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Tetrakis[μ-(acetato-O:O')]dirhodium Produkt Beschreibung

Rhodium(II) acetate dimer Struktur
15956-28-2
CAS-Nr.
15956-28-2
Bezeichnung:
Tetrakis[μ-(acetato-O:O')]dirhodium
Englisch Name:
Rhodium(II) acetate dimer
Synonyma:
tetraac;Rh2(OAc)4;Rh2(CH3CO2)4;RHODIUM(11) ACETATE;RHODIUM ACETATE DIMER;dirhodiumtetraacetate;rhodiumdiacetatedimer;tetraacetatodirhodium;Rhodium(Ⅱ) acetate dimer;RHODIUM(II) ACETATE DIMER
CBNumber:
CB2332600
Summenformel:
C8H12O8Rh2
Molgewicht:
441.99
MOL-Datei:
15956-28-2.mol

Tetrakis[μ-(acetato-O:O')]dirhodium Eigenschaften

Schmelzpunkt:
205 °C
storage temp. 
Store below +30°C.
Aggregatzustand
powder
Farbe
Green to dark green
Wasserlöslichkeit
Soluble in aqueous solution like water. Slightly soluble in ethanol
InChIKey
ANSVJOOIUURYRN-UHFFFAOYSA-N
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/38
S-Sätze: 37/39-26-15
WGK Germany  3
RTECS-Nr. VI9361000
TSCA  No
HS Code  28439000
Bildanzeige (GHS)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
Sicherheit
P261 Einatmen von Staub vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

Tetrakis[μ-(acetato-O:O')]dirhodium Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/38:Reizt die Augen und die Haut.

S-Sätze Betriebsanweisung:

S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S15:Vor Hitze schützen.

Chemische Eigenschaften

Rhodium(II) acetate dimer is Emerald Green Powder

Verwenden

Rhodium (II) Acetate Dimer is used in the preparation of molybdenum triisopropylbenzoate isonicotinate which maintains ambivalent properties.

läuterung methode

Dissolve 5g of the salt in boiling MeOH (ca 600mL) and filter. Concentrate it to 400mL and chill overnight at ca 0o to give dark green crystals of the MeOH adduct. Concentration of the mother liquors gives a further crop of [Rh(OAc)2]2.2MeOH. The adduct is then heated at 45o in a vacuum for 2hours (all MeOH is lost) to leave the emerald green crystals of the actetate. [Legzdins et al. J Chem Soc (A) 3322 1970.] Alternatively dissolve the acetate in glacial AcOH and reflux for a few hours to give an emerald green solution. Evaporate most of the AcOH on a steam bath, then heat the residue at 120o/1hour. Extract the residue with boiling Me2CO. Filter, concentrate to half its volume and keep at 0o/18hours. Collect the crystals, wash them with ice cold Me2CO and dry them at 110o. It is soluble in most organic solvents with which it forms adducts including Me3N and Me2S and gives solutions with different colours varying from green to orange and red. [UV: Johnson et al. Inorg Chem 2 960 1963, Beilstein 1 H 124.]

Tetrakis[μ-(acetato-O:O')]dirhodium Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Tetrakis[μ-(acetato-O:O')]dirhodium Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 191)Lieferanten
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0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22631 55
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sales@coreychem.com CHINA 30057 58
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15956-28-2(Tetrakis[μ-(acetato-O:O')]dirhodium)Verwandte Suche:


  • 12.Rhodium(II) Acetate Dimer
  • tetrakis-(mu-acetato)dirhodium
  • tetrakis[mu-(acetato-O:O')]dirhodium
  • RHODIUM(II) ACETATE DIMER, POWDER
  • RHODIUM(II) ACETATE DIMER, 99.99+% METALS BASIS
  • Rhodium(Ⅱ) acetate dimer ,99% [anhydrous, 46% Rh]
  • Rhodium(II) acetate dimer dihydrate,Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
  • Rhodium(II) acetate dimer,Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
  • RhodiuM(II) acetate diMer, anhydrous, ca 46% Rh 1GR
  • RhodiuM(II) acetate diMer, anhydrous, ca 46% Rh 250MG
  • RhodiuM(II) acetate diMer,98% Rh2(OAc)4
  • Dirhodium(II) Tetraacetate Tetrakis(acetato)dirhodium(II)
  • Rhodium(Ⅱ) acetate dimer
  • RhodiuM(Ⅱ) acetate diMer, anhydrous, 46% Rh
  • Rhodium(II) acetate dimer dihydrate, 98+%
  • Rhodium(II) acetate dimer, 99%, anhydrous, 46% Rh
  • tetraac
  • TETRAKIS(ACETATO)DIRHODIUM(II)
  • tetrakis[micron-(acetato-o:o')]dirhodium
  • RHODIUM ACETATE DIMER
  • RHODIUM(II) ACETATE DIMER
  • DIRHODIUM(II) TETRAACETATE
  • dirhodiumtetraacetate
  • rhodiumdiacetatedimer
  • tetraacetatodirhodium
  • tetrakis(acetato)dirhodium
  • tetrakis(mu-acetato)di-rhodiu
  • RhodiuM(Ⅱ) acetate diMer, 42% Rh, Product of UMicore
  • RhodiuM, tetrakis[M-(acetato-kO:kO')]di-, (Rh-Rh)
  • Rh2(OAc)4
  • Rhodium(II) acetate dimer 99.99% trace metals basis
  • Rh2(CH3CO2)4
  • Rhodium(II) acetate dimer (46.5% Rh) for synthesis
  • Rhodium(II) acetate, dimer, Rh 46.2% min.
  • RHODIUM(II) ACETATE DIMER DIHYDRATE, ~43 % RH
  • Rhodium(II)acetatedimeredihydrate
  • Rhodium(II) acetate dimer, anhydrous, ca 46% Rh
  • Rhodium(II)acetatedimer,99%
  • Rhodium, tetrakis.mu.-(acetato-.kappa.O:.kappa.O)di-, (Rh-Rh)
  • RHODIUMACETATEDIMER,ANHYDROUS
  • RHODIUM(II) ACETATE DIMER , (43%RH)
  • TETRAKIS(ACETATO)DIRHODIUM(LL)HYDRATE
  • RHODIUM(11) ACETATE
  • Rhodium(II)acetate dimer rhodium(ii) acetate dimer
  • TETRAKIS[.MU.-(ACETATO-.KAPPA.O:.KAPPA.O'')]DI-RHODIUM
  • Rhodium(II) Acetate Dimer, Rh 46.6%
  • Tetrakis(acetato) rhodium (II) –2-hydrat
  • Rhodium(II) acetate, dimer, 98+%
  • Rhodium(II) acetate, dimer, Premion(R), 99.99% (metals basis), Rh 46.2% min
  • 15956-28-2
  • 15956-28-9
  • 15965-28-2
  • C8H16O8Rh2
  • Rh2OOCCH34
  • RhCO2CH322
  • RhCH3COO22
  • RhCH3COO222H2O
  • C8H12O8Rh2
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