| Identification | More | [Name]
2-(Bromomethyl)naphthalene | [CAS]
939-26-4 | [Synonyms]
2-BMN
2-(BROMOMETHYL)NAPHTHALENE
BROMOMETHYLNAPTHALENE-2
2-Bromomethylnaphthalene98%
2-(Bromomethyl)naphthalene,96%
Naphthalene, 2-(bromomethyl)-
2-naphthylmethyl bromide
2-(Bromomethyl)naphthalene 96%
(2-Naphtylmethyl) bromide
2-Naphtylmethyl bromide | [EINECS(EC#)]
213-359-5 | [Molecular Formula]
C11H9Br | [MDL Number]
MFCD00004123 | [Molecular Weight]
221.09 | [MOL File]
939-26-4.mol |
| Chemical Properties | Back Directory | [Appearance]
White to cream solid | [Melting point ]
51-54 °C(lit.)
| [Boiling point ]
213 °C100 mm Hg(lit.)
| [density ]
1.3971 (rough estimate) | [refractive index ]
1.6411 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Sparingly), Ethyl Acetate (Very Slightly) | [form ]
Fine Crystalline Powder | [color ]
Slightly yellow to light beige | [Water Solubility ]
Soluble in water (reacts), and chloroform. | [Detection Methods]
HPLC,NMR | [BRN ]
636546 | [InChI]
InChI=1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2 | [InChIKey]
RUHJZSZTSCSTCC-UHFFFAOYSA-N | [SMILES]
C1=C2C(C=CC=C2)=CC=C1CBr | [CAS DataBase Reference]
939-26-4(CAS DataBase Reference) | [NIST Chemistry Reference]
Naphthalene, 2-(bromomethyl)-(939-26-4) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS05,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H314-H317 | [Precautionary statements ]
P260-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R43:May cause sensitization by skin contact.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S37:Wear suitable gloves .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [Hazard Note ]
Corrosive/Keep Cold | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29039990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B
Skin Sens. 1 |
| Hazard Information | Back Directory | [Chemical Properties]
White to cream solid | [Uses]
It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff. | [Purification Methods]
Dissolve the bromo compound in toluene, wash it with saturated aqueous NaHCO3, dry (Mg SO4), evaporate, fractionally distil the residue and recrystallise the solidified distillate from EtOH. [Chapman & Williams J Chem Soc 5044, 1952, Bergmann & Szmuszkovicz Bull Soc Chim Fr 20 566 1953, Beilstein 5 IV 1698.] |
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