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4-Hydroxyphthalonitrile

4-Hydroxyphthalonitrile Structure
4-Hydroxyphthalonitrile structure
CAS No.
30757-50-7
Chemical Name:
4-Hydroxyphthalonitrile
Synonyms
3,4-Dicyano Penol;3,4-DICYANOPHENOL;4-HYDROXYPHTHALONITRILE;4-Hydroxyphehalonitrile;4-Hydroxyphthalonitrile>4-HYDROXYPHTHALONITRILE 97+%;4-hydroxy-1,2-benzenedicarbonitrile;4-HYDROXYBENZENE-1,2-DICARBONITRILE;1,2-Benzenedicarbonitrile,4-hydroxy-;4-Hydroxyphthalonitrile SynonyMs 3,4-Dicyanophenol
CBNumber:
CB5354797
Molecular Formula:
C8H4N2O
Molecular Weight:
144.13
MDL Number:
MFCD00191653
MOL File:
30757-50-7.mol
MSDS File:
SDS
Last updated:2026-05-28 05:35:20
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4-Hydroxyphthalonitrile Properties

Melting point ~218 °C
Boiling point 394.6±37.0 °C(Predicted)
Density 1.34±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol
form powder to crystal
pka 6.45±0.18(Predicted)
color White to Gray to Brown
BRN 2718847
InChIKey FTVOPKROFUTOKY-UHFFFAOYSA-N
CAS DataBase Reference 30757-50-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  2926907090
NFPA 704
0
2 0

4-Hydroxyphthalonitrile price More Price(52)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical H0813 4-Hydroxyphthalonitrile >97.0%(GC) 30757-50-7 1g $107 2026-04-30 Buy
TCI Chemical H0813 4-Hydroxyphthalonitrile >97.0%(GC) 30757-50-7 5g $267 2026-04-30 Buy
Apolloscientific OR919916 4-Hydroxyphthalonitrile >98% 30757-50-7 1g $21 2026-06-04 Buy
Apolloscientific OR919916 4-Hydroxyphthalonitrile >98% 30757-50-7 5g $24 2026-06-04 Buy
Apolloscientific OR919916 4-Hydroxyphthalonitrile >98% 30757-50-7 25g $111 2026-06-04 Buy
Product number Packaging Price Buy
H0813 1g $107 Buy
H0813 5g $267 Buy
OR919916 1g $21 Buy
OR919916 5g $24 Buy
OR919916 25g $111 Buy

4-Hydroxyphthalonitrile Chemical Properties, Uses, Production

Chemical Properties

Colorless transparent liquid

Synthesis Reference(s)

Synthetic Communications, 19, p. 3231, 1989 DOI: 10.1080/00397918908052723

Synthesis

4-Nitrophthalonitrile

31643-49-9

4-Hydroxyphthalonitrile

30757-50-7

The general procedure for the synthesis of 3,4-dicyanophenol from 4-nitrophthalonitrile was as follows: 1) 103.9 g (600 mmol) of 4-nitrophthalonitrile and 800 mL of dimethyl sulfoxide (DMSO) were added to a three-necked flask equipped with a stirrer. After the solid was completely dissolved, 91.0 g (660 mmol) of potassium carbonate and 46.0 g (660 mmol) of sodium nitrite were added sequentially. The reaction mixture was heated to 160 °C and kept at reflux for 5 hours. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently poured into a large amount of water to precipitate the product. The yellow solid was collected by filtration and dried under vacuum at 110 °C to give 73.3 g of 4-hydroxyphthalonitrile in 85% yield.

References

[1] RSC Advances, 2015, vol. 5, # 96, p. 79207 - 79215
[2] Patent: CN104910113, 2017, B. Location in patent: Paragraph 0041-0042; 0045-0046
[3] Synthetic Communications, 1989, vol. 19, # 18, p. 3231 - 3240
[4] Russian Journal of General Chemistry, 2011, vol. 81, # 4, p. 768 - 772

4-Hydroxyphthalonitrile synthesis

31643-49-9
30757-50-7
23277-29-4
Synthesis of 4-Hydroxyphthalonitrile from 4-Nitrophthalonitrile

4-Hydroxyphthalonitrile Preparation Products And Raw materials

Raw materials

1,2-Benzenedicarbonitrile,4,4'-oxybis- 1,2-Benzenedicarbonitrile, 4-(phenylmethoxy)- 2-Ethyl-2-methyl-1,3-propanediol 4-Nitrophthalonitrile Dimethyl sulfoxide
3,4-Dibromophenol 4-Nitrophthaldiamide ZINC CYANIDE 2-Methyl-1-propanol Copper(I) Cyanide

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Preparation Products

4-Hydroxyphthalic acid 4-Hydroxyphthalic anhydride

4-Hydroxyphthalonitrile Suppliers

Global Suppliers ( 138)
Supplier Tel Email Country ProdList Advantage
Wuhan EnTai Technology Development Co,.Ltd 86-27-82330560 2536851935@qq.com China 346 69
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9409 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44852 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Beijing Eternalchem Co,. Ltd. 010-59484199 18611897322;18611897322; sales@eternalchem.com China 1993 60
Supplier Advantage
Wuhan EnTai Technology Development Co,.Ltd 69
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
TCI (Shanghai) Development Co., Ltd. 81
Beijing HwrkChemical Technology Co., Ltd 55
Energy Chemical 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65
Shanghai Hanhong Scientific Co.,Ltd. 64
Beijing Eternalchem Co,. Ltd. 60

View Latest Price from 4-Hydroxyphthalonitrile manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Hydroxyphthalonitrile pictures 2026-10-09 4-Hydroxyphthalonitrile
30757-50-7
 $209.30 25Kg/Drum 98.0%Min 3tons/month Asia Chem I and E (Jiangsu) Co Ltd
4-Hydroxyphthalonitrile pictures 2026-10-09 4-Hydroxyphthalonitrile
30757-50-7
 $281.69 25Kg/Drum 98.5%min, 99.5%min 2tons/month Asia Chem I and E (Jiangsu) Co Ltd
4-Hydroxyphthalonitrile pictures 2019-07-06 4-Hydroxyphthalonitrile
30757-50-7
 $1.00 1KG 99% Career Henan Chemical Co

4-Hydroxyphthalonitrile Spectrum

4-Hydroxyphthalonitrile(30757-50-7)1HNMR

30757-50-7 (4-Hydroxyphthalonitrile) Related Search:

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3,4-DICYANOPHENOL 4-HYDROXYPHTHALONITRILE 4-HYDROXYBENZENE-1,2-DICARBONITRILE 4-Hydroxyphehalonitrile 4-HYDROXYPHTHALONITRILE 97+% 1,2-Benzenedicarbonitrile,4-hydroxy- 4-Hydroxyphthalonitrile SynonyMs 3,4-Dicyanophenol 3,4-Dicyano Penol 4-Hydroxyphthalonitrile> 4-hydroxy-1,2-benzenedicarbonitrile 30757-50-7 C8 to C9 Building Blocks Phthalonitriles & Naphthalonitriles Phthalonitriles (Building Blocks for Phthalocyanines) Organic Building Blocks Nitrogen Compounds Cyanides/Nitriles Functional Materials Phthalonitriles & Naphthalonitriles Phthalonitriles (Building Blocks for Phthalocyanines)