimidine, 99+%
4-Methoxy-6-methylpyrimidine-2-amine
4-Methyl-6-methoxypyrimidine-2-amine | [Molecular Formula]
C6H9N3O | [MDL Number]
MFCD00059768 | [Molecular Weight]
139.16 | [MOL File]
7749-47-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to pinkish or light beige | [Melting point ]
156-158 °C (lit.) | [Boiling point ]
255.11°C (rough estimate) | [density ]
1.2081 (rough estimate) | [refractive index ]
1.6500 (estimate) | [solubility ]
methanol: soluble1%, clear to very slightly hazy, colorless to yellow | [form ]
powder to crystal | [pka]
6.38±0.10(Predicted) | [color ]
White to Almost white | [BRN ]
121733 | [CAS DataBase Reference]
7749-47-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R21/22:Harmful in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
8 | [Hazard Note ]
Irritant | [HS Code ]
29335990 |
| Hazard Information | Back Directory | [Chemical Properties]
white to pinkish or light beige | [Uses]
2-Amino-4-methoxy-6-methylpyrimidine may be employed as nucleophile to investigate the regioselective introduction of some nucleophiles at the secondary position of Baylis-Hillman adducts. It may be used in the preparation of 2-amino-4-methoxy-6-methylpyrimidin-1-ium picrate. | [General Description]
2-Amino-4-methoxy-6-methylpyrimidine (AMMP) is a pyrimidine derivative. It acts as electron donor and forms charge transfer complexes with iodine (σ-electron acceptor). The FTIR and FT-Raman spectra of 2-amino-4-methoxy-6-methylpyrimidine have been recorded to evaluate the energy, structural and thermodynamical parameters. Molecules of AMMP exhibit space group of Pnma and are joined by two N-H…N hydrogen bonds. | [Purification Methods]
Recrystallise it from H2O. The picrate has m 220-221o(dec). [Baker et al. J Am pKEst ~ Chem Soc 69 3072, 3075 1947, Sirakawa et al. Yakugaku Zasshi 73 598 1953, Backer & Grevenstuk Recl Trav Chim, Pays-Bas 61 291 1942, Beilstein 25 III/IV 3385.] |
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| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
China Langchem Inc.
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| Telephone: |
0086-21-58956006 |
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www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
| Company Name: |
Maya High Purity Chemicals
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+86 (573) 82222445 (0)18006601000 452520369 |
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www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
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