BroModifluoroMethyl phenyl sulfone
- CAS No.
- 80351-58-2
- Chemical Name:
- BroModifluoroMethyl phenyl sulfone
- Synonyms
- BroModifluoroMethyl phenyl sulfone;Bromodifluoromethanesulfonylbenzene;[(bromodifluoromethyl)sulfonyl]benzene;Benzene, [(bromodifluoromethyl)sulfonyl]-
- CBNumber:
- CB42709701
- Molecular Formula:
- C7H5BrF2O2S
- Molecular Weight:
- 271.08
- MDL Number:
- MFCD22628354
- MOL File:
- 80351-58-2.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P280-P302+P352-P362+P364 |
| Safety Statements | 24/25 |
| HS Code | 29309090 |
BroModifluoroMethyl phenyl sulfone price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Frontier Specialty Chemicals | JK1711632 | Bromodifluoromethylphenylsulfone 98% | 80351-58-2 | 250mg | $72 | 2021-12-16 | Buy |
| Frontier Specialty Chemicals | JK1711632 | Bromodifluoromethylphenylsulfone 98% | 80351-58-2 | 1g | $217 | 2021-12-16 | Buy |
| Matrix Scientific | 130596 | Bromodifluoromethanesulfonylbenzene | 80351-58-2 | 1g | $684 | 2021-12-16 | Buy |
| AK Scientific | 8445AJ | Bromodifluoromethanesulfonylbenzene | 80351-58-2 | 1g | $973 | 2021-12-16 | Buy |
| Atlantic Research Chemicals | XS0011229 | Bromodifluoromethanesulphonylbenzene 95% | 80351-58-2 | 1gm: | $378.2 | 2021-12-16 | Buy |
BroModifluoroMethyl phenyl sulfone Chemical Properties,Uses,Production
Description
The nucleophilic reactions of bromodifluoromethyl phenyl sulfone with electrophiles such as aldehydes in the presence of TDAE affords (phenylsulfonyl)difluoromethyl-containing synthetically useful intermediates. Palladium-mediated reactions of styrene derivatives, vinyl ethers, and heteroaromatics with bromodifluoromethyl phenyl sulfone in the presence of potassium carbonate affords the (phenylsulfonyl)difluoromethylated products.
Uses
Bromodifluoromethyl phenyl sulfone is an intermediate component in the synthesis of (phenylsulfonyl)difluoromethyl and can be used to prepare (phenylsulfonyl)difluoromethylated products by palladium-mediated reactions.
Uses
Bromodifluoromethyl Phenyl Sulfone can be used to prepare difluoromethyl ethers via difluoromethylation of alcohols.
Reactions
(1) Difluoromethylation of aldehydes.
(2) Difluoromethylation of styrenes, vinyl ethers, and heteroaromatics.
References
[1] G.K. SURYA PRAKASH . Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone[J]. Journal of Fluorine Chemistry, 2005. DOI:10.1016/j.jfluchem.2005.07.011.
[2] NAKIN SURAPANICH. ChemInform Abstract: Palladium-Mediated Heck-Type Reactions of [(Bromodifluoromethyl)sulfonyl]benzene: Synthesis of α-Alkenyl- and α-Heteroaryl-Substituted α,α-Difluoromethyl Phenyl Sulfones.[J]. ChemInform, 2013. DOI:10.1002/chin.201314090.
BroModifluoroMethyl phenyl sulfone Preparation Products And Raw materials
BroModifluoroMethyl phenyl sulfone Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 11013 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Allfluoro pharmaceutical co. ltd. | 021-26137118 +8615821363818 | sales@allfluoro.com | China | 5791 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23556 | 58 |
| Jilin Chinese Academy of Sciences-yanshen Technology | +undefined18143011203 | info@chemextension.com | China | 42057 | 58 |
| Henan Aochuang Chemical Co.,Ltd. | +86-0371-63689365 +8618638391208 | sales@aochuangchem.com | China | 9425 | 58 |
| Shangfluoro | 021-021-65170832 13331983812 | qinba_2@163.com | China | 301 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| HANGZHOU HETE CHEMICAL TECHNOLOGY CO.,LTD | 571-89189769 15168342188 | China | 281 | 62 | |
| Daicel Chiral Technologies (China)CO.,LTD | 021-50460086-9 15921403865 | han_yajun@dctc.daicel.com | China | 6854 | 65 |
View Lastest Price from BroModifluoroMethyl phenyl sulfone manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-15 | Difluoromethyl sulfonylbenzene
80351-58-2
|
US $0.10-0.10 / kg | 0.005kg | 99.99% | 20 tons | Zibo Hangyu Biotechnology Development Co., Ltd | |
 |
2022-10-10 | BroModifluoroMethyl phenyl sulfone
80351-58-2
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2020-02-21 | BroModifluoroMethyl phenyl sulfone
80351-58-2
|
US $8.00 / KG | 1g | ＞98% HPLC | kg--ton | Career Henan Chemical Co |
-
- Difluoromethyl sulfonylbenzene
80351-58-2
- US $0.10-0.10 / kg
- 99.99%
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- BroModifluoroMethyl phenyl sulfone
80351-58-2
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- BroModifluoroMethyl phenyl sulfone
80351-58-2
- US $8.00 / KG
- ＞98% HPLC
- Career Henan Chemical Co