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Lauroyl peroxide

CAS No.
105-74-8
Chemical Name:
Lauroyl peroxide
Synonyms
LPO;LAUROYL PEROXIDE;LAURYL PEROXIDE;lauroyl;DODECANOYL PEROXIDE;laurox;dodecanoyl;Dodecanoic peroxyanhydride;dodecanoyl dodecaneperoxoate;alperoxc
CBNumber:
CB6255318
Molecular Formula:
C24H46O4
Molecular Weight:
398.62
MDL Number:
MFCD00008964
MOL File:
105-74-8.mol
MSDS File:
SDS
Last updated:2023-09-21 19:01:29

Lauroyl peroxide Properties

Melting point 53-57 °C(lit.)
Boiling point 441.76°C (rough estimate)
Density 0,91 g/cm3
vapor density 13.7 (vs air)
vapor pressure 0Pa at 20℃
refractive index 1.4460 (estimate)
storage temp. 2-8°C
solubility Chloroform (Slightly), DMSO (Slightly, Sonicated)
form Powder
color White
Odor wh. coarse powd., faint odor, tasteless
Water Solubility Soluble in oils and organic solvents. Slightly soluble in alcohol. Insoluble in water.
BRN 1804936
InChIKey YIVJZNGAASQVEM-UHFFFAOYSA-N
LogP 10.3
CAS DataBase Reference 105-74-8(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances LAUROYL PEROXIDE
FDA 21 CFR 175.105; 176.170
EWG's Food Scores 1
FDA UNII 83TLB4N1D5
IARC 3 (Vol. 36, Sup 7, 71) 1999
EPA Substance Registry System Peroxide, bis(1-oxododecyl) (105-74-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Danger
Hazard statements  H242
Precautionary statements  P210-P234-P235-P280-P370+P378-P410
Hazard Codes  O
Risk Statements  7
Safety Statements  14-3/7-36/37/39-14A-37/39-36
RIDADR  UN 3106 5.2
WGK Germany  1
RTECS  OF2625000
TSCA  Yes
HazardClass  5.2
PackingGroup  II
HS Code  29159000
NFPA 704
0
0 1

Lauroyl peroxide price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 290785 Luperox? LP, Lauroyl peroxide 97% 105-74-8 100g $50.34 2024-03-01 Buy
Sigma-Aldrich 8.43861 Lauroyl peroxide for synthesis 105-74-8 100G $70.9 2024-03-01 Buy
Sigma-Aldrich 290785 Luperox? LP, Lauroyl peroxide 97% 105-74-8 5g $78.3 2024-03-01 Buy
Alfa Aesar L14310 Lauroyl peroxide, 97% 105-74-8 100g $57.6 2024-03-01 Buy
Alfa Aesar L14310 Lauroyl peroxide, 97% 105-74-8 500g $130 2024-03-01 Buy
Product number Packaging Price Buy
290785 100g $50.34 Buy
8.43861 100G $70.9 Buy
290785 5g $78.3 Buy
L14310 100g $57.6 Buy
L14310 500g $130 Buy

Lauroyl peroxide Chemical Properties,Uses,Production

Chemical Properties

Dilauroyl peroxide (Lauroyl peroxide) is a tasteless, coarse, white powder. Dilauroyl peroxide is not a deflagration hazard. However, it has been judged an intermediate fire hazard by Noller et al.  When all the physical tests available for this peroxide are evaluated collectively, it actually ranks as a low physical hazard .

Uses

Lauroyl peroxide is used as an initiatorfor free-radical polymerization in makingpolyvinyl chloride. Lauroyl peroxide constitutesabout 4% of all organic peroxides consumptionin the United States.

Uses

Dilauroyl peroxide is produced by reaction of lauroyl chloride with sodium peroxide. Its major use is as an initiator for vinyl chloride. It is used as a polymerization agent in the plastics industry and as a curing agent for rubber. It has also been used as a burnout agent for acetate yarns. The pharmaceutical industry uses it in topical creams in combination with antibiotics for acne treatment .

