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2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane structure

CAS No.: 83558-87-6

Chemical Name:: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane

Synonyms: 6FAP;AHHFP;BAFA;4,4'-(Perfluoropropane-2,2-diyl)bis(2-aMinophenol);BAPAF;2,2-Bis(3-aMino-4-hydroxylphenyl)hexafluoropropane(6FAP);1,1-Bis(3-aMino-4-hydroxyphenyl)-2,2,2-trifluoro-1-(trifluoroMethyl)ethane;BIS-AP-AF;Bis-AP-AF2;Bis-AP-AF/6FAP

CBNumber:: CB7397729

Molecular Formula:: C15H12F6N2O2

Molecular Weight:: 366.26

MDL Number:: MFCD00039147

MOL File:: 83558-87-6.mol

MSDS File:: SDS

Last updated:2024-05-23 11:31:01

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2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Properties

Melting point	245-248 °C (lit.)
Boiling point	411.3±45.0 °C(Predicted)
Density	1.545±0.06 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
solubility	DMSO (Slightly), Methanol (Slightly)
pka	9.07±0.10(Predicted)
form	Solid
color	White to Off-White
InChI	InChI=1S/C15H12F6N2O2/c16-14(17,18)13(15(19,20)21,7-1-3-11(24)9(22)5-7)8-2-4-12(25)10(23)6-8/h1-6,24-25H,22-23H2
InChIKey	MSTZGVRUOMBULC-UHFFFAOYSA-N
SMILES	C(C1=CC=C(O)C(N)=C1)(C1=CC=C(O)C(N)=C1)(C(F)(F)F)C(F)(F)F
CAS DataBase Reference	83558-87-6(CAS DataBase Reference)
EPA Substance Registry System	Phenol, 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[2-amino- (83558-87-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany

Hazard Note

Irritant

HS Code

29222990

NFPA 704

	0
2		0

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane price More Price(36)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	541710	2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 97%	83558-87-6	5g	$67.68	2024-03-01	Buy
TCI Chemical	B1415	2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane >98.0%(T)	83558-87-6	5g	$86	2024-03-01	Buy
TCI Chemical	B1415	2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane >98.0%(T)	83558-87-6	25g	$257	2024-03-01	Buy
TRC	B591980	2,2-Bis(3-Amino-4-hydroxyphenyl(hexafluoropropane))	83558-87-6	500mg	$50	2021-12-16	Buy
SynQuest Laboratories	4756-3-34	2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 99%	83558-87-6	25g	$60	2021-12-16	Buy

Product number	Packaging	Price	Buy
541710	5g	$67.68	Buy
B1415	5g	$86	Buy
B1415	25g	$257	Buy
B591980	500mg	$50	Buy
4756-3-34	25g	$60	Buy

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Chemical Properties,Uses,Production

Description

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane (6FAP,83558-87-6) is white crystal. Its boiling point and density are expected to be 411.3±45.0 °C and 1.545±0.06 g/cm3, respectively. It is slightly soluble in DMSO and methanol.The product is non-toxic and can be stored at room temperature away from light and air.

Synthesis

30 g two (3-nitro-4-hydroxyphenyl) hexafluoropropanes are dropped into the 1000 mL autoclave, add 300 g DMF and 1.5 g palladium/carbon (the mass fraction of palladium in the palladium/carbon is 5%), press hydrogen to 1MPa, open stirring and be warmed up to 70 ℃, stop reaction after two (3-nitro-4-hydroxyphenyl) hexafluoropropane content＜0.1%, target product two (3-amino-4-hydroxyphenyl) hexafluoropropane Fluoropropane gas phase content is 98%, and the system is black, and the temperature of the still is lowered to room temperature, filtered, and the filtrate is de-dried under reduced pressure at 70-80°C to obtain bis(3-amino-4-hydroxyphenyl) hexafluoropropane crude product , the crude product is recrystallized, the recrystallization solvent is water and DMF, and the mass ratio of bis(3-amino-4-hydroxyphenyl)hexafluoropropane, water and DMF is 1:4:2.
First, the bis(3-nitro-4-hydroxyphenyl) hexafluoropropane crude product is mixed with the recrystallization solvent to increase the still temperature to 60 °C and stir, and then the still temperature is reduced to 10-20 °C for crystallization, filtered, After drying, 25.4 g of pure bis(3-nitro-4-hydroxyphenyl)hexafluoropropane was obtained. The yield of bis(3-amino-4-hydroxyphenyl)hexafluoropropane was 98.3% and the purity was 99.6%. 1H-NMR (400MHz, D6-DMSO) δ (ppm): 4.64 (s, 4H), 6.42 (d, 2H), 7.57 (s, 2H), 6.65 (d, 2H), 9.36 (s, 2H). 19F-NMR (400MHz, D6-DMSO) δ (ppm): -62.78. [1]. 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane

Physical properties

White powder

Uses

2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane（BisAPAF） is a polyimide monomer.It is mairly used in the aynthesis of the heat resisting polymers,especially in the manufacture of specialty polymeoric electronic material-fluorinated polyimides.

Application

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane (Bis-AP-AF/6FAP) consists of two aminophenols bridged with a hexafluoropropane. The reaction of Bis-AP-AF and BTDA can be used to synthesise polyimide (PI) films. The tensile strength, tensile modulus and elongation at break of the PI films were significantly improved by 60Co irradiation with an optimum irradiation dose of 50 kGy. The maximum increments in tensile strength, tensile modulus and elongation at break of the irradiated PI films were 37.8%, 45.0% and 95.2%, respectively. The high proton conductivity and good chemical and thermal stability of these fluorinated films make them most suitable for use in fuel cell systems. In addition, Bis-AP-AF can be used to synthesise polybenzoxazole (TR-PBO) membranes for use as semiconductor fabrication materials.

General Description

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane, also referred to as 4,4′-(1,1,1,3,3,3-hexafluoro-2,2-propanediyl)bis(2-aminophenol), is an aromatic diamine.

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane synthesis

Synthesis of 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane from Phenol, 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[2-nitro-

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Preparation Products And Raw materials

Raw materials

Phenol, 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[2-nitro-

Preparation Products

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Suppliers

Global( 379)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Fluoropharm Co., Ltd.	+86-0571-85586753; +8613336034509	sales@fluoropharm.com	China	1377	60
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	+8618222493702	sales8@chinatechem.com	China	61	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2966	58
Shanghai Daeyeon Chemicals Co., Ltd	021-64478606 +8615900664856	daeyeon001@vip.163.com	China	2062	58
Henan Allgreen Chemical Co.,LTD	+86-37155567971 +86-13633837469	info@allgreenchem.com	China	5986	58
Heynova (Shanghai) New Material Technology CO., Ltd	+8617821320848	zoe@heynovachem.com	China	431	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12470	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	6708	58
Hangzhou ICH Biofarm Co., Ltd	+86-0571-28186870; +undefined8613073685410	sales@ichemie.com	China	985	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	18223	58

Supplier	Advantage
Fluoropharm Co., Ltd.	60
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	58
Jinan Finer Chemical Co., Ltd	58
Shanghai Daeyeon Chemicals Co., Ltd	58
Henan Allgreen Chemical Co.,LTD	58
Heynova (Shanghai) New Material Technology CO., Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Shanghai UCHEM Inc.	58
Hangzhou ICH Biofarm Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58

Synthesis and Application of 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane
2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane is an important synthetic intermediate.
Aug 26，2022

View Lastest Price from 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-23	2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 83558-87-6	US $1.00 / KG	1KG	99.91%	200000	Ouhuang Engineering Materials (Hubei) Co., Ltd
2024-02-23	2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 83558-87-6	US $24.00-151.00 / g	25g	0.98	100kg	Shanghai UCHEM Inc.
2024-01-23	2,2-Bis(3-amino-4-hydroxyphenyl)-hexafluoropropane(Bis-AP-AF/6FAP) 83558-87-6	US $0.00 / KG	1KG	99%	1500KG/month	Shanghai Daken Advanced Materials Co.,Ltd

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
83558-87-6
US $1.00 / KG
99.91%
Ouhuang Engineering Materials (Hubei) Co., Ltd

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
83558-87-6
US $24.00-151.00 / g
0.98
Shanghai UCHEM Inc.

2,2-Bis(3-amino-4-hydroxyphenyl)-hexafluoropropane(Bis-AP-AF/6FAP)
83558-87-6
US $0.00 / KG
99%
Shanghai Daken Advanced Materials Co.,Ltd

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Spectrum

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane(83558-87-6)MS 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane(83558-87-6)¹HNMR 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane(83558-87-6)¹³CNMR 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane(83558-87-6)IR1 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane(83558-87-6)IR2

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2-aMino-4-[2-(3-aMino-4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]phenol 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluopropane 2,2-Bis(3-amino-4-hydroxyphenyl)-hexafluoropropane(Bis-AP-AF/6FAP) BIS-AP-AF 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS(2-AMINOPHENOL) 2,2-BIS(3-AMINO-4-HYDROXYPHENYL)HEXAFLUOROPROPANE 2,2'-DIAMINO-4,4'-(PERFLUOROPROPANE-2,2-DIYL)DIPHENOL 2,2-BIS(3-AMINO-4-HYDROXYPHENYL)HEXAFLUO 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane,6-FAP 2,2-Bis(3-amino-4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane 4,4'-(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis(2-aminophenol) 4,4'-[Bis(trifluoromethyl)methylene]bis(2-aminophenol) Phenol, 4,4'-(2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(2-amino- 2,2-bis(3-amino-4-hy 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 99% 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane99% 2,2-Bis(3-amino-4-hydroxyphenyl)- 2,2-bis(3-amino-4-hydroxyphenyl) -hexafluoropropane (Bis-AP-AF) 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane > 2-Amino-4-[1-(3-amino-4-hydroxy-phenyl)-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenol 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane USP/EP/BP 2-aMino-4-[2-(3-aMino-4-hydroxyphenyl)-1,1,1,3,3,3- Bis-AP-AF2 1,1-Bis(3-aMino-4-hydroxyphenyl)-2,2,2-trifluoro-1-(trifluoroMethyl)ethane 2,2-Bis(3-aMino-4-hydroxylphenyl)hexafluoropropane(6FAP) 4,4'-(Perfluoropropane-2,2-diyl)bis(2-aMinophenol) AHHFP 6FAP BAPAF BAFA Bis-AP-AF/6FAP O-aminobisphenol AF 4,4'-(Perfluoropropane-2,2-diyl)bis(2-aminophenol) 83558-87-6 F3C2CC6H3NH2OH2 C15H12F6N2O2 Organic Building Blocks Oxygen Compