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Trichlorofluoromethane

CAS No.
75-69-4
Chemical Name:
Trichlorofluoromethane
Synonyms
CFCl3;CFC-11;CCl3F;TRICHLOROMONOFLUOROMETHANE;f11;f-11;Trichlorfluormethan;FLUOROTRICHLOROMETHANE;Methane, trichlorofluoro-;f11b
CBNumber:
CB1127379
Molecular Formula:
CCl3F
Molecular Weight:
137.37
MDL Number:
MFCD00000784
MOL File:
75-69-4.mol
MSDS File:
SDS
Modify Date:
2022-08-15 17:38:38

Trichlorofluoromethane Properties

Melting point -111°C
Boiling point 23.8°C
Density 1.494
vapor density 5.04 (vs air)
vapor pressure 12.85 psi ( 20 °C) &_& 39.17 psi ( 55 °C)
refractive index 1.382
Flash point 2 °C
storage temp. 2-8°C
solubility water: soluble1g/L
form neat
color Colorless, odorless liquid
Odor Odorless; weak chlorinated solvent.
Water Solubility insoluble. 0.124 g/100 mL
Merck 13,9714
BRN 1732469
Henry's Law Constant At 25 °C: 88.2 and 123 in distilled water and seawater, respectively (Hunter-Smith et al., 1983)
Exposure limits NIOSH REL: ceiling 1,000 ppm (5,600 mg/m3), IDLH 2,000 ppm; OSHA PEL: TWA 1,000 ppm; ACGIH TLV: ceiling 1,000 ppm (adopted).
Stability Stable. Incompatible with bronze, silver, copper, beryllium, alkali and alkaline earth metals.
InChIKey CYRMSUTZVYGINF-UHFFFAOYSA-N
CAS DataBase Reference 75-69-4(CAS DataBase Reference)
FDA 21 CFR 701.30
EWG's Food Scores 1
FDA UNII 990TYB331R
NIST Chemistry Reference Trichloromonofluoromethane(75-69-4)
EPA Substance Registry System CFC-11 (75-69-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08
Signal word  Danger
Hazard statements  H302-H315-H319-H331-H336-H351-H361d-H372-H420
Precautionary statements  P301+P312-P302+P352-P304+P340+P311-P305+P351+P338-P308+P313-P502
Hazard Codes  Xn;N,Xi,N,Xn,T,F
Risk Statements  20-59-23-21/22-36/37/38-20/22-11-23/25-39/23/24/25-23/24/25-21-67-66-36
Safety Statements  23-24/25-59-61-45-36/37-36-26-16-24-7
RIDADR  3082
WGK Germany  3
RTECS  PB6125000
Hazard Note  Irritant
Toxicity Drinking water standard: No MCLGs or MCLs have been proposed although trichlorofluoromethane has been listed for regulation (U.S. EPA, 1996). A DWEL of 100 μg/L was recommended (U.S. EPA, 2000).
IDLA 2,000 ppm
NFPA 704
0
1 0

Trichlorofluoromethane price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 710717 Trichlorofluoromethane solution NMR reference standard, 10% in acetone-d6 (99.9 atom % D), 1,2-dichloro-1,1-difluoroethane 1?%, TMS 6?% 75-69-4 1pkg $313 2022-05-15 Buy
Sigma-Aldrich 612715 Trichlorofluoromethane solution NMR reference standard, 50% in chloroform-d (99.8 atom % D), NMR tube size 5?mm × 8?in. 75-69-4 1EA $281 2022-05-15 Buy
Sigma-Aldrich 254991 Trichlorofluoromethane ≥99.5% 75-69-4 100ml $80.6 2022-05-15 Buy
Sigma-Aldrich 48541 Trichlorofluoromethane analytical standard 75-69-4 5000mg $164 2022-05-15 Buy
Sigma-Aldrich 254991 Trichlorofluoromethane ≥99.5% 75-69-4 800ml $291 2022-05-15 Buy
Product number Packaging Price Buy
710717 1pkg $313 Buy
612715 1EA $281 Buy
254991 100ml $80.6 Buy
48541 5000mg $164 Buy
254991 800ml $291 Buy

Trichlorofluoromethane Chemical Properties,Uses,Production

Description

Trichlorofluoromethane is a chlorofluorocarbon (CFC) which is commonly used as a refrigerant, a foaming or blowing agent in industry, a solvent, an aerosol propellant, and in chemical syntheses.
Trichlorofluoromethane is a colorless, odorless gas at normal temperatures and pressures. Under high pressures as in cans, tanks or refrigerators it is in liquid form. When released from a pressurized container it evaporates almost instantly and can cause freezing at the point of release. At very high concentrations in air it may smell like ether. It is slightly soluble in water but evaporates quickly if exposed to air. The chemical formula for Trichlorofluoromethane is CFCL3.

Chemical Properties

Fluorotrichloromethane is a colorless liquid or gas. Chlorinated solvent odor. The Odor Threshold is 5.0 ppm.

Occurrence

Trichlorofluoromethane is man-made and its presence in the environment is due to releases from common household and industrial uses. It is extremely stable in the atmosphere and does not degrade naturally. It can also be produced as an industrial by-product wherever chlorine products are used; including small quantities which are formed by reaction of chlorine disinfectants with organic pollutants in water. It is released into the air by leaking refrigeration units and air conditioners and by spray paint, spray varnish, spray cosmetics and other sprays in which it has been used as a propellant. Since 1978 many uses of trichlorofluoromethane as a propellant have been prohibited by law in the U.S. It can still be used as a propellant in some specialized products used in businesses and industries. It may also be found in air emissions and waste waters from a number of industries particularly refrigeration, electronics and foam manufacturing.

Uses

Trichlorofluoromethane is a coolant in conditioning systems. It is a bulking agent for polymer foams. It is also used as a degrease solvent for printed circuit boards and to dry clean textiles. It is used as an aerosol propellant in various industries.

Uses

Aerosol propellant; refrigerant and blowing agent; solvent for cleaning and degreasing.

Uses

In refrigeration machinery requiring a refrigerant effective at negative pressures. As aerosol propellant.

Definition

ChEBI: A one-carbon compound that is methane in which the hydrogens have been replaced by three chlorine and one fluorine atom.

General Description

A clear light colored liquid. Nearly odorless. Denser than water. Poses low acute health hazard to humans. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.

Air & Water Reactions

Water soluble. Hydrolyzed slowly.

Reactivity Profile

Trichlorofluoromethane is incompatible with alkali or alkaline earth metals, powdered aluminum, zinc and beryllium. Trichlorofluoromethane reacts violently with barium and lithium.

Health Hazard

Breathing concentrations approaching 10% in air will cause dizziness and drowsiness. Contact with tissues may cause frostbite.

Fire Hazard

Special Hazards of Combustion Products: Produces irritating and toxic products when heated to decomposition temperatures.

Chemical Reactivity

Reactivity with Water: No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

High concentrations cause narcosis and anesthesia in humans. Human systemic effects by inhalation: conjunctiva irritation, fibrosing alveolitis, and liver changes. Experimental poison by inhalation. Moderately toxic by intraDeritoneal route. Reacts violentlv with I aluminum, barium, or lithium. When heated to decomposition it emits highly toxic fumes of Fand Cl-. Used as an aerosol propellant, refrigerant, and blowing agent for polymeric foams. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.

Potential Exposure

This material is used as a refrigerant; aerosol propellant; and foaming agent; as blowing agent in production of polyurethane foams.

Carcinogenicity

When administered by gavage to groups of 50 male and 50 female mice at daily doses of 1962 or 3952mg/kg, 5 days/week for 78 weeks followed by a 13week observation period, there was no evidence of carcinogenicity. Also,when given to rats at daily doses of 488 and 977mg/kg for males and 538 and 1077mg/kg for females, again for 5 days/week for 78 weeks, but followed by a 28–33 week observation period, there was no evidence of carcinogenicity. Maltoni et al. exposed groups of 90 male and 90 female Sprague–Dawley rats and groups of 60 male and 60 female Swiss mice by inhalation to levels of 1000 and 5000 ppm 4 h/day, 5 days/week for life. The exposures did not produce evidence of carcinogenicity.

Environmental Fate

Biological. In a static-culture-flask screening test, trichlorofluoromethane was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum. No significant degradation was observed after 28 d of incubation. At substrate concentrations of 5 and 10 mg/L, percent losses due to volatilization were 58 and 37% after 10 d (Tabak et al., 1981).
Chemical/Physical. When trichlorofluoromethane (50 μg/L) in an ultrasonicator was exposed to 20-kHz ultrasound at 5 °C, nearly 100% degradation was achieved after 6 min. During sonication, the pH of the aqueous solution decreased, which is consistent with the formation of HCl, hydrofluoric acid, and acidic species from fluorine and chlorine. In this experiment <5% of trichlorofluoroethane was lost to volatilization (Cheung and Kurup, 1994).

Shipping

Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas, Technical Name Required.

Incompatibilities

Chemically active and powdered metals: aluminum, barium, sodium, potassium, calcium, powdered aluminum; zinc, magnesium.

Waste Disposal

Incineration, preferably after mixing with another combustible fuel. Care must be exer cised to assure complete combustion to prevent the forma tion of phosgene. An acid scrubber is necessary to remove the halo acids produced. Consult with environmental regu latory agencies for guidance on acceptable disposal prac tices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations govern ing storage, transportation, treatment, and waste disposal.

View Lastest Price from Trichlorofluoromethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2022-05-17 Trichlorofluoromethane
75-69-4
US $1.20 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
2021-08-12 Trichlorofluoromethane
75-69-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2019-07-10 Trichlorofluoromethane
75-69-4
US $3.00 / KG 1KG 99% 100kg Career Henan Chemical Co
Algofrene Type 1 algofrenetype1 Arcton 11 Arcton 9 arcton11 arcton9 Asahifron11 caswellno.878 Chladone11 Chlorofluoromethane (CCl3F) Daiflon 11 Daiflon S 1 Daiflon11 DaiflonS1 Distillex DS6 Dymel11 Electro-CF 11 f11b FC 11 FC 11, Halocarbon fc11 fc-11 FC11(halocarbon) FKW 11 fkw11 Fluon11 fluorocarbonno.11 Fluorochloroform fluorotrichloro-methan fluorotrichloromethane (Freon 11) fluorotrojchlorometan fluorotrojchlorometan(polish) Fluortrichlormethan Freon MF freon11a freon11b freonhe freonmf Frigen 11 Frigen 11A Frigen S 11 frigen11 Frigen11A FrigenS11 Fron11 Genesolv a solvent Genetron 11 CFC-11, Fluorotrichloromethane, Freon(R) 11 Butaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester tert-Butyl peroxy-2-ethylbutyrate Trigonox 27 Trichlorofluoromethane (in cylinder without valve) [To use this product charged in cylinder, a valve is required which is sold separately (Product Code:V0030)] Fluorotrichloromethane, NMR grade,99.5+% Trichlorofluoromethane (in cylinder without valve) Trichlorofluoromethane 1g [75-69-4] Khladon 11 khladon11 Ledon 11