ChemicalBook
Chinese Japanese Germany Korea

tert-Butyl peroxyacetate

tert-Butyl peroxyacetate
tert-Butyl peroxyacetate structure
CAS No.
107-71-1
Chemical Name:
tert-Butyl peroxyacetate
Synonyms
tert-butyl;lupersol70;Trigonox?F;LUPEROX 7M75;LUPEROX 7M50;trigonoxf-c50;Butylperacetate;T-BUTYL PERACETATE;50%inmineralspirit;t-butylperoxyacetate
CBNumber:
CB5852718
Molecular Formula:
C6H12O3
Formula Weight:
132.16
MOL File:
107-71-1.mol

tert-Butyl peroxyacetate Properties

Melting point:
-20 °C
Boiling point:
184.08°C (rough estimate)
Density 
0.828 g/mL at 25 °C
refractive index 
n20/D 1.412
Flash point:
99 °F
storage temp. 
Refrigerator (+4°C) + Flammables area
form 
Solution
color 
Clear
FDA 21 CFR
177.2600
CAS DataBase Reference
107-71-1(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances
TERT-BUTYL PEROXYACETATE
FDA UNII
FJ3F3S50CS
EPA Substance Registry System
tert-Butyl peroxyacetate (107-71-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS06,GHS08
Signal word  Danger
Hazard statements  H226-H242-H302-H304-H315-H319-H331-H335-H340-H350
Precautionary statements  P201-P210-P280-P304+P340+P312-P308+P313-P370+P378
Hazard Codes  F,T,O,Xi
Risk Statements  23/24/25-36/37/38-40-65-22-10-7-45-46
Safety Statements  16-26-36/37/39-45-62-47-14-7-53-3/7-36/37-35
RIDADR  UN 3103 5.2
WGK Germany  2
RTECS  SD8925000
HazardClass  5.2
PackingGroup  II
HS Code  29159000
NFPA 704
3
3 3
OX

tert-Butyl peroxyacetate price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 388076 tert-Butyl peracetate solution 50wt. % in odorless mineral spirits 107-71-1 500ml $93.7 2019-12-02 Buy

tert-Butyl peroxyacetate Chemical Properties,Uses,Production

Chemical Properties

clear solution

Uses

Polymerization initiator for vinyl monomers, manufacture of polyethylene and polystyrene.

Uses

It is used to initiate polymerization, and inorganic syntheses.

General Description

tert-Butyl peroxyacetate is sensitive to heat. Storage of tert-Butyl peroxyacetate must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with an inert solid.

Reactivity Profile

tert-Butyl peroxyacetate explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602]. Upon contact with organic matter, t-butyl peroxyacetate can ignite or give rise to an explosion [Haz. Chem. Data 1973 p. 77].

Hazard

Flammable, dangerous fire risk. Oxidizer.

Health Hazard

Mild skin and eye irritant. Its toxicity is low,both via inhalation and ingestion routes.
LD50 value, oral (rats): 675 mg/kg.

Fire Hazard

The pure compound is highly reactive and oxidizing, and sensitive to heat and shock.
A 75% solution in benzene or mineral spirits is the maximum assay that is sold commercially. Its benzene solution at this concentration is reactive, oxidizing, and flammable. The flash point varies depending on the solvent; the autoignition temperature not reported; the self-accelerating decomposition temperature is 93°C (199.4°F).
t-Butyl peroxyacetate forms an explosive mixture with air, explosive range not reported. It can ignite or explode when in contact with combustible organic compounds. Fire-extinguishing agent: water from a sprinkler from an explosion-resistant location; keep the containers cool.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation. Moderate skin and eye irritant. A shockand heat-sensitive explosive. Dangerous fire hazard when exposed to heat, flame, reducing agents. To fight fire, use dry chemical, alcohol foam, spray and mist. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC; and ESTERS

storage

Store in a cool and well-ventilated placeisolated from other chemicals; protect fromphysical damage. It is shipped in glass andearthenware containers not exceeding 7 lb,inside a wooden or fiberboard box.

Purification Methods

Wash the ester with NaHCO3 from a *benzene solution, then redistil to remove *benzene [Kochi J Am Chem Soc 84 774 1962]. Handle with adequate protection due to possible EXPLOSIVE nature. [Beilstein 2 IV 391.]

tert-Butyl peroxyacetate Preparation Products And Raw materials

Raw materials

Preparation Products


tert-Butyl peroxyacetate Suppliers

Global( 46)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28231 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23045 58
Mainchem Co., Ltd. +86-0592-6210733
+86-0592-6210733 sale@mainchem.com CHINA 32444 55
J & K SCIENTIFIC LTD. 400-666-7788 010-82848833-
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 400-660-8290 21-61259100-
86-21-61259102 sh@meryer.com China 40268 62
Tianjin heowns Biochemical Technology Co., Ltd. 400 638 7771
sales@heowns.com China 14460 57
Maya High Purity Chemicals +86 (573) 82222445 (0)18006601000 QQ:452520369
+86 (573) 82222643 sales@maya-r.com China 11740 57
Thermo Fisher Scientific 800-810-5118
+86-10-84193589 cnchemical@thermofisher.com China 17444 75
Beijing innoChem Science & Technology Co.,Ltd. 400-810-7969 010-59572699
010-59572688 ningzi.li@inno-chem.com.cn China 6152 55
9ding chemical ( Shanghai) Limited 4009209199
86-021-52271987 sales@9dingchem.com China 22544 55

107-71-1(tert-Butyl peroxyacetate)Related Search:


Copyright 2017 © ChemicalBook. All rights reserved