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4-Bromomethyl-7-methoxycoumarin

4-Bromomethyl-7-methoxycoumarin structure

CAS No.: 35231-44-8

Chemical Name:: 4-Bromomethyl-7-methoxycoumarin

Synonyms: BMC;BR-MMC;BMC, Br-Mmc;-7-methoxy-2H-chromen-2-one;4-BROMOETHYL-7-METHOXYCOUMARIN;4-Bromomethyl-7-methoxycoumain;4-bromomethyl-7-hydroxycoumarin;7-Methoxy-4-bromomethylcoumarin;4-BROMOMETHYL-7-METHOXYCOUMARIN;4-BroMoMethyl-7-MethoxycouMarine

CBNumber:: CB6345309

Molecular Formula:: C11H9BrO3

Molecular Weight:: 269.09

MDL Number:: MFCD00006869

MOL File:: 35231-44-8.mol

Last updated:2023-05-25 18:01:15

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4-Bromomethyl-7-methoxycoumarin Properties

Melting point	213-215 °C (lit.)
Boiling point	385.3±42.0 °C(Predicted)
Density	1.552±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
solubility	chloroform: soluble20mg/mL, clear, colorless to faintly yellow
form	Powder and/or Chunks
color	Off-white to light yellow or beige
Water Solubility	insoluble
λmax	330 nm (MeOH)
BRN	187211
Stability	Stable, but moisture and light-sensitive. Combustible. Incompatible with strong oxidizing agents.
Major Application	Detection of nitrated explosives; measuring ultraviolet ray power; photoacid generators; polyurethane foams; photoresists silica nanoparticles
Biological Applications	Analyzing/detecting carboxylic acids;analyzing/labeling fatty acids; detecting nitric oxide; detecting/separating bile acids; labeling pyrimidine nucleobases; anticancer agents; biomedical trace analysis; herbicides; as a substrate for measuring histone acetyltransferases (HATs) activity, peptidases activity, sirtuin activity
LogP	2.730 (est)
CAS DataBase Reference	35231-44-8(CAS DataBase Reference)
FDA UNII	4K32PB5K8Q

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P261-P264-P270-P301+P312-P302+P352-P305+P351+P338

Hazard Codes

Xi,Xn

Risk Statements

36/37/38-22

Safety Statements

26-36-37/39

RIDADR

1759

WGK Germany

HazardClass

PackingGroup

III

HS Code

29322090

NFPA 704

	0
1		0

4-Bromomethyl-7-methoxycoumarin price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	235202	4-Bromomethyl-7-methoxycoumarin 97%	35231-44-8	1g	$65.4	2024-03-01	Buy
Sigma-Aldrich	235202	4-Bromomethyl-7-methoxycoumarin 97%	35231-44-8	5g	$248	2024-03-01	Buy
TCI Chemical	A5551	Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling] >98.0%(T)	35231-44-8	1g	$91	2024-03-01	Buy
TCI Chemical	A5551	Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling] >98.0%(T)	35231-44-8	5g	$272	2024-03-01	Buy
TRC	B685400	4-Bromomethyl-7-methoxycoumarin	35231-44-8	1g	$90	2021-12-16	Buy

Product number	Packaging	Price	Buy
235202	1g	$65.4	Buy
235202	5g	$248	Buy
A5551	1g	$91	Buy
A5551	5g	$272	Buy
B685400	1g	$90	Buy

4-Bromomethyl-7-methoxycoumarin Chemical Properties,Uses,Production

Chemical Properties

Light Green-Yellow Crystals

Uses

4-Bromomethyl-7-methoxycoumarin has been used:

as derivatization reagent in determination of 5-fluorouracil (5-FU) in human plasma by HPLC-tandem mass spectrometry
as derivatization reagent in fluorescence detection of sodium monofluoroacetate (MFA-Na) in biological samples by HPLC
in the synthesis of new caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3′,5′-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3′,5′-monophosphate (8-Br-cGMP)
in TLC and HPLC separation and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B₂

Uses

4-Bromomethyl-7-methoxycoumarin can be used as fluorescent label for fatty acids. For derivatization, TLC and HPLC separation, and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2.

Purification Methods

The coumarin crystallises from boiling AcOH; the crystals are washed with AcOH, EtOH and dried in a vacuum; 1HNMR (TFA) 3.97s, 4.57s, 6.62s, 6.92-7.19m and 7.80d. [Secrist et al. Biochem Biophys Res Commun 45 1262 1971, Dünges Anal Chem 49 442 1977, Beilstein 18 III/IV 348.]

