| Identification | More | [Name]
4-Bromobenzyl alcohol | [CAS]
873-75-6 | [Synonyms]
4-BROMOBENZYL ALCOHOL
P-BROMOBENZYL ALCOHOL
RARECHEM AL BD 0075
(4-Bromophenyl)methanol
Benzyl alcohol, p-bromo-
4-Brom-benzyl alcohol
Brombenzylalcohol
4-BROMOBENZYL ALCOHOL 98%
4-Bromobenzyl alcohol, 98+%
4-Bromobenzylalcohol,99%
Benzenemethanol, 4-bromo-
4-Bromobenzenemethanol | [EINECS(EC#)]
212-851-7 | [Molecular Formula]
C7H7BrO | [MDL Number]
MFCD00004650 | [Molecular Weight]
187.03 | [MOL File]
873-75-6.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO SLIGHTLY BEIGE CRYSTALS OR CRYST. POWDER | [Melting point ]
75-77 °C (lit.) | [Boiling point ]
220.79°C (rough estimate) | [density ]
1.3839 (rough estimate) | [vapor pressure ]
0.083Pa at 20℃ | [refractive index ]
1.5840 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
dioxane: soluble1g/10 mL, clear to faintly turbid, colorless to faintly yellow | [form ]
Crystals or Crystalline Powder | [pka]
14.16±0.10(Predicted) | [color ]
White to slightly beige | [Water Solubility ]
2.31g/L at 20℃ | [BRN ]
1931620 | [InChI]
1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2 | [InChIKey]
VEDDBHYQWFOITD-UHFFFAOYSA-N | [SMILES]
OCc1ccc(Br)cc1 | [LogP]
1.59 at 20℃ | [CAS DataBase Reference]
873-75-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenemethanol, 4-bromo-(873-75-6) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [REACH Registrations]
Active | [HS Code ]
29062990 | [Storage Class]
13 - Non Combustible Solids | [Hazard Classifications]
Aquatic Chronic 3 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO SLIGHTLY BEIGE CRYSTALS OR CRYST. POWDER | [Uses]
4-Bromobenzyl alcohol was used in the synthesis of:
- hydroxyl end functionalized, substituted polyfluorene
- amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 48, p. 3074, 1983 DOI: 10.1021/jo00166a029
Tetrahedron Letters, 36, p. 3169, 1995 DOI: 10.1016/0040-4039(95)00504-6 | [General Description]
4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile. | [Flammability and Explosibility]
Notclassified | [Synthesis]
4-Bromobenzyl alcohol can be obtained by first preparing p-bromobenzoic acid borate from methyl p-bromobenzoate and then reacting it with methanol. |
|
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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www.energy-chemical.com |
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Jia Xing Isenchem Co.,Ltd
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