ChemicalBook >> CAS DataBase List >>4-Chlorophenylboronic acid
4-Chlorophenylboronic acid
- CAS No.
- 1679-18-1
- Chemical Name:
- 4-Chlorophenylboronic acid
- Synonyms
- 4-CHLOROBENZENEBORONIC ACID;AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid
- CBNumber:
- CB0307561
- Molecular Formula:
- C6H6BClO2
- Molecular Weight:
- 156.37
- MDL Number:
- MFCD00039137
- MOL File:
- 1679-18-1.mol
- MSDS File:
- SDS
Modify Date:2023-05-11
| Melting point | 284-289 °C(lit.) |
|---|---|
| Boiling point | 295.4±42.0 °C(Predicted) |
| Density | 1.32±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | DMSO |
| pka | 8.39±0.10(Predicted) |
| form | Crystalline Powder |
| color | Off-white to beige |
| Water Solubility | 2.5 g/100 mL |
| BRN | 2936346 |
| InChI | InChI=1S/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H |
| InChIKey | CAYQIZIAYYNFCS-UHFFFAOYSA-N |
| SMILES | B(C1=CC=C(Cl)C=C1)(O)O |
| CAS DataBase Reference | 1679-18-1(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | AB2T8N4T4C |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302 | |||||||||
| Precautionary statements | P301+P312+P330 | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 36-37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | CY8950000 | |||||||||
| TSCA | No | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
4-Chlorophenylboronic acid price More Price(50)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 417548 | 4-Chlorophenylboronic acid 95% | 1679-18-1 | 1g | $35 | 2023-01-07 | Buy |
| Sigma-Aldrich | 417548 | 4-Chlorophenylboronic acid 95% | 1679-18-1 | 10g | $114 | 2023-01-07 | Buy |
| TCI Chemical | C1473 | 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) | 1679-18-1 | 5g | $47 | 2023-01-07 | Buy |
| TCI Chemical | C1473 | 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) | 1679-18-1 | 25g | $136 | 2023-01-07 | Buy |
| Alfa Aesar | A15657 | 4-Chlorobenzeneboronic acid, 98+% | 1679-18-1 | 1g | $20.16 | 2023-01-06 | Buy |
4-Chlorophenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
off-white to beige crystalline powder
Chemical Properties
4-Chlorophenylboronic acid is white or off-white crystalline powder. It has certain solubility in water and is soluble in strong polar organic solvents such as dimethyl sulfoxide, but insoluble in ether solvents. It has similar chemical properties to phenylboronic acid.
Uses
4-Chlorophenylboronic acid can be used as a reactant in:
- Palladium-catalyzed direct arylation.
- Cyclopalladation.
- Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
- Copper-mediated ligandless aerobic fluoroalkylation.
- Pd-catalyzed arylative cyclization.
- Ruthenium catalyzed direct arylation.
- Ligand-free copper-catalyzed coupling reactions.
- Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.
It can also be used to prepare:
- Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
- Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
- Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
- Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.
Uses
4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.
Uses
suzuki reaction
Synthesis of 4-Chlorophenylboronic acid from Benzeneboronic acid, p-chloro-, diisobutyl ester (6CI) and Water
4-Chlorophenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
6-(4-CHLOROPHENYL)PYRIDINE-2-CARBALDEHYDE
2-chloro-4-(4-chlorophenyl)-6-phenyl-1,3,5-triazine
Fenofibric acid
AZD4320
4'-CHLORO-BIPHENYL-4-YLAMINE
1of3
Global( 651)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Maison Chemical Co.,Ltd. | +8615511852758 | sales@maisonchem.com.cn | China | 451 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52877 | 58 |
| ZHEJIANG ESTCHEM CO.,LTD | 15957180504 | sales@zjestchem.com | China | 193 | 58 |
| Yurui (Shanghai) Chemical Co., Ltd. | +86-021-50456736 +8615000292053 | sales209@riyngroup.com | China | 458 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29810 | 60 |
| Henan DaKen Chemical CO.,LTD. | +86-371-66670886 | info@dakenchem.com | China | 18267 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21975 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 31813 | 60 |
View Lastest Price from 4-Chlorophenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-05-04 | 4-Chlorophenylboronic acid
1679-18-1
|
US $48.00 / KG | 1KG | 99% | 200tons | Guangzhou Sunton Biotechnology Co., Ltd. | |
 |
2023-02-09 | 4-Chlorophenylboronic acid
1679-18-1
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2022-12-23 | 4-Chlorophenylboronic acid
1679-18-1
|
US $171.80 / KG | 1g | 99% | 10Tons | Baoji Guokang Bio-Technology Co., Ltd. |
-
- 4-Chlorophenylboronic acid
1679-18-1
- US $48.00 / KG
- 99%
- Guangzhou Sunton Biotechnology Co., Ltd.
-
- 4-Chlorophenylboronic acid
1679-18-1
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- 4-Chlorophenylboronic acid
1679-18-1
- US $171.80 / KG
- 99%
- Baoji Guokang Bio-Technology Co., Ltd.
1679-18-1(4-Chlorophenylboronic acid)Related Search:
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1of4
4-Chlorophenylboronic acid,97%
4-Chlorophenylboronic acid, May contain varying amounts of anhydride, 97%
4-Chlorophenylboronic acid,4-Chlorobenzeneboronic acid
p-chlorophenylboronic aci
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4-Chlorophenylboronic acid, 97% 5GR
NSC 25408
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p-chloro-benzeneboronicaci
(p-chlorophenyl)metaboric acid
4-Chlorophenylboronicacid,min.97%
4-CHLOROBENZENEBORONIC ACID / 4-CHLOROPHENYLBORONIC ACID
PARACHLOROPHENYLBORONIC ACID
4-Chlorophenylboronic acid ,98%
4-Chlorophenylboronic acid, min. 97%
(4-Chlorophenyl)boranic acid
4-Chlorophenylboranic acid
4-Chlorophenylboron dihydoxide
4-Chlorobenzeneboronic acid, 98+%
4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
4-Chlorophenylbronic Acid
The effects of boric acid
4-Chlorophenylboronic acid 95%
AC 34441
Benzeneboronic acid, p-chloro-
WLN: QBQR DG
B-(4-Chlorophenyl)boronic acid
BORONIC ACID, (4-CHLOROPHENYL)-
AKOS BRN-0011
4-CHLOROPHENYLBORNIC ACID
4-CHLOROPHENYLBORONIC ACID
P-CHLOROPHENYLBORONIC ACID
P-CHLORO BENZENE BORONIC ACID
RARECHEM AH PB 0178
boronicacid,p-chlorophenyl
orobenzeneboronic Acid
4-Chlorophenylboronic acid,99%
Boronic acid, B-(4-chlorophenyl)-
4-Chlorophenylboronic Acid extrapure, 97%
4-CHLOROBENZENEBORONIC ACID
4-Chlorophenylboornic acid
4-Chlorophenylboronic acid supplier in China CAS NO.1679-18-1 CAS NO.1679-18-1
13C6]-4-Chlorobenzeneboronic acid
1679-18-1
1679-81-1
B (Classes of Boron Compounds)
Boronic Acids
Organometallic Reagents
Boronic Acids and Derivatives
Aryl
blocks
BoronicAcids
Boronic Acid series
Fluorin-contained phenyl boronic acid series
Heterocyclic Compounds
Boronic Acid
Aryl
Organoborons