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ChemicalBook >> CAS DataBase List >>(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Structure
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% structure
CAS No.
150971-45-2
Chemical Name:
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms
(R)-iPr-MeOBIPHEP;(R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;SL-A116-1;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine);(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'- dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97%;(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine);(R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl - [B90889]
CBNumber:
CB51180977
Molecular Formula:
C26H40O2P2
Molecular Weight:
446.54
MDL Number:
MFCD09753011
MOL File:
150971-45-2.mol
MSDS File:
SDS
Last updated:2026-01-13 11:21:34
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(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Properties

Boiling point 517.2±50.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color white
InChI 1S/C26H40O2P2/c1-17(2)29(18(3)4)23-15-11-13-21(27-9)25(23)26-22(28-10)14-12-16-24(26)30(19(5)6)20(7)8/h11-20H,1-10H3
InChIKey HLLUWVKDDQIKNF-UHFFFAOYSA-N
SMILES COc1cccc(P(C(C)C)C(C)C)c1-c2c(OC)cccc2P(C(C)C)C(C)C
UNSPSC Code 12352112

SAFETY

Risk and Safety Statements

PPE Eyeshields, Gloves, type N95 (US)
WGK Germany  WGK 3
HS Code  29319090
Storage Class 11 - Combustible Solids

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% min.97% 150971-45-2 100mg $99 2026-04-30 Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% min.97% 150971-45-2 500mg $366 2026-04-30 Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% min.97% 150971-45-2 2g $1244 2026-04-30 Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% min.97% 150971-45-2 10g $4969 2026-04-30 Buy
Synthonix B90889 (R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl 97% 150971-45-2 100mg $170 2026-05-06 Buy
Product number Packaging Price Buy
15-0654 100mg $99 Buy
15-0654 500mg $366 Buy
15-0654 2g $1244 Buy
15-0654 10g $4969 Buy
B90889 100mg $170 Buy

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties, Uses, Production

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.

  1. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
  2. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
  3. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
  4. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
  5. Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
  6. Rhodium-catalyzed carbonyl Z-dienylation.
  7. Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
Reactions of 150971-45-2_1
Reactions of 150971-45-2_2

Chemical Properties

Off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

Global Suppliers ( 23)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Energy Chemical 400-0056266 18918157536; sales8178@energy-chemical.com China 45000 61
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 sales@kingorgchem.com China 806 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5985 58
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39866 58
Yangzhou modier Electronic Materials Co., Ltd 13761402923 19975033992 market@modeltemol.com China 7913 58
Shanghai Kaiwei Chemical Technology Co., Ltd. 021-58461859 15821823057 service@aiviche.com China 49299 58
Bide Pharmatech Ltd. 400-6005915 sales@picasso-e.com China 39645 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
Chongqing Chemdad Co., Ltd 58
Yangzhou modier Electronic Materials Co., Ltd 58
Shanghai Kaiwei Chemical Technology Co., Ltd. 58
Bide Pharmatech Ltd. 58

View Latest Price from (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% pictures 2019-08-09 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
150971-45-2
 $1.00 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co

150971-45-2 ((R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%) Related Search:

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(S)-H8-BINAP (R)-DM-BINAP (S)-SunPhos (S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-TolBINAP
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-SEGPHOS (R)-H8-BINAP
(R)-DIFLUORPHOS(TM) (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS

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(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97% (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine) (R)-iPr-MeOBIPHEP, SL-A116-1, (R)-2,2μ-Bis(diisopropylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl SL-A116-1 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'- dimethoxy-1,1'-biphenyl (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97% (R)-(+)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(1-methylethyl)- (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine) (R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine), CAS 150971-45-2 (R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl - [B90889] (R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-iPr-MeOBIPHEP 150971-45-2 Chiral Phosphine MeOBIPHEP Series