ChemicalBook >> CAS DataBase List >>(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

CAS No.
52509-14-5
Chemical Name:
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
Synonyms
OMTPPB;96.0%(T);2-(1,3)-DIO;LABOTEST-BB LT00233112;Amyl 4-Carboxyphenyl Carbonate >(1,3-DIOXOLAN-2-YL)-METHYLTRIPHENYLPHOSP;1,3-dioxolan-2-ylmethyl(triphenyl)phosphanium;1,3-Dioxolan-2-ylmethyl-triphenylphosphanium bromide;(1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;TRIPHENYL-1,3-DIOXOLAN-2-YLMETHYL-PHOSPHONIUM BROMIDE
CBNumber:
CB0176860
Molecular Formula:
C22H22BrO2P
Molecular Weight:
429.29
MDL Number:
MFCD00011966
MOL File:
52509-14-5.mol
MSDS File:
SDS
Last updated:2024-01-16 16:12:45

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Properties

Melting point 193-195 °C(lit.)
storage temp. Store below +30°C.
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder or Crystals
color White to light brown
Water Solubility Soluble in water (20°C).
Sensitive Hygroscopic
InChIKey FRHRVQQUICVJDG-UHFFFAOYSA-M
CAS DataBase Reference 52509-14-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  26-37/39
WGK Germany  3
HS Code  29329970
NFPA 704
1
2 1

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.18094 (1,3-Dioxolan-2-yl)-methyltriphenylphosphonium bromide for synthesis 52509-14-5 10G $141 2024-03-01 Buy
Sigma-Aldrich 223859 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide 98% 52509-14-5 5g $71.2 2023-01-07 Buy
TCI Chemical D2164 (1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide >97.0%(T) 52509-14-5 5g $42 2024-03-01 Buy
TCI Chemical D2164 (1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide >97.0%(T) 52509-14-5 25g $144 2024-03-01 Buy
Alfa Aesar A18882 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98% 52509-14-5 10g $66.65 2024-03-01 Buy
Product number Packaging Price Buy
8.18094 10G $141 Buy
223859 5g $71.2 Buy
D2164 5g $42 Buy
D2164 25g $144 Buy
A18882 10g $66.65 Buy

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Chemical Properties,Uses,Production

Chemical Properties

white to light brown granular powder

Uses

Reactant for:

  • Preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione
  • Microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II
  • Preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands
  • Synthesis and antitumor agents
  • Regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization

Uses

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium Bromide is used as a reactant in the synthesis of ketolides methyloxoerythromycins with antibacterial activity as highly potent against macrolide-resistant and susceptible respiratory pathogens.

Purification Methods

Wash the crystals with Et2O, dry them in a vacuum and recrystallise them from CH2Cl2/dry Et2O to give prisms m 172-174o, which is raised to 191.5-193o on drying at 56o/0.5mm. [Cresp et al. J Chem Soc, Perkin Trans 1 37 1974.]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 246)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 16799 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15965 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9342 55
JingJiang Connect Chemical manufacturing Co., Ltd.
0523-80501690 15252623102 andy@katchemical.com CHINA 59 55
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2995 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5601 58

View Lastest Price from (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
((1,3-Dioxolan-2-yl)methyl)triphenylphosphonium bromide pictures 2024-01-14 ((1,3-Dioxolan-2-yl)methyl)triphenylphosphonium bromide
52509-14-5
US $8.00-0.60 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide pictures 2023-04-06 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
52509-14-5
US $0.00-0.00 / kg 1kg 98.0% 1000kg LY Global chemicals co.,ltd .
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide pictures 2023-02-09 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
52509-14-5
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
LABOTEST-BB LT00233112 (1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE (1,3-DIOXOLANE-2-YL METHYL) TRIPHENYL PHOSPHONIUM BROMIDE TRIPHENYL-1,3-DIOXOLAN-2-YLMETHYL-PHOSPHONIUM BROMIDE 2-(1,3)-DIOXOLANE-2-YL-METHYLTRIPHENYLPHOSPHONIUM BROMIDE (1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE 98% (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98 % Phosphonium, (1,3-dioxolan-2-ylmethyl)triphenyl-, bromide 1,3-Dioxolan-2-ylmethyl-triphenylphosphanium bromide Triphenyl(1,3-dioxolane-2-ylmethyl)phosphonium·bromide (1,3-DIOXOLAN-2-YL)-METHYLTRIPHENYLPHOSP 2-(1,3)-DIO OMTPPB (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%, for synthesis (1,3-Dioxolan-2-yl)methyltriphenylphosphoniumBromide> N-1-NaphthylethylenediamineDihydrochlorideMonomethanolate> 96.0%(T) Amyl 4-Carboxyphenyl Carbonate > 1,3-dioxolan-2-ylmethyl(triphenyl)phosphanium 52509-14-5 C22H22BrO2P C22H22O2PBr C22H24BrO2P Wittig Reaction Phosphonium Compounds C-C Bond Formation Wittig Reagents Synthetic Reagents Olefination Wittig & Horner-Emmons Reaction Dioxanes & Dioxolanes Dioxolanes Dioxanes & Dioxolanes Dioxolanes Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction C-C Bond Formation Olefination Wittig Reagents