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Methyl propiolate

CAS No.
922-67-8
Chemical Name:
Methyl propiolate
Synonyms
4-Methoxy-4-oxobut-2-ynoic acid;PROPYNOIC ACID, METHYL ESTER;HCequivCCOOCH3;METHYL PROPYNOATE;METHYL PROPIOLATE;Methyl propinoate;METHYPROPIOLATE,99%;Methyl propargylate;MethylPropiolate>Sucrose Impurity 14
CBNumber:
CB3155439
Molecular Formula:
C4H4O2
Molecular Weight:
84.07
MDL Number:
MFCD00008572
MOL File:
922-67-8.mol
MSDS File:
SDS
Last updated:2024-04-25 13:42:50

Methyl propiolate Properties

Melting point 171-173 °C
Boiling point 103-105 °C (lit.)
Density 0.945 g/mL at 25 °C (lit.)
refractive index n20/D 1.408(lit.)
Flash point 50 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Methanol (Sparingly)
form Liquid
Specific Gravity 0.9450
color Clear colorless
Water Solubility Not miscible in water.
BRN 605462
Stability Stable. Highly flammable. Incompatible with strong oxidizing agents, bases, acids.
InChIKey IMAKHNTVDGLIRY-UHFFFAOYSA-N
CAS DataBase Reference 922-67-8(CAS DataBase Reference)
FDA UNII T88NXO102K
NIST Chemistry Reference 2-Propynoic acid, methyl ester(922-67-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-36/37/38-36
Safety Statements  26-36-36/37/39-23-16-33-7/9
RIDADR  UN 3272 3/PG 2
WGK Germany  3
RTECS  UE0050000
19
Hazard Note  Highly Flammable/Harmful
HazardClass  3
PackingGroup  II
HS Code  29161980
NFPA 704
3
2 0

Methyl propiolate price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 171859 Methyl propiolate 99% 922-67-8 2.5g $55.6 2024-03-01 Buy
Sigma-Aldrich 171859 Methyl propiolate 99% 922-67-8 10g $110 2024-03-01 Buy
TCI Chemical P0528 Methyl Propiolate >98.0%(GC) 922-67-8 5mL $40 2024-03-01 Buy
TCI Chemical P0528 Methyl Propiolate >98.0%(GC) 922-67-8 25mL $162 2024-03-01 Buy
Alfa Aesar A14743 Methyl propiolate, 99% 922-67-8 5g $59.1 2024-03-01 Buy
Product number Packaging Price Buy
171859 2.5g $55.6 Buy
171859 10g $110 Buy
P0528 5mL $40 Buy
P0528 25mL $162 Buy
A14743 5g $59.1 Buy

Methyl propiolate Chemical Properties,Uses,Production

Chemical Properties

colourless to light yellow liquid

Uses

Methyl propiolate was used in the synthesis of polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives. It was also used as a thiol derivatizing agent for capillary electrophoresis.

Purification Methods

Purify the propiolate by fractional distillation and collecting the middle fraction, note that propiolic acid has a high b [144o(dec)/760mm]. [Beilstein 2 IV 1688.] LACHRYMATORY.

124-38-9
922-67-8
922-67-8
Synthesis of Methyl propiolate from Carbon dioxide and Methyl propiolate
Global( 413)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Capot Chemical Co.,Ltd.
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hefei TNJ Chemical Industry Co.,Ltd.
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Changzhou Ansciep Chemical Co., Ltd.
+86 519 86305871 sales@ansciepchem.com CHINA 4242 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
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15982321820 abby@arkpharm.com CHINA 3279 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58

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View Lastest Price from Methyl propiolate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl propiolate pictures 2024-04-25 Methyl propiolate
922-67-8
US $10.00 / kg 1kg 99.8% 10000ton Ouhuang Engineering Materials (Hubei) Co., Ltd
Methyl propiolate pictures 2023-09-06 Methyl propiolate
922-67-8
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Methyl propiolate pictures 2023-06-28 Methyl propiolate
922-67-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
  • Methyl propiolate pictures
  • Methyl propiolate
    922-67-8
  • US $10.00 / kg
  • 99.8%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
  • Methyl propiolate pictures
  • Methyl propiolate
    922-67-8
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
METHYL PROPIOLATE METHYL PROPYNOATE METHYL ACETYLENECARBOXYLATE PROPARGYLIC ACID METHYL ESTER PROPIOLIC ACID METHYL ESTER Acetylenecarboxylic acid methyl ester acetylenecarboxylicacidmethylester HCequivCCOOCH3 Methyl ethynecarboxylate 2-propynoic acid methyl ester Methyl acetylenecarboxylate~Propiolic acid methyl ester~Propynoic acid methyl ester Methylpropiolate,99% METHYPROPIOLATE,99% (Methoxycarbonyl)acetylene Methyl acetylenemonocarboxylate Methyl propargylate Acetylene-1-carboxylic acid methyl ester Methyl propinoate Prop-2-ynoic acid=methyl Methyl propiolate, 99% 10GR Methyl propiolate, 99% 50GR Propiolic Acid Methyl Ester Propargylic Acid Methyl Ester 2-Propynoic acid, methyl ester (9CI) prop-2-ynoic acid methyl ester Methyl propiolate, 98.5% Methyl acetylenecarboxylate for synthesis Ppropiolic acid methyl aster METHYL PROPIOLATE, 98%METHYL PROPIOLATE, 98%METHYL PROPIOLATE, 98%METHYL PROPIOLATE, 98% Nitriloacetic acid methyl ester MethylPropiolate> PROPYNOIC ACID, METHYL ESTER 4-Methoxy-4-oxobut-2-ynoic acid Sucrose Impurity 14 Methylpropiolate, 98% (Custom work) 922-67-8 HC8801CCO2CH3 HCCCO2CH3 HCCCOOCH3 ESTER Acetylenes Acetylenic Carboxylic Acids & Their Derivatives Esters Organic Building Blocks Building Blocks C2 to C5 Carbonyl Compounds Pyridines pharmaceutical raw material Miscellaneous Aliphatics Esters Acetylenes Acetylenic Carboxylic Acids & Their Derivatives bc0001