4-Bromomethyl-7-methoxycoumarin Preparation Products And Raw materials

Raw materials

Preparation Products

7-methoxy-4-(piperazin-1-ylmethyl)-2H-chromen-2-one

4-Bromomethyl-7-methoxycoumarin Suppliers

Global( 166)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanxi Tihondan Pharmaceutical Technology Co., Ltd	+8618235132063	sales@tihondan.com	China	3721	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
Shaanxi Dideu Medichem Co. Ltd	18192627656	1012@dideu.com	China	2766	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12733	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	19892	58

Supplier	Advantage
Shanxi Tihondan Pharmaceutical Technology Co., Ltd	58
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58
Zhengzhou Alfa Chemical Co.,Ltd	58
SIMAGCHEM CORP	58
TargetMol Chemicals Inc.	58

View Lastest Price from 4-Bromomethyl-7-methoxycoumarin manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-01-15	4-Bromomethyl-7-methoxycoumarin 35231-44-8	US $0.00 / KG	1KG	98.7%	100 tons	Honest Joy Holdings Limited
2021-10-30	4-Bromomethyl-7-methoxycoumarin 35231-44-8	US $1.10 / g	1g	99.00%	100 Tons Min	Dideu Industries Group Limited
2020-04-28	4-Bromomethyl-7-methoxycoumarin 35231-44-8	US $0.01-1.00 / KG	1KG	99%	50 tons	Shaanxi Dideu Medichem Co. Ltd

4-Bromomethyl-7-methoxycoumarin
35231-44-8
US $0.00 / KG
98.7%
Honest Joy Holdings Limited

4-Bromomethyl-7-methoxycoumarin
35231-44-8
US $1.10 / g
99.00%
Dideu Industries Group Limited

4-Bromomethyl-7-methoxycoumarin
35231-44-8
US $0.01-1.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

4-Bromomethyl-7-methoxycoumarin Spectrum

4-Bromomethyl-7-methoxycoumarin(35231-44-8)MS 4-Bromomethyl-7-methoxycoumarin(35231-44-8)¹HNMR 4-Bromomethyl-7-methoxycoumarin(35231-44-8)IR1 4-Bromomethyl-7-methoxycoumarin(35231-44-8)Raman

35231-44-8(4-Bromomethyl-7-methoxycoumarin)Related Search:

Coumarin 6-Methylcoumarin 7-Methoxycoumarin Bromotrimethylsilane 4-Bromomethylbenzoic acid

(Trifluoromethoxy)benzene 4-Methylcumarin SCOPARONE 7-Methoxy-4-methylcoumarin 3-Hydroxyphenyl acetate

Allyl bromide 4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN Methyl 3-methyl-2-butenoate 3,3-Dimethylacrylic acid Methyl 4-bromocrotonate

3-METHOXYPHENYL ACETATE Methyl bromide 4-METHOXYPHENETHYL BROMIDE

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Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling] BR-MMC (=4-BROMOETHYL-7-METHOXYCOUMARIN) 4-BROMOMETHYL-7-METHOXYCOUMARIN [FOR HPLC LABELING] BMC, Br-Mmc 2H-1-Benzopyran-2-one, 4-(bromomethyl)-7-methoxy- 4-(Bromomethyl)-7-methoxychromen-2-one 4-(Bromomethyl)-7-methoxy-2H-1-benzopyran-2-one 7-Methoxy-4-bromomethylcoumarin 4-bromomethyl-7-hydroxycoumarin 4-(Bromomethyl)-7-methoxycoumarin,99% 4-(Bromomethyl)-7-methoxycoumarin,97% Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) 4-Bromomethyl-7-methoxycoumarin,BMC, Br-Mmc 4-Bromomethyl-7-methoxycoumarin (BrMMC) [for HPLC Labeling] BROMOMETHYL-7-METHOXYCOUMARIN, 4-(RG) 4-(BroMoMethyl)-7-MethoxycouMarin, 97% 1GR 4-BroMoMethyl-7-MethoxycouMarine 4-BroMoMethyl-7-MethoxycouMarin 97% 4-(BroMoMethyl)-7-Methoxy-2H-chroMen-2-one BR-MMC 4-BROMOMETHYL-7-METHOXYCOUMARIN 4-BROMOETHYL-7-METHOXYCOUMARIN 4-BROMOMETHYL-7-METHOXYCOUMARIN, FOR FLU ORESCENCE 4-Bromomethyl-7-methoxycoumain 4-BROMOMETHYL-7-METHOXYCOUMARIN (BR-MMC) Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling]> 4-Bromomethyl-7-methoxycoumarin ISO 9001：2015 REACH 4-(bromomethyl)-7-methoxy-2H-chromene-2-one -7-methoxy-2H-chromen-2-one BMC Br-Mmc (=4-Bromomethyl-7-methoxycoumarin), for HPLC，≥ 98.0% 35231-44-8 C11H9BrO3 ESTER HPLC Labeling Reagents Fluorescence Detection (HPLC Labeling Reagents) Carboxyl Group Labeling Reagents for Fluorescence HPLC Detection Fluorescent Labels Fluorescent Probes, Labels, Particles and Stains Other Fluorescent Labels Biochemicals and Reagents BioChemical Carboxyl Group Labeling Reagents for Fluorescence HPLC Fluorescence Detection (HPLC Labeling Reagents) HPLC Labeling Reagents Fluorescent Labels & Indicators Fluorescent Labels and Indicators Coumarins Analytical Chemistry