| Identification | More | [Name]
BISMUTH(III) IODIDE | [CAS]
7787-64-6 | [Synonyms]
BISMUTH(+3)IODIDE
BISMUTH(III) IODIDE
BISMUTH IODIDE
BISMUTH TRIIODIDE
Bismuth iodide (BiI3)
Bismuthine, triiodo-
triiodo-bismuthin
BISMUTH(III) IODIDE ANHYDROUS BEADS &
BISMUTH(III) IODIDE, 99.999%
Bismuth(III)iodide,tech.,95%
Bismuth(III)iodide,Puratronic,99.999%(metalsbasis)
BISMUTH IODIDE, 99.99+%
Bismuth(III)iodide(99.999%-Bi)PURATREM
bismuth(iii) iodide, puratronic
bismuth(iii) iodide, tech.
bismuth(iii) iodide, ultra dry
BISMUTH (LLL) IODIDE
Bismuth(III) iodide, ultra dry, 99.998% (metals basis)
Bismuth(III) iodide, Puratronic(R), 99.999% (metals basis)
Triiodobismuth(III) | [EINECS(EC#)]
232-127-4 | [Molecular Formula]
BiI3 | [MDL Number]
MFCD00010894 | [Molecular Weight]
589.69 | [MOL File]
7787-64-6.mol |
| Chemical Properties | Back Directory | [Appearance]
White to yellowish white crystalline powder | [Melting point ]
408 °C(lit.)
| [Boiling point ]
500°C | [density ]
5.78 g/mL at 25 °C(lit.)
| [Fp ]
500°C | [solubility ]
soluble in ethanol | [form ]
beads
| [color ]
Dark gray to black | [Specific Gravity]
5.778 | [Water Solubility ]
Insoluble in water. Highly soluble in ethanol, benzene, toluene and xylene, hydrochloric acid and in hydriodic acid. | [Sensitive ]
Hygroscopic | [Merck ]
14,1269 | [Solubility Product Constant (Ksp)]
pKsp: 18.11 | [InChI]
InChI=1S/Bi.3HI/h;3*1H/q+3;;;/p-3 | [InChIKey]
KOECRLKKXSXCPB-UHFFFAOYSA-K | [SMILES]
[Bi](I)(I)I | [CAS DataBase Reference]
7787-64-6(CAS DataBase Reference) | [EPA Substance Registry System]
Bismuthine, triiodo- (7787-64-6) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 3
| [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
2827.60.5100 | [HazardClass ]
8 | [PackingGroup ]
III | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellowish white crystalline powder | [Uses]
Polycrystalline films of bismuth triiodide are used as beta direct and digital detectors for medical imaging applications. Bismuth(III) iodide is used as an ice nucleant. It is also used in electron microscopy to reveal synapses. Addition of bismuth triiodide has been shown to improve the glass forming ability and thermal stability of Ge-Te-BiI(3) chalcogenide glasses. Solution-processable BiI3 nanosheets have been shown to exhibit the potential to be used as HTLs (Hole Transport Layer) in conventional OPV (organic photovoltaic) devices. | [reaction suitability]
reagent type: catalyst
core: bismuth | [Synthesis]
Iodine (20 g.) is ground with 45 g. of finely powdered Bi in a mortar and then rapidly placed in a retort. The mixture is heated until reaction begins. At the end of the reaction, a stream of CO3 is passed through the warm retort to remove unreacted iodine. The iodide is then sublimed in a stream of CO3. Smaller quantities can also be prepared by placing the mixture in a boat inserted into a Vycor tube, heating, and then subliming the Bil 3 in a CO3 stream. |
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