ChemicalBook--->CAS DataBase List--->88-95-9

88-95-9

88-95-9 Structure

88-95-9 Structure
IdentificationMore
[Name]

Phthaloyl dichloride
[CAS]

88-95-9
[Synonyms]

1,2-BENZENEDICARBONYL CHLORIDE
1,2-BENZENEDICARBONYL DICHLORIDE
O-PHTHALOYL CHLORIDE
O-PHTHALOYL DICHLORIDE
ORTHO-PHTHALOYL CHLORIDE
PHTHALIC ACID DICHLORIDE
PHTHALOYL CHLORIDE
PHTHALOYL DICHLORIDE
PHTHALYL CHLORIDE
1,2-Bis(chlorocarbonyl)benzene
benzenedioylchloride
Phthalic chloride
Phthalic dichloride
Phthalyl dichloride
Benzene-1,2-dicarbonyl chloride~Phthaloyl dichloride
O-Pathaloyl Dichloride
Phthaloyl Dichloride/Phthaloyl chloride
PHTHALOYL CHLORIDE, DIST.
o-Phthalyl chloride
o-Phthaloyl dichloride, pract., 97%
[EINECS(EC#)]

201-869-0
[Molecular Formula]

C8H4Cl2O2
[MDL Number]

MFCD00000666
[Molecular Weight]

203.02
[MOL File]

88-95-9.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow liquid
[Melting point ]

6-12 °C(lit.)
[Boiling point ]

269-271 °C(lit.)
[density ]

1.409 g/mL at 25 °C(lit.)
[vapor pressure ]

30 mm Hg ( 47 °C)
[refractive index ]

n20/D 1.568(lit.)
[Fp ]

>230 °F
[storage temp. ]

Store below +30°C.
[solubility ]

Miscible with ether.
[form ]

Liquid
[color ]

Clear yellow
[Water Solubility ]

decomposes
[Sensitive ]

Moisture Sensitive
[Merck ]

14,7375
[BRN ]

608200
[Stability:]

Moisture Sensitive
[InChI]

1S/C8H4Cl2O2/c9-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H
[InChIKey]

FYXKZNLBZKRYSS-UHFFFAOYSA-N
[SMILES]

ClC(=O)c1ccccc1C(Cl)=O
[CAS DataBase Reference]

88-95-9(CAS DataBase Reference)
[NIST Chemistry Reference]

1,2-Benzenedicarbonyl dichloride(88-95-9)
[EPA Substance Registry System]

88-95-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[F ]

21
[TSCA ]

Yes
[REACH Registrations]

Inactive
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29173980
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Skin Corr. 1B
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Admire-->HEPTENOPHOS-->Fumaryl chloride-->Milnacipran Related Impurity 3-->Tetrachlorophthalic acid-->Dibenzyl phthalate-->1,3-Dihydro-N-nitro-1,3-dioxo-2H-isoindole-2-carboximidothioic acid Methyl Ester-->4-Bromomethyl-2-phthalimido-pyridine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,2-Benzenedicarbonyl dichloride(88-95-9).msds
Hazard InformationBack Directory
[Chemical Properties]

clear yellow liquid
[Uses]

Phthaloyl chloride is used for the preparation of volatile acid chlorides from the acids. It acts as a trapping agent for the nitrite ion in the fluorodenitration of aromatic substrates with potassium fluoride. It serves as an additive in polymers and fibers to improve the color stability. It is used as an ingredient in ceramic mold binders, as a stabilizer for polymers and in reverse osmosis membranes.
[Preparation]

Synthesis of phthaloyl dichloride: Mix 148g of phthalic anhydride with 220g of phosphorus pentachloride, heat, gradually increase the temperature to 250°C, escape the phosphorus oxychloride, distill the reaction product under reduced pressure, collect the 131-133°C (1.2-1.33kPa) fraction to obtain 187g of phthaloyl dichloride.
[General Description]

equilibrium mixture (phthaloyl chloride ~80% and pseudochloride ~10%) both components show equal chemical behaviour
Spectrum DetailBack Directory
[Spectrum Detail]

Phthaloyl dichloride(88-95-9)MS
Phthaloyl dichloride(88-95-9)1HNMR
Phthaloyl dichloride(88-95-9)13CNMR
Phthaloyl dichloride(88-95-9)IR1
Phthaloyl dichloride(88-95-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

o-Phthaloyl dichloride, remainder mainly phthalic acid, 90%(88-95-9)
[Alfa Aesar]

Phthaloyl chloride, 94%(88-95-9)
[Sigma Aldrich]

88-95-9(sigmaaldrich)
[TCI AMERICA]

Phthaloyl Chloride,>98.0%(T)(88-95-9)
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