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4-Methoxyphenylessigsäure Produkt Beschreibung

CAS-Nr.104-01-8
Bezeichnung:4-Methoxyphenylessigsäure
Englisch Name:4-Methoxyphenylacetic acid
Synonyma:
ASISCHEM D13364;HOMOANISIC ACID;HOMO-P-ANISIC ACID;p-Anisylacetic acid;RARECHEM AL BO 0133;4-Methoxyphenylaceti;p-Methioxy-toluicacid;4-Methoxyphenylacetic;2-(p-anisyl)aceticacid;LABOTEST-BB LT00848110
CBNumber:CB5113770
Summenformel:C9H10O3
Molgewicht:166.17
MOL-Datei:104-01-8.mol
4-Methoxyphenylessigsäure physikalisch-chemischer Eigenschaften
Schmelzpunkt:: 84-86 °C(lit.)
Siedepunkt:: 140 °C3 mm Hg(lit.)
Dichte: 1.1708 (rough estimate)
Brechungsindex: 1.5101 (estimate)
Flammpunkt:: 193°C
storage temp. : Store below +30°C.
Löslichkeit: 6g/l
pka: pK1:4.358 (25°C)
Aggregatzustand: Crystalline Powder and Chunks
Farbe: White to light yellow
Wasserlöslichkeit: 6 g/L (20 ºC)
BRN : 1101737
InChIKey: NRPFNQUDKRYCNX-UHFFFAOYSA-N
CAS Datenbank: 104-01-8(CAS DataBase Reference)
NIST chemische Informationen: Benzeneacetic acid, 4-methoxy-(104-01-8)
EPA chemische Informationen: Benzeneacetic acid, 4-methoxy-(104-01-8)
Sicherheit
Kennzeichnung gefährlicher: Xn,Xi
R-Sätze:: 22-36/37/38-20/21/22
S-Sätze:: 26-36
WGK Germany : 3
RTECS-Nr.: AI8960000
Hazard Note : Irritant
TSCA : Yes
HS Code : 29189090

4-Methoxyphenylessigsäure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
white to light yellow crystalline powder and
Verwenden
Preparation of pharmaceuticals, other organic compounds.
Definition
ChEBI: A monocarboxylic acid that is phenylacetic acid carrying a 4-methoxy substituent. It is used as an intermediate for pharmaceuticals and other organic synthesis. It has been found to inhibit the germination of cress and lettuce seeds.
Allgemeine Beschreibung
Pale yellow or off white colored flakes. Severely irritates skin and eyes. May be toxic by ingestion.
Reaktivität anzeigen
Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in 4-Methoxyphenylacetic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Brandgefahr
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Sicherheitsprofil
Moderately toxic by ingestion and intraperitoneal routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits acrid smoke and irritating fumes.
läuterung methode
Crystallise the acid from EtOH/water, EtOAc/pet ether (m 87o) or *C6H6/pet ether (m 84-86o). [Beilstein 10 III 431, 10 IV 544.] The acid chloride [4693-91-8] has M 184.6, b 143o/10mm, d 254
4-Methoxyphenylessigsäure Upstream-Materialien And Downstream Produkte
Upstream-Materialien
4-Methoxyacetophenon
Downstream Produkte
4-Methoxyphenylessigsäure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.      Global( 311)Lieferanten     
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95sales@capotchem.com China 19919 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21930 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693info@tianfuchem.com CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733sales@mainchem.com CHINA 32457 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20516 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23982 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20094 58
Accela ChemBio Inc.
(+1)-858-699-3322
(+1)-858-876-1948info@accelachem.com United States 12233 58
MINKESH (SHANGHAI) CO., LTD. +86 021 20983811 13167252998
+86 021 23027795sales@minkesh.com China 56 55
Shanghai Boyle Chemical Co., Ltd. Mr Qiu:021-50182298(Demestic market) Miss Xu:021-50180596(Abroad market)
+86-21-57758967sales@boylechem.com China 2214 55
 
104-01-8(4-Methoxyphenylessigsäure)Verwandte Suche:
Phenethylphenylacetat (R)-(-)-α-Methoxyphenylessigsure 3,4-Dimethoxyphenylessigsure Zitronensure Folsure Stearinsure 2,2-Diphenylacetic acid 4-Methoxyphenylacetonitril ACETIC ACID p-Methoxyphenethylamin o-Hydroxyphenylessigsure o-Tolylessigsure 3,5-dimethoxyphenylacetic acid 4-Methoxyphenylessigsäure Phenylessigsure p-Hydroxyphenylessigsure 4-Methoxyacetophenon 3-Methoxyphenylessigsure
(4-methoxyphenyl)ethanoicacid 2-(p-Anisyl)acetic acid 2-(p-anisyl)aceticacid 4-Methoxybenzeneacetic acid 4-methoxy-benzeneaceticaci 4-methoxybenzeneaceticacid 4-methoxy-Benzeneaceticacid 4-methoxybenzeneethanoicacid 4-Methoxyphenylethanoicacid PARA-METHOXYPHENYLACETICACID ACETICACID,PARAMETHOXYPHENYL- 2-(p-Methoxyphenyl)acetic acid p-Anisylacetic acid 4-Methoxyphenylacetic acid ,99% 4-Methoxyphenylacetic acid, 98+% 4-Methoxyphenylaceti 4-Methoxyphenylacetic acid, 99% 5GR 4-Methoxyphenylacetic acid (4-MPAA) Homoanisic acid, 4-(Carboxymethyl)anisole 4-Methoxyphenylacetic acid ReagentPlus(R), 99% 4-Methoxyphenylacetic Acid, 97+% ASISCHEM D13364 LABOTEST-BB LT00848110 HOMOANISIC ACID HOMO-P-ANISIC ACID 4-METHOXYPHENYLACETIC ACID P-METHOXY-A-CARBOXYTOLUENE P-METHOXYPHENYLACETIC ACID RARECHEM AL BO 0133 104-01-8 C9 Carboxylic Acids Acetic acid, (p-methoxyphenyl)- Benzeneaceticacid,4-methoxy- ethanoicacid,(4-methoxyphenyl)- p-Methioxy-toluicacid p-Methoxy-alpha-toluic acid p-methoxyphenyl-aceticaci p-Methoxy-α-carboxy-toluene p-Methoxy-α-toluic acid 4-Methoxyphenylacetic 101-01-8 CH3OC6H4CH2CO2H The Methoxy benzene acetic acid 4-Methoxyphenylacetic acid Vetec(TM) reagent grade, 98% - Carbonyl Compounds Building Blocks Organic Building Blocks Aromatic Phenylacetic Acids and Derivatives pharmacetical Building Blocks C9 Carbonyl Compounds Carboxylic Acids Chemical Synthesis Organic Building Blocks Pyridines
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