Uses

Lauroyl peroxide acts as a bleaching agent, drying agent for fats, oils and waxes. Further, it serves as a polymerization initiator as well as vulcanizing agent. In addition to this, it plays an important role for high-pressure polyethylene and food used in bleaching agent.

Preparation

Dilauroyl peroxide is the symmetrical peroxide of lauric acid. It is produced by treating lauroyl chloride with hydrogen peroxide in the presence of base:
2C11H23COCl + H2O2+ 2NaOH → (C11H23CO2)2 + 2HCl

Definition

ChEBI: Lauroyl peroxide is a dicarboxylic acid.

General Description

Dilauroyl peroxide appears as a white solid with a faint soapy odor. Less dense than water and insoluble in water. Hence floats on water. Melting point 49 °C. Toxic by ingestion and inhalation. Strong skin irritant. Used as bleaching agent, drying agent for fats, oils and waxes, and as a polymerization catalyst.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Dilauroyl peroxide is an oxidizing agent. Can ignite organic materials; hence a dangerous fire and explosion risk [Hawley]. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively. Vigorous reactions with other reducing agents. With charcoal sometimes ignites. [Bretherick, 5th ed., 1995, p. 1194].

Health Hazard

Contact with liquid irritates eyes and skin. Ingestion causes irritation of mouth and stomach.

Health Hazard

Lauroyl peroxide is a mild eye irritant; theirritation from 500 mg/day in rabbits’ eyeswas mild. It is nontoxic. Prolonged exposureto laboratory animals caused tumors at thesite of application. However, the evidence ofcarcinogenicity in animals is inadequate todate.

Fire Hazard

Behavior in Fire: Can increase the severity of a fire. Becomes sensitive to shock when hot. Containers may explode in a fire. May ignite or explode spontaneously if mixed with flammable materials.

Flammability and Explosibility

Not classified

Carcinogenicity

The International Agency for Research on Cancer has evaluated the carcinogenicity of lauroyl peroxide. They classified it as a Group 3 material, which means there is limited or inadequate evidence for animals and inadequate or absent information for humans . The carcinogenicity of this peroxide has primarily been studied using skin applications. After a single topical application of 10, 20, or 40 mg of lauroyl peroxide, the epidermal thickness increased markedly. This hyperplasia was characterized by a sustained production of dark basal keratinocytes. This peroxide is inactive as a tumor initiator or as a complete carcinogen. However, it is as effective as benzoyl peroxide as a skin tumor promoter.

storage

Store in a well-ventilated, cool area, isolatedfrom other chemicals. It is shippedin fiber drums not exceeding 100 lb. Smallamounts may be shipped in 1-lb fiberboardboxes.

Purification Methods

Crystallise it from n-hexane or *benzene and store it below 0o. Potentially EXPLOSIVE. [cf Beilstein 2 IV 1102.]

Waste Disposal

Although lauroyl peroxide is relatively lesshazardous, it is recommended that to handlespills and disposal, the same safety measuresbe followed as those for other hazardousorganic peroxides.

112-16-3
105-74-8
Synthesis of Lauroyl peroxide from Lauroyl chloride

Lauroyl peroxide Preparation Products And Raw materials

Global( 182)Suppliers
Supplier Tel Email Country ProdList Advantage
Taizhou Suze Chemical Materials Co.,Ltd.
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Henan Tianfu Chemical Co.,Ltd.
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Shanxi Naipu Import and Export Co.,Ltd
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Xiamen AmoyChem Co., Ltd
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View Lastest Price from Lauroyl peroxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dilauroyl peroxide pictures 2024-04-24 Dilauroyl peroxide
105-74-8
US $150.00-145.00 / kg 10kg 99.99% 100Tons Hebei Dangtong Import and export Co LTD
Dilauroyl peroxide pictures 2023-09-06 Dilauroyl peroxide
105-74-8
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Dilauroyl peroxide pictures 2023-08-18 Dilauroyl peroxide
105-74-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
  • Dilauroyl peroxide pictures
  • Dilauroyl peroxide
    105-74-8
  • US $150.00-145.00 / kg
  • 99.99%
  • Hebei Dangtong Import and export Co LTD
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