ChemicalBook--->CAS DataBase List--->88-16-4

88-16-4

88-16-4 Structure

88-16-4 Structure
IdentificationMore
[Name]

2-Chlorobenzotrifluoride
[CAS]

88-16-4
[Synonyms]

1-CHLORO-2-(TRIFLUOROMETHYL)BENZENE
2-CHLORO-ALPHA,ALPHA,ALPHA-TRIFLUOROTOLUENE
2-CHLOROBENZOTRIFLUORIDE
2-chloro(trifluoromethyl)benzene
2-CHLOROTRIFLUOROTOLUENE
CHLOROBENZOTRIFLUORIDE(O-)
O-CHLORO-A,A,A-TRIFLUOROTOLUENE
O-CHLORO-ALPHA,ALPHA,ALPHA-TRIFLUOROTOLUENE
O-CHLOROBENZOTRIFLUORIDE
O-CHLOROBENZYLIDYNE TRIFLUORIDE
O-CHLORO(TRIFLUOROMETHYL)BENZENE
1-(trifluoromethyl)-2-chlorobenzene
1-chloro-2-(trifluoromethyl)-benzen
benzene,1-chloro-2-(trifluoromethyl)-
Chlorobenzotrifluoride
o-(Trifluoromethyl)chlorobenzene
o-(Trifluoromethyl)phenyl chloride
o-Chloro-,,,-trifluorotoluene
o-Trifluoromethylphenyl
Toluene, o-chloro-alpha,alpha,alpha-trifluoro-
[EINECS(EC#)]

201-805-1
[Molecular Formula]

C7H4ClF3
[MDL Number]

MFCD00000561
[Molecular Weight]

180.55
[MOL File]

88-16-4.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colourless to light yellow liquid
[Melting point ]

-7.4 °C
[Boiling point ]

152 °C(lit.)
[density ]

1.379 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.456(lit.)
[Fp ]

138 °F
[storage temp. ]

Flammables area
[form ]

clear liquid
[color ]

Colorless to Light yellow
[Specific Gravity]

1.379
[Stability:]

Stable. Flammable. Incompatible with strong oxidizing agents, strong bases.
[explosive limit]

1.7%(V)
[Water Solubility ]

<0.1 g/100 mL at 19.5 ºC
[BRN ]

510993
[Exposure limits]

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
[InChI]

1S/C7H4ClF3/c8-6-4-2-1-3-5(6)7(9,10)11/h1-4H
[InChIKey]

DGRVQOKCSKDWIH-UHFFFAOYSA-N
[SMILES]

FC(F)(F)c1ccccc1Cl
[Uses]

Dye intermediate, chemical intermediate, solvent, and dielectric fluid.
[CAS DataBase Reference]

88-16-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-chloro-2-(trifluoromethyl)-(88-16-4)
[EPA Substance Registry System]

88-16-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,F,Xn,N
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2234 3/PG 3
[WGK Germany ]

3
[RTECS ]

XS9141000
[Hazard Note ]

Flammable/Irritant
[TSCA ]

T
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29036990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chlorine-->Hydrogen fluoride-->2-Chlorotoluene-->ANTIMONY(V) CHLORIDE-->2-Chlorobenzotrichloride
[Preparation Products]

Fomesafen-->4-Chloro-3-(trifluoromethyl)benzaldehyde-->2-(Trifluoromethyl)benzyl bromide-->2-(Trifluoromethyl)benzoic acid-->1-(2-TRIFLUOROMETHYLPHENYL)-PIPERAZINE-->2-Chloro-3,5-dinitrobenzotrifluoride-->2-Chloro-5-nitrobenzotrifluoride-->2-chloro-1-nitro-3-(trifluoromethyl)benzene-->Methyl 2-(trifluoromethyl)benzoate-->Benzotrifluoride-->(2-Chlorophenyl)phenyl-methanone
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Chloro-alpha,alpha,alpha-trifluorotoluene(88-16-4).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear colourless to light yellow liquid
[Purification Methods]

Dry the trifluoride over CaSO4, and distil it at high reflux ratio through a silvered vacuum-jacketed glass column packed with one-eight inch glass helices [Potter & Saylor J Am Chem Soc 73 90 1951]. [Beilstein 5 H 302, 5 III 692, 5 IV 814.]
Spectrum DetailBack Directory
[Spectrum Detail]

2-Chlorobenzotrifluoride(88-16-4)MS
2-Chlorobenzotrifluoride(88-16-4)1HNMR
2-Chlorobenzotrifluoride(88-16-4)13CNMR
2-Chlorobenzotrifluoride(88-16-4)IR1
2-Chlorobenzotrifluoride(88-16-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Chlorobenzotrifluoride, 99%(88-16-4)
[Alfa Aesar]

2-Chlorobenzotrifluoride, 99%(88-16-4)
[Sigma Aldrich]

88-16-4(sigmaaldrich)
[TCI AMERICA]

2-Chlorobenzotrifluoride,>98.0%(GC)(88-16-4)
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