| Identification | Back Directory | [Name]
TRIMETHYLSILYLMETHYL AZIDE | [CAS]
87576-94-1 | [Synonyms]
TRIMETHYLSILYLMETHYL AZIDE
AZIDOMETHYLTRIMETHYLSILANE
Silyl Methyl azide triMethyl | [Molecular Formula]
C4H11N3Si | [MDL Number]
MFCD00059964 | [MOL File]
87576-94-1.mol | [Molecular Weight]
129.24 |
| Chemical Properties | Back Directory | [Boiling point ]
92-95°C | [density ]
0,87 g/cm3 | [refractive index ]
1.4300 to 1.4340 | [Fp ]
6°C | [solubility ]
Sol organic solvents; insol water. | [form ]
clear liquid | [color ]
Colorless to Yellow to Green | [Specific Gravity]
0.87 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [InChI]
InChI=1S/C4H11N3Si/c1-8(2,3)4-6-7-5/h4H2,1-3H3 | [InChIKey]
HKBUFTCADGLKAS-UHFFFAOYSA-N | [SMILES]
C(N=[N+]=[N-])[Si](C)(C)C |
| Hazard Information | Back Directory | [Physical properties]
bp 43 °C/43 mmHg; IR νmax 2100 cm?1;
1H NMR (CDCl3) δ = 0.12 (s, 9H), 2.75 (s, 2H); MS m/z
129, 73. | [Uses]
Trimethylsilylmethyl Azide is used in the amination of organometallic compounds; preparation of
heterocyclic compounds; precursor of azomethine ylide, reactant in Silylmethyl-Substituted Heterocumulenes and [3 + 2] Cycloaddition etc. | [Preparation]
Obtained in high yield by reaction of
sodium azide and (chloromethyl)trimethylsilane in DMF or
HMPA at 80°C. | [Precautions]
Trimethylsilylmethyl Azide is a useful, safe substitute for methyl azide, bp 20 °C, which is explosive. It is stable to temperatures of at least 120 °C and can be stored in a refrigerator for more than 6 months.
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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