ChemicalBook >> CAS DataBase List >>Chlorodiphenylphosphine
Chlorodiphenylphosphine
- CAS No.
- 1079-66-9
- Chemical Name:
- Chlorodiphenylphosphine
- Synonyms
- DPPC;PH2PCL;PPh2Cl;ClPPh2;DIPHENYLCHLOROPHOSPHINE;DIPHENYLPHOSPHINOUS CHLORIDE;95% (C6H5)2PCl;AURORA KA-1322;Chlordiphenylphosphin;CHLORODIPHENYLPHOSPINE
- CBNumber:
- CB6365608
- Molecular Formula:
- C12H10ClP
- Molecular Weight:
- 220.63
- MDL Number:
- MFCD00000529
- MOL File:
- 1079-66-9.mol
- MSDS File:
- SDS
Last updated:2024-04-08 17:36:13
| Melting point | 14-16°C |
|---|---|
| Boiling point | 320 °C(lit.) |
| Density | 1.229 g/mL at 25 °C(lit.) |
| vapor density | 7.8 (vs air) |
| vapor pressure | 1.3 hPa (20 °C) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | Miscible with alcohol. Slightly miscible with ammonia. |
| form | Liquid |
| color | Colorless to yellow |
| Specific Gravity | 1.229 |
| Water Solubility | Reacts violently |
| Sensitive | Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 512032 |
| InChIKey | XGRJZXREYAXTGV-UHFFFAOYSA-N |
| LogP | 5.330 (est) |
| CAS DataBase Reference | 1079-66-9(CAS DataBase Reference) |
| FDA UNII | WO975PJK1Y |
| NIST Chemistry Reference | Chlorodiphenylphosphine(1079-66-9) |
| EPA Substance Registry System | Phosphinous chloride, diphenyl- (1079-66-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H290-H302-H314-H412 | |||||||||
| Precautionary statements | P273-P280-P301+P312+P330-P303+P361+P353-P305+P351+P338+P310 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 14-34-29-36 | |||||||||
| Safety Statements | 26-36/37/39-45-8-30-25-27 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| F | 1-9-19 | |||||||||
| Autoignition Temperature | 320 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29310095 | |||||||||
| Toxicity | LD50 orally in Rabbit: 316 mg/kg | |||||||||
| NFPA 704 |
|
Chlorodiphenylphosphine price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | C39601 | Chlorodiphenylphosphine 96% | 1079-66-9 | 25g | $63.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 766054 | P-Chlorodiphenylphosphine 99% | 1079-66-9 | 25g | $102 | 2024-03-01 | Buy |
| TCI Chemical | C0597 | Chlorodiphenylphosphine >97.0%(T) | 1079-66-9 | 25g | $23 | 2024-03-01 | Buy |
| TCI Chemical | C0597 | Chlorodiphenylphosphine >97.0%(T) | 1079-66-9 | 100g | $64 | 2024-03-01 | Buy |
| Alfa Aesar | 041352 | Chlorodiphenylphosphine, 98+% | 1079-66-9 | 10g | $29.6 | 2024-03-01 | Buy |
Chlorodiphenylphosphine Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.
Production Methods
The specific synthesis steps of Chlorodiphenylphosphine are as follows: In a sealed NMR tube filled with argon,Dissolve Ph2P (O) H (0.05 mmol) in 0.5 mL of tetrahydrofuran,Add acetyl chloride (the amount of acetyl chloride added is 1.2 times the equivalent of Ph2P (O) H),The mixture was reacted at 100 ° C for 12 hours with a yield of 99%.
Synthesis Reference(s)
Journal of the American Chemical Society, 77, p. 3526, 1955 DOI: 10.1021/ja01618a030
Flammability and Explosibility
Non flammable
Purification Methods
This air-sensitive, pale yellow lachrymatory liquid is purified by careful fractional distillation and discarding the lower boiling fraction which contains the main impurity PhPCl2 (b 48-51o/0.7mm), and checking for impurities by NMR. [Weinberg J Org Chem 40 3586 1975, Honer et al. Chem Ber 94 2122 1961, Beilstein 16 IV 969.]
Chlorodiphenylphosphine Preparation Products And Raw materials
Raw materials
Preparation Products
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
Diphenylphosphine
4-(DIMETHYLAMINO)PHENYLDIPHENYLPHOSPHINE
1,1'-Bis(diphenylphosphino)ferrocene
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
VANADIUM(III) CHLORIDE
1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH&
Phosphine, 4-dibenzofuranyldiphenyl-
2-(Diphenylphosphino)-biphenyl
1of4
Global( 505)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Z&T Chemical Co., Ltd | +86-21-33561011 13818804961 | Sales@ztchemical.com.cn | China | 402 | 58 |
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@airuikechemical.com | China | 994 | 58 |
| hebei hongtan Biotechnology Co., Ltd | +86-86-1913198-3935 +8617331935328 | sales03@chemcn.cn | China | 951 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Shanghai Bojing Chemical Co.,Ltd. | +86-86-02137122233 +8613795318958 | bj1@bj-chem.com | China | 298 | 55 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
View Lastest Price from Chlorodiphenylphosphine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-26 | Chlorodiphenylphosphine
1079-66-9
|
US $0.00 / KG | 1KG | 98% | 1000mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-04-26 | Chlorodiphenylphosphine
1079-66-9
|
US $30.00 / kg | 1kg | 98% | 2000kg | hebei hongtan Biotechnology Co., Ltd | |
 |
2024-04-08 | chlorodiphenylphosphine
1079-66-9
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. |
-
- Chlorodiphenylphosphine
1079-66-9
- US $0.00 / KG
- 98%
- Jinan Finer Chemical Co., Ltd
-
- Chlorodiphenylphosphine
1079-66-9
- US $30.00 / kg
- 98%
- hebei hongtan Biotechnology Co., Ltd
-
- chlorodiphenylphosphine
1079-66-9
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
1079-66-9(Chlorodiphenylphosphine)Related Search:
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95% (C6H5)2PCl
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DIPHENYLPHOSPHINE CHLORIDE OR CHLORODIPHENYLPHOSPHINE OR DIPHENYLPHOSPHINOUS CHLORIDE
Diphenylphosphinchlorid
Diphenylphosphinous chloride
P-Chlorodiphenylphosphine
Diphenyl phosphine chlorideDiphenyl phosphine chloride
3,3’,5,5’-Tetramethy-2,2’biphenol
Chlorodiphenyl phosphine(95%)
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P-Chlorodiphenylphosphine, Diphenylphosphinous chloride
Chlorodiphenylphosphine >
Chlordiphenylphosphin
ClPPh2
PPh2Cl
DIPHENYLPHOSPHINOUS CHLORIDE
DIPHENYLCHLOROPHOSPHINE
DPPC
PH2PCL
Chioro diphenyl phosphine
1079-66-9
1070-66-9
079-66-9
C12H10PCl
C6H52PCl
C12H10ClP
Catalysis and Inorganic Chemistry
Phosphorus Precursors
Phosphorus Compounds
Ligand