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Copper(I) Cyanide

Chemical Properties Uses Preparation
Copper(I) Cyanide
Copper(I) Cyanide structure
CAS No.
544-92-3
Chemical Name:
Copper(I) Cyanide
Synonyms
Cu(CN);CUPRICIN;ai3-28745;CUCURBITACINA;COPPER CYANIDE;Cyanocopper(I);CUPROUS CYANIDE;Coprous cyanide;COPPER(+1)CYANIDE;COPPER(I) CYANIDE
CBNumber:
CB0193966
Molecular Formula:
CCuN
Formula Weight:
89.56
MOL File:
544-92-3.mol

Copper(I) Cyanide Properties

Melting point:
474 °C(lit.)
Boiling point:
decomposes [STR93]
Density 
2.92 g/mL at 25 °C(lit.)
storage temp. 
Poison room
form 
Powder
Specific Gravity
2.92
color 
White-beige to greenish
Water Solubility 
Practically insoluble in water and alcohol. Soluble in ammonium hydroxide, aqueous ammonia, pyridine and N-methylpyrrolidone.
Sensitive 
air sensitive
Merck 
14,2661
Solubility Product Constant (Ksp)
pKsp: 19.46
BRN 
3587244
Exposure limits
TLV-TWA 1 mg Cu/m3 (ACGIH).
Stability:
Stable. Incompatible with acids, bases, magnesium. Reacts violently with oxidizing agents, nitrates. Reaction with acid releases highly toxic gas (HCN).
CAS DataBase Reference
544-92-3(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
534K22856J
EPA Substance Registry System
Copper(I) cyanide (544-92-3)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS06,GHS09
Signal word  Danger
Hazard statements  H400-H300-H310-H330-H410-H300+H310+H330
Precautionary statements  P301+P310a-P304+P340-P320-P330-P405-P501a-P260-P264-P273-P280-P284-P301+P310
Hazard Codes  T+,N,T
Risk Statements  26/27/28-32-50/53
Safety Statements  7-28-29-45-60-61-28A
RIDADR  UN 1587 6.1/PG 2
WGK Germany  2
RTECS  GL7150000
10-23
TSCA  Yes
HS Code  2837 19 00
HazardClass  6.1
PackingGroup  II
NFPA 704
0
2 0

Copper(I) Cyanide price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.41811 Copper(I) cyanide for synthesis 544-92-3 100 g $31.63 2021-03-22 Buy
Sigma-Aldrich 216305 Copper(I) cyanide 99% 544-92-3 5g $50.6 2021-03-22 Buy
Sigma-Aldrich 216305 Copper(I) cyanide 99% 544-92-3 100g $54.4 2021-03-22 Buy
Sigma-Aldrich 8.41811 Copper(I) cyanide for synthesis 544-92-3 500 g $100.82 2021-03-22 Buy
Sigma-Aldrich 8.41811 Copper(I) cyanide for synthesis 544-92-3 1 kg $132.27 2021-03-22 Buy

Copper(I) Cyanide Chemical Properties,Uses,Production

Chemical Properties

Copper(I) cyanide, CuCN, [544-92-3], MW 89.56, MP 474°C, d 2.92, is white when pure, but usually available as an off-white or cream-colored powder and is insoluble in water and dilute acids but dissolves in complexing media such as ammonia and alkali cyanide solutions. It is produced by the reaction of sodium cyanide with copper(I) chloride solutions or by the reaction of copper(II) sulfate solutions with alkali cyanide and sodium hydrogen sulfite. It is used extensively in the electroplating industry and as a polymerization catalyst in organic reactions.

Uses

Copper(I) cyanide is used in copper plating of nickel, chromium, zinc alloys, steel, and other metals or alloys. Such copper plating imparts brightness, smoothness, hardness, and strength. The cyanide solution employed for copper electroplating consists of copper cyanide and sodium cyanide. Other applications of this compound are as an insecticide, a catalyst in polmerization, and as an antifouling agent in marine paints.

Preparation

Copper(I) cyanide is a precipitate obtained by adding potassium cyanide solution to an aqueous solution of Cu2+ salt:
COPPER(I) CYANIDE 2652CuCl2 + 4KCN → 2CuCN + C2N2 + 4KCl
The Cu2+ to CN¯ molar ratio should be 1:2. The precipitate dissolves in an excess of cyanide, forming soluble ions Cu(CN)2¯ , Cu(CN)32¯, and Cu(CN)43¯.

Description

off-white to green powder. Insoluble in water,soluble in HCI, Nl40H, and potassium cyanide. Used in Sandmeyer's reaction to synthesize aryl cyanides. Toxic by skin absorption, through open wounds, by ingestion, and by inhalation of hydrogen cyanide that arises from slight decomposition. Produces toxic oxides of nitrogen in fires.

Chemical Properties

Cuprous cyanide is a white crystalline substance.

Physical properties

Cream-colored powder or green orthorhombic or red monoclinic crystals; density 2.90 g/cm3; melts at 474°C; decomposes at higher temperatures; practically insoluble in water, ethanol, and cold dilute acids; dissolves in ammonium hydroxide and potassium cyanide solutions.

Uses

Cuprous cyanide is used in electroplating; as an insecticide and fungicide; and as a catalyst for polymerization.

Uses

In electroplating Cu or Fe; as insecticide, fungicide; as antifouling agent in marine paints; as polymerization catalyst.

Reactivity Profile

Copper(I) Cyanide is decomposed by acids to give off hydrogen cyanide, a flammable poisonous gas. Tends to explosive instability. Capable of violent oxidation under certain condition: fusion with metal chlorates, perchlorates, nitrates or nitrites can cause explosions [Bretherick, 1979 p. 101]. Reacts with incandescence with magnesium [Mellor, 1940, Vol. 4, 271].

Hazard

Poison.

Health Hazard

Cuprous cyanide is a highly toxic substance. The toxic routes are inhalation of dust, ingestion, and skin contact. Toxicology and LD50 values for this compound are not reported. Because it is slightly soluble in water, its dissociation to cuprous and cyanide ions in the body may not be significant. The role of cyanide ion in the toxicity of cuprous cyanide is not established. The inhalation hazard, however, is attributable to copper. It is a skin irritant.

Fire Hazard

Special Hazards of Combustion Products: Toxic hydrogen cyanide gas may form in fires.

Safety Profile

A poison. Reacts violently with magnesium. When heated to decomposition it emits very toxic CNand NOx. See also CYANIDE and COPPER COMPOUNDS.

Potential Exposure

Copper cyanide is used in electroplating copper on iron; and as an insecticide and a catalyst.

Shipping

UN1587 Copper cyanide, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Purification Methods

Wash the cyanide thoroughly with boiling H2O, then with EtOH. Dry it at 100o to a fine soft powder. It dissolves in excess alkali cyanide solutions to form the very soluble complex ion Cu(CN)43-. [Bassett & Corbett J Chem Soc 125 1660 1924, Barber J Chem Soc 79 1943.]

Incompatibilities

Contact with heat, strong acids (HCl, H2SO4, HNO3) forms deadly hydrogen cyanide gas. May release hydrogen cyanide on contact with moisture. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acetylene gas, and chemically active metals, such as potassium, sodium, magnesium, and zinc.

Waste Disposal

Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill. Copper-containing wastes can be concentrated to the point where copper can be electrolytically removed and reclaimed. If recovery is not feasible, the copper can be precipitated by alkali; the cyanide destroyed by alkaline oxidation yielding a sludge which can be sent to a chemical waste landfill. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Copper(I) Cyanide Preparation Products And Raw materials

Raw materials

Preparation Products


Copper(I) Cyanide Suppliers

Global( 159)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Chongqing Chemdad Co.,Ltd
+86-19923101450
sales@chemdad.com CHINA 4000 58
Hubei xin bonus chemical co. LTD
86-13657291602
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Chongqing Chemdad Co., Ltd
+86-13650506873
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Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63726 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
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CONIER CHEM AND PHARMA LIMITED
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career henan chemical co
13203830695 0086-371-86658258
0086-371-86658258 factory@coreychem.com CHINA 29865 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072 (WhatsApp)
Wechat: +8613111626072 Wickr me: waynehu zzwenxi@126.com CHINA 13187 58
Antai Fine Chemical Technology Co.,Limited
18503026267
info@antaichem.com CHINA 9664 58

View Lastest Price from Copper(I) Cyanide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-12 COPPER(I) CYANIDE
544-92-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2020-07-05 Copper(I) Cyanide
544-92-3
US $885.00 / KG 1KG 98.0% 1T Shaanxi Dideu Medichem Co. Ltd
2019-12-25 COPPER(I) CYANIDE
544-92-3
US $1.00 / KG 1IU 99% 100kg Career Henan Chemical Co

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