| Identification | More | [Name]
3'-Chloroacetophenone | [CAS]
99-02-5 | [Synonyms]
1-(3-CHLOROPHENYL)ETHANONE
3'-CHLOROACETOPHENONE
3-CHLOROACETOPHENONE
M-CHLOROACETOPHENONE
1-(3-chlorophenyl)-ethanon
3'-Chloroacetylphenone
Ethanone, 1-(3-chlorophenyl)-
3'-Chloroacetophenone 1-(3-Chlorophenyl)ethanone 3-Chloroacetophenone
3-Chloroacetophenone, 98+%
3-CHLORO ACETOPHENONE,99.0%MIN
3''-CHLOROACETOPHENONE,=99.0%
1-(3-Chlorophenyl)ethan-1-one
1-Acetyl-3-chlorobenzene
3-Chlorophenyl methyl ketone
Methyl 3-chlorophenyl ketone | [EINECS(EC#)]
202-721-8 | [Molecular Formula]
C8H7ClO | [MDL Number]
MFCD00000593 | [Molecular Weight]
154.59 | [MOL File]
99-02-5.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless to yellow liquid | [Boiling point ]
227-229 °C(lit.)
| [density ]
1.191 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.550(lit.)
| [Fp ]
221 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Liquid | [color ]
Clear colorless to yellow | [Specific Gravity]
1.191 | [Sensitive ]
Lachrymatory | [BRN ]
636318 | [InChI]
InChI=1S/C8H7ClO/c1-6(10)7-3-2-4-8(9)5-7/h2-5H,1H3 | [InChIKey]
UUWJBXKHMMQDED-UHFFFAOYSA-N | [SMILES]
C(=O)(C1=CC=CC(Cl)=C1)C | [CAS DataBase Reference]
99-02-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Acetophenone, 3'-chloro-(99-02-5) | [EPA Substance Registry System]
99-02-5(EPA Substance) |
| Questions And Answer | Back Directory | [Uses]
3'-Chloroacetophenone can be used as a raw material for pharmaceutical synthesis, mainly for the synthesis of carbamazepine, a drug for the treatment of epilepsy, and as an intermediate for fine chemicals, pesticides, etc. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S13:Keep away from food, drink and animal feeding stuffs .
S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
UN 3416 6.1/PG 2
| [WGK Germany ]
3
| [F ]
19 | [Hazard Note ]
Harmful/Irritant/Lachrymatory | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29147090 | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colourless to yellow liquid | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 60, p. 2361, 1995 DOI: 10.1021/jo00113a013 | [General Description]
The activity of strain, Saccharomyces cerevisiae B5, on the reduction of 3′-chloroacetophenone was studied. | [Synthesis]
The first step of the reaction is to use anhydrous ether as solvent, carbon tetrachloride as initiating catalyst, from magnesium, anhydrous ethanol and diethyl malonate, at atmospheric pressure and 20 ℃ ~ 35 ℃, heating reflux for 2 ~ 4 hours, while the pr |
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