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PHENOXATHIIN-4-BORONIC ACID

CAS No.
100124-07-0
Chemical Name:
PHENOXATHIIN-4-BORONIC ACID
Synonyms
AKOS BRN-0042;4-Phenoxathinboronic acid;4-PHENOXATHIINBORONIC ACID;PHENOXATHIIN-4-BORONIC ACID;4-Phenoxathiineboronic acid;PHENOXATHINE-4-BORONIC ACID;PHENOXANTHIN-4-BORONIC ACID;phenoxathiin-4-ylboronicaci;PHENOXANTHIIN-4-BORONIC ACID;4-PHENOXATHIINYLBORONIC ACID
CBNumber:
CB7325577
Molecular Formula:
C12H9BO3S
Molecular Weight:
244.07
MDL Number:
MFCD01605731
MOL File:
100124-07-0.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:42
Product description Number Pack Size Price
Phenoxathiin-4-boronicAcid P320843 50mg $45
PheNoxathiiN-4-boroNic acid 287592 250mg $358
Phenoxathiin-4-boronic acid 97% 004158 5g $436
PHENOXATHIIN-4-BORONIC ACID 95.00% BOR0001718 5G $1230.08
Phenoxathiin-4-boronic acid 97% 004158 1g $103
More product size

PHENOXATHIIN-4-BORONIC ACID Properties

Melting point 162-167 °C
Boiling point 457.5±55.0 °C(Predicted)
Density 1.45±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka 7.83±0.20(Predicted)
Appearance White to off-white Solid
CAS DataBase Reference 100124-07-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26
HazardClass  IRRITANT
HS Code  29349990

PHENOXATHIIN-4-BORONIC ACID price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC P320843 Phenoxathiin-4-boronicAcid 100124-07-0 50mg $45 2021-12-16 Buy
Usbiological 287592 PheNoxathiiN-4-boroNic acid 100124-07-0 250mg $358 2021-12-16 Buy
Matrix Scientific 004158 Phenoxathiin-4-boronic acid 97% 100124-07-0 5g $436 2021-12-16 Buy
American Custom Chemicals Corporation BOR0001718 PHENOXATHIIN-4-BORONIC ACID 95.00% 100124-07-0 5G $1230.08 2021-12-16 Buy
Matrix Scientific 004158 Phenoxathiin-4-boronic acid 97% 100124-07-0 1g $103 2021-12-16 Buy
Product number Packaging Price Buy
P320843 50mg $45 Buy
287592 250mg $358 Buy
004158 5g $436 Buy
BOR0001718 5G $1230.08 Buy
004158 1g $103 Buy

PHENOXATHIIN-4-BORONIC ACID Chemical Properties,Uses,Production

Chemical Properties

White to beige crystalline powder

Uses

phenoxathiin-4-boronic acid is used as a chemosensor due to its strong fluorescent when it binds to sugars.

Synthesis

PHENOXATHIIN

262-20-4

Triisopropyl borate

5419-55-6

PHENOXATHIIN-4-BORONIC ACID

100124-07-0

The general procedure for the synthesis of phenoxathiophene-4-boronic acid from phenoxathiophene and triisopropyl borate was as follows: phenoxathiophene (30 g, 145 mmol) was dissolved in 300 mL of tetrahydrofuran (THF) and the solution was cooled to -78 °C. Subsequently, n-butyllithium (n-BuLi) (72 mL, 180 mmol) was added slowly and dropwise. After stirring the reaction at -78 °C for 1 h, the reaction mixture was warmed to room temperature and the reaction was continued for 2 h. The reaction mixture was cooled to -78 °C for 1 h. The reaction mixture was then cooled to -78 °C for 2 h. The reaction mixture was again cooled to -78 °C and triisopropyl borate (33.8 g, 180 mmol) was slowly added. The reaction mixture continued to react at -78 °C for 2 hours before slowly warming to room temperature and reacting for 4 hours. Upon completion of the reaction, dilute hydrochloric acid (HCl) was added to terminate the reaction and the aqueous and organic layers were separated. The organic layer was concentrated by distillation under reduced pressure and extracted with chloroform (1 L) and water (1 L). The extracted organic layer was dried with magnesium sulfate and concentrated by distillation under reduced pressure again. Finally, phenoxathia-4-boronic acid (25 g, 68% yield) was obtained by recrystallization using hexane.

References

[1] Patent: CN107325090, 2017, A. Location in patent: Paragraph 0218-0220

PHENOXATHIIN-4-BORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from PHENOXATHIIN-4-BORONIC ACID manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PHENOXATHIIN-4-BORONIC ACID pictures 2019-09-03 PHENOXATHIIN-4-BORONIC ACID
100124-07-0
US $7.00 / KG 1KG 99% JD 812 Career Henan Chemical Co

PHENOXATHIIN-4-BORONIC ACID Spectrum

4-Phenoxathinboronic acid PHENOXANTHIIN-4-BORONIC ACID Phenoxathiin-4-boronic acid,97% 4-Phenoxathiinylboronic acid, May contain varying amounts of anhydride, 97% 4-Phenoxathiineboronic acid Phenoxathiin-4-boronic acid, 97% 100MG phenoxathiin-4-ylboronic acid 4-PHENOXATHIINBORONIC ACID 4-PHENOXATHIINYLBORONIC ACID AKOS BRN-0042 PHENOXATHIIN-4-BORONIC ACID PHENOXATHINE-4-BORONIC ACID PHENOXANTHIN-4-BORONIC ACID Boronic acid, B-4-phenoxathiinyl- phenoxathiin-4-ylboronicaci B-4-Phenoxathiinylboronic acid Phenoxathiine-4-boronic Acid Phenoxathiin-4-ylboronic acid - [P4930] Phenoxathiin-4-ylboronic acid(contains varying amounts of Anhydride) 100124-07-0 C12H9BO3S Boronic acid Heterocycle Organoborons Boronic Acids