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Benzyl methacrylate

CAS No.
2495-37-6
Chemical Name:
Benzyl methacrylate
Synonyms
BZMA;Benzylmethacrylat;BENZYL METHACRYLATE;BENZYLMETHACRAYLATE;Benzyl 2-methylacrylate;Methacrylic acid benzyl;Benzyl methacrylate ,98%;benzyl 2-methylprop-2-enoate;METHACRYLIC ACID BENZYL ESTER;Benzyl Methacrylate, stabilized
CBNumber:
CB7306028
Molecular Formula:
C11H12O2
Molecular Weight:
176.21
MDL Number:
MFCD00053684
MOL File:
2495-37-6.mol
MSDS File:
SDS
Last updated:2024-05-06 09:26:40

Benzyl methacrylate Properties

Melting point <25 °C
Boiling point 95-98 °C/4 mmHg (lit.)
Density 1.04 g/mL at 25 °C (lit.)
vapor pressure 3Pa at 20℃
refractive index n20/D 1.512(lit.)
Flash point 225 °F
storage temp. 2-8°C(protect from light)
form clear liquid
color Colorless
Viscosity 2.51mm2/s
Water Solubility Insoluble in water.
Sensitive Light Sensitive
BRN 2045924
Stability Stable. Flammable. Incompatible with free-radical initiators, oxidizing agents, reducing agents. Avoid heat. Light-sensitive.
LogP 3.1 at 20℃
CAS DataBase Reference 2495-37-6(CAS DataBase Reference)
FDA UNII Z3248K2SSM
NIST Chemistry Reference Benzyl methacrylate(2495-37-6)
EPA Substance Registry System 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  1
TSCA  Yes
HS Code  29163990
NFPA 704
1
2 0

Benzyl methacrylate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 409448 Benzyl methacrylate 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor 2495-37-6 250ml $82.3 2024-03-01 Buy
Sigma-Aldrich 409448 Benzyl methacrylate 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor 2495-37-6 1l $264 2024-03-01 Buy
TCI Chemical M0279 Benzyl Methacrylate (stabilized with MEHQ) >98.0%(GC) 2495-37-6 25mL $20 2024-03-01 Buy
TCI Chemical M0279 Benzyl Methacrylate (stabilized with MEHQ) >98.0%(GC) 2495-37-6 500mL $76 2024-03-01 Buy
Alfa Aesar L10840 Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol 2495-37-6 50g $23.65 2024-03-01 Buy
Product number Packaging Price Buy
409448 250ml $82.3 Buy
409448 1l $264 Buy
M0279 25mL $20 Buy
M0279 500mL $76 Buy
L10840 50g $23.65 Buy

Benzyl methacrylate Chemical Properties,Uses,Production

Description

The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].

Chemical Properties

colourless liquid

Uses

Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Flammability and Explosibility

Not classified

Advantages

The Tg of the copolymer was elevated, while thermal stability was first increased and then decreased with the introduction of Benzyl methacrylate. Besides, the water resistance of the latex PSA was improved by the presence of BzMA, which was confirmed by water contact angle measurements. Furthermore, as the BzMA content increased, the gel content slightly decreased, while sol molecular weight (Mw, Mn) of the polymer increased. Finally, with respect to the adhesive properties of the PSA, it was observed that loop tack decreased, while shear strength increased with the incorporation of BzMA. 180° peel strength initially increased and then decreased with the addition of Benzyl methacrylate from 0 to 30 wt%, with a maximum value at 5 wt%.

References

[1] Cheng Fang , Xiaolong Zhu, Fuxiang Zhou . “The application research of benzyl methacrylate (BzMA) in acrylate latex pressure sensitive adhesives.” International Journal of Adhesion and Adhesives 107 (2021): Article 102861.

80-62-6
100-51-6
2495-37-6
Synthesis of Benzyl methacrylate from Methyl methacrylate and Benzyl alcohol
Global( 315)Suppliers
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View Lastest Price from Benzyl methacrylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzyl methacrylate pictures 2024-05-15 Benzyl methacrylate
2495-37-6
US $0.00 / kg 20kg 99.5% 10 toms Qingdao RENAS Polymer Material Co., Ltd.
Benzyl methacrylate pictures 2024-04-22 Benzyl methacrylate
2495-37-6
US $30.00 / kg 1kg 99.7% 200000kg Ouhuang Engineering Materials (Hubei) Co., Ltd
Benzyl methacrylate pictures 2023-12-24 Benzyl methacrylate
2495-37-6
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2-methyl-2-propenoicaciphenylmethylester 2-Propenoic acid, 2-methyl-, phenylmethyl ester 2-Propenoicacid,2-methyl-,phenylmethylester Benzyl 2-methylacrylate Benzyl Methacrylate, 98%, stabilized Benzyl Methacrylate, stabilized Benzyl methacrylate, stabilized with &ap:50 to 100ppm 4-methoxyphenol Benzyl Methacrylate 96%, contains 50 ppM MonoMethyl ether hydroquinone as inhibitor BENZYL METHACRYLATE METHACRYLIC ACID BENZYL ESTER Phenylmethyl 2-methylprop-2-enoate Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol Benzyl Methacrylate (stabilized with MEHQ) Phenylmethyl-2-methyl-2-propenoate METHACRYLIC ACID BENZYL ESTER (STABILIZED WITH MEHQ) 98+% 2-Methylacrylic acid benzyl ester 2-Methylpropenoic acid benzyl ester Methacrylic acid benzyl Benzyl methacrylate ,98% benzyl 2-methylprop-2-enoate BenzylMethacrylate(stabilizedwithMEHQ)> BENZYLMETHACRAYLATE Benzylmethacrylat BZMA Benzyl methacrylate CAS NO.2495-37-6 2495-37-6 H2CCCH3CO2CH2C6H5 Carbonyl Compounds C10 to C11 Organic Building Blocks Esters Building Blocks Acrylic Monomers C10 to C11Monomers Carbonyl Compounds Esters Methacrylate