ChemicalBook--->CAS DataBase List--->94-82-6

94-82-6

94-82-6 Structure

94-82-6 Structure
IdentificationMore
[Name]

2,4-Dichlorophenoxybutyric acid
[CAS]

94-82-6
[Synonyms]

2,4-DB
2,4-DB ACID
2,4-Dichlorophenoxybutyric acid
4-(2,4-Dichlorophenoxy)butanoic acid
4-(2,4-DICHLOROPHENOXY)BUTYRIC ACID
AKOS B030304
BUTORMONE
BUTOXONE
BUTOXONE(R)
BUTYRAC(R)
DB STRAIGHT
DUBLEX
EMBUTOX
EMBUTOX(R)
GAMMA-(2,4-DICHLOROPHENOXY)BUTYRIC ACID
HERBOMOBEED B
LABOTEST-BB LT00068598
'LGC' (1304)
MALERBANE PRATI
MB 2878
[EINECS(EC#)]

202-366-9
[Molecular Formula]

C10H10Cl2O3
[MDL Number]

MFCD00002819
[Molecular Weight]

249.09
[MOL File]

94-82-6.mol
Chemical PropertiesBack Directory
[Appearance]

White to light-brown crystalline solid. May be shipped as a concentrate to be mixed with water and used as a spray. Slight phenolic odor.
[Melting point ]

118-120 °C(lit.)
[Boiling point ]

324.35 °C
[density ]

1.3342 (estimate)
[storage temp. ]

0-6°C
[form ]

Amorphous Powder
[pka]

4.56±0.10(Predicted)
[color ]

Off-white
[Water Solubility ]

53mg/L(room temperature)
[Merck ]

13,2855
[BRN ]

1976809
[Henry's Law Constant]

4.3×103 mol/(m3Pa) at 25℃, HSDB (2015)
[Major Application]

agriculture
environmental
[InChI]

InChI=1S/C10H10Cl2O3/c11-7-3-4-9(8(12)6-7)15-5-1-2-10(13)14/h3-4,6H,1-2,5H2,(H,13,14)
[InChIKey]

YIVXMZJTEQBPQO-UHFFFAOYSA-N
[SMILES]

C(O)(=O)CCCOC1=CC=C(Cl)C=C1Cl
[CAS DataBase Reference]

94-82-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Butanoic acid, 4-(2,4-dichlorophenoxy)-(94-82-6)
[EPA Substance Registry System]

94-82-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,N
[Risk Statements ]

R22:Harmful if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S25:Avoid contact with eyes .
S29:Do not empty into drains .
S46:If swallowed, seek medical advice immediately and show this container or label .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

2
[RTECS ]

ES9100000
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29189900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Chronic 2
[Hazardous Substances Data]

94-82-6(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

tert-Butanol-->Chloroacetic acid-->Sodium chloroacetate-->Phenoxyacetic acid-->Butyl 2,4-dichlorophenoxyacetate
Hazard InformationBack Directory
[General Description]

Colorless crystals. Slightly corrosive to iron. A chlorinated phenoxy herbicide. Soluble in organic solvents.
[Reactivity Profile]

2,4-DB is an organic acid. Neutralizes bases in exothermic reactions. Forms water soluble metal and amine salts. Hard water precipitates the calcium and magnesium salts from aqueous solutions of such salts.
[Potential Exposure]

2,4-DB is a chlorophenoxy/arylox- yalkanoic acid selective systemic herbicide used to control annual and perennial broadleaf weeds in many field crops such as alfalfa, peanuts, cereals and soybeans; used as a defoliant. In the plant, the compound changes to 2,4-D and inhibits growth at the tips of stems and roots.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped.Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Do not induce vomiting when formulations containing petroleum solvents are ingested. Otherwise, give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz- ardous material, Technical Name Required.
[Incompatibilities]

2,4-DB is a weak organic acid. Keep away from oxidizers, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, and epichlorohydrin. Corrosive to iron, aluminum, zinc, and possibly other metals, especially in the presence of moisture.
[Description]

2,4-DB is a post-emergence herbicide that is used to control broadleaved weeds. It is highly soluble in water and most organic solvents. It is relatively volatile but it may leach to groundwater under certain conditions. It is not persistent in soil systems but may tend to be persistent in aquatic systems. It is moderately toxic to mammals and there is some concern regarding its potential for bioaccumulation. It is moderately toxic to birds, earthworms, honeybees and most aquatic organisms.
[Chemical Properties]

White to light-brown crystalline solid. May be shipped as a concentrate to be mixed with water and used as a spray. Slight phenolic odor.
[Waste Disposal]

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guid- ance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office
[Uses]

4-(2,4-Dichlorophenoxy)butanoic Acid is a herbicide.
[Definition]

ChEBI: A monocarboxylic acid that is butyric acid in which one of the hydrogens at position 4 is replaced by a 2,4-dichlorophenoxy group. A selective post-emergence herbicide.
[Production Methods]

2,4-DB (is manufactured through a multi-step chemical synthesis process that begins with the preparation of key intermediates such as 2,4-dichlorophenol and monochloroacetic acid. These compounds are first neutralized with sodium hydroxide to form sodium salts. The sodium 2,4-dichlorophenate is then condensed with sodium monochloroacetate to produce sodium 2,4-dichlorophenoxyacetate, which is further reacted with butyric acid derivatives to form 2,4-DB. The final product undergoes purification steps such as washing, stripping, and crystallization to ensure high purity and stability.
[Mechanism of action]

Selective, systemic. Synthetic auxin causing stem and leaf malformations leading to death.
[Pesticide Type]

Herbicide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-(2,4-Dichlorophenoxy)butanoic acid(94-82-6).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2,4-Dichlorophenoxybutyric acid(94-82-6)MS
2,4-Dichlorophenoxybutyric acid(94-82-6)1HNMR
2,4-Dichlorophenoxybutyric acid(94-82-6)13CNMR
2,4-Dichlorophenoxybutyric acid(94-82-6)IR1
2,4-Dichlorophenoxybutyric acid(94-82-6)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-(2,4-Dichlorophenoxy)butyric acid, 95%(94-82-6)
[Sigma Aldrich]

94-82-6(sigmaaldrich)
94-82-6 suppliers list
Company Name: Jinan Tai Hang Seng Material Technology Co., LTD  Gold
Telephone: 17852565707
Website: www.chemicalbook.com/ShowSupplierProductsList1849419/0_EN.htm
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: China Langchem Inc.  
Telephone: 0086-21-58956006
Website: www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Spectrum Chemical Manufacturing Corp.  
Telephone: 021-021-021-67601398-809-809-809 15221380277
Website: www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us
Company Name: Shanghai JONLN Reagent Co., Ltd.  
Telephone: 400-0066400 13621662912
Website: http://www.jonln.com
Company Name: Shanghai YuLue Chemical Co., Ltd.  
Telephone: 021-60345187 13671753212
Website: https://www.chemicalbook.com/ShowSupplierProductsList16365/0_EN.htm
Company Name: Sigma-Aldrich  
Telephone: 021-61415566 800-8193336
Website: https://www.sigmaaldrich.cn
Company Name: Alta Scientific Co., Ltd.  
Telephone: 022-6537-8550 15522853686
Website: http://www.altascientific.cn
Company Name: Tianjin Being Technology Co., Ltd.  
Telephone: 18622939839
Website: http://www.beingtech.cn
Company Name: Shanghai Xilong Biochemical Technology Co., Ltd.  
Telephone: 021-52907766-8042
Website: www.chemicalbook.com/ShowSupplierProductsList19329/0_EN.htm
Company Name: Shanghai YuanYe Biotechnology Co., Ltd.  
Telephone: 15026964105
Website: www.shyuanye.com
Company Name: Shenzhen Regent Biochemical Technology Co., Ltd.  
Telephone: 0755-85201366 18938635012
Website: http://www.regentsciences.com/
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400-6387771-6039 18920764717
Website: www.heowns.com
Company Name: Jinan Liheng Biotechnology Co., Ltd.  
Telephone: 0531-18763987518 18763987518
Website: www.lihengpharm.com
Company Name: Shenzhen Polymeri Biochemical Technology Co., Ltd.  
Telephone: +86-400-002-6226
Website: https://www.rrkchem.com
Tags:94-82-6 Related Product Information
94-75-7 541-73-1 95-50-1 462-95-3 79-31-2 107-92-6 94-99-5 13609-67-1 133-32-4 52645-53-1 10094-34-5 1134-47-0 122-88-3 6843-66-9 56-12-2 305-03-3 108-90-7 94-82-6