ChemicalBook--->CAS DataBase List--->787618-22-8

787618-22-8

787618-22-8 Structure

787618-22-8 Structure
IdentificationBack Directory
[Name]

2-DICYCLOHEXYLPHOSPHINO-2',6'-DI-I-PROPOXY-1,1'-BIPHENYL
[CAS]

787618-22-8
[Synonyms]

RUPHOS
RuPhos 95%
98% RuPhos
dicyclohexyl(2',6'-diisopropox
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROP&
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL
dicyclohexyl(2',6'-diisopropoxybiphenyl-2-yl)phosphine
2-DicyclohexylphosphiNA-2',6'-diisopropoxy-1,1'-biphenyl
2-DICYCLOHEXYLPHOSPHINO-2',6'-DI-I-PROPOXY-1,1'-BIPHENYL
2-Dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl,RuPhos
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,98%
2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl, 98%
{2-[2,6-bis(propan-2-yloxy)phenyl]phenyl}dicyclohexylphosphane
Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine
Dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,RuPhos
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl, min.98%
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl, min. 98%
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,98% RuPhos
[2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,min.98%RuPhos
[EINECS(EC#)]

1312995-182-4
[Molecular Formula]

C30H43O2P
[MDL Number]

MFCD06798294
[MOL File]

787618-22-8.mol
[Molecular Weight]

466.63
Chemical PropertiesBack Directory
[Melting point ]

123-124°C
[Boiling point ]

551.7±40.0 °C(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
[form ]

Powder
[color ]

white
[Sensitive ]

Air Sensitive
[InChI]

InChI=1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3
[InChIKey]

MXFYYFVVIIWKFE-UHFFFAOYSA-N
[SMILES]

P(C1=CC=CC=C1C1=C(OC(C)C)C=CC=C1OC(C)C)(C1CCCCC1)C1CCCCC1
Hazard InformationBack Directory
[Uses]

Bulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborate?s with electron-poor aryl bromides.
[Uses]

Ligand used for the palladium-catalyzed coupling of alkyl boronates
[Uses]

suzuki reaction
[reaction suitability]

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H312-H332-H413
[Precautionary statements ]

P280
[Hazard Codes ]

Xn
[Risk Statements ]

36/37/38-20/21/22
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

29310099
[Storage Class]

13 - Non Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Versatile Ligand for the Pd-catalyzed coupling of secondary arylamines and alkylamines.
  2. Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero)arylchlorides.
  3. Synthesis of ladder-type π-conjugated heteroacenes via palladium-catalyzed double N-arylation and intramolecular O-arylation.
  4. A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles,
  5. Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst.
  6. Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
  7. Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides.
  8. Ligand used for the palladium-catalyzed coupling of alkyl boronates.
Reactions of 787618-22-8_1
Reactions of 787618-22-8_2
Reactions of 787618-22-8_3
Reactions of 787618-22-8_4
Spectrum DetailBack Directory
[Spectrum Detail]

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL(787618-22-8)1HNMR
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL(787618-22-8)31PNMR
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