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4-Nitrobenzoyl chloride

4-Nitrobenzoyl chloride
4-Nitrobenzoyl chloride structure
CAS No.
122-04-3
Chemical Name:
4-Nitrobenzoyl chloride
Synonyms
PNBC;4-Nitrobenzoyl;4-Nitrobenzoyl chlor;p-Nitrobenzoyl chlori;LABOTEST-BB LT00077260;4-nitro-benzoylchlorid;p-nitro-benzoylchlorid;NITROBENZOYL-4 CHLORIDE;P-NITROBENZOYL CHLORIDE;4-NITROBENZOYL CHLORIDE
CBNumber:
CB2182076
Molecular Formula:
C7H4ClNO3
Formula Weight:
185.56
MOL File:
122-04-3.mol

4-Nitrobenzoyl chloride Properties

Melting point:
71-74 °C(lit.)
Boiling point:
202-205 °C105 mm Hg(lit.)
Density 
1.53
refractive index 
1.5890 (estimate)
Flash point:
102 °C
storage temp. 
Store below +30°C.
solubility 
Soluble in terahydrofuran, dichloromethane, chloroform and pyridine.
form 
Flakes or Crystals
color 
Yellow
Water Solubility 
Decomposes
Sensitive 
Moisture Sensitive
Merck 
14,6589
BRN 
473192
Stability:
Stability Stable, but moisture sensitive. Combustible. Incompatible with water, alcohols, strong oxidizing agents, strong bases.
InChIKey
SKDHHIUENRGTHK-UHFFFAOYSA-N
CAS DataBase Reference
122-04-3(CAS DataBase Reference)
NIST Chemistry Reference
4-Nitrobenzoic acid chloride(122-04-3)
EPA Substance Registry System
Benzoyl chloride, 4-nitro-(122-04-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  2
RTECS  DM6651000
9-19-21
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29163900
Toxicity LD50 orally in Rabbit: 5600 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P390 Absorb spillage to prevent material damage.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P501 Dispose of contents/container to..…

4-Nitrobenzoyl chloride price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 112208 4-Nitrobenzoyl chloride 98% 122-04-3 50g $32.9 2018-11-13 Buy
Sigma-Aldrich 112208 4-Nitrobenzoyl chloride 98% 122-04-3 250g $75.8 2018-11-13 Buy
TCI Chemical N0176 4-Nitrobenzoyl Chloride >98.0%(GC)(T) 122-04-3 25g $14 2018-11-22 Buy
TCI Chemical N0176 4-Nitrobenzoyl Chloride >98.0%(GC)(T) 122-04-3 500g $62 2018-11-22 Buy
Alfa Aesar A12543 4-Nitrobenzoyl chloride, 98% 122-04-3 250g $39.7 2018-11-13 Buy

4-Nitrobenzoyl chloride Chemical Properties,Uses,Production

Chemical Properties

yellow needles or powder

Uses

4-Nitrobenzoyl Chloride is used inorganic syntheses such as Michael additions. Also used in the synthesis of polysubstituted furanonaphthoquinoines.

General Description

Yellow needles or powder with a pungent odor.

Air & Water Reactions

Unstable in moist surroundings and should be kept in a tightly-closed container. React with water or steam .

Reactivity Profile

4-Nitrobenzoyl chloride is incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react with reducing agents. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Flash point data are not available for 4-Nitrobenzoyl chloride, but 4-Nitrobenzoyl chloride is combustible.

Safety Profile

Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx and Cl-. See also NITRO COhlPOUNDS OF AROMATIC HYDROCARBONS and CHLORIDES.

Purification Methods

Crystallise the acid chloride from dry pet ether (b 60-80o), *C6H6 or CCl4. Distil it under vacuum. Irritant. [Adama & Jenkins Org Synth Coll Vol I 394 1941, Beilstein 9 III 1709, 9 IV 1191.]

4-Nitrobenzoyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products


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Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-04 4-Nitrobenzoyl chloride
122-04-3
US $500.00 / KG 1KG 98% 1ton career henan chemical co

4-Nitrobenzoyl chloride Spectrum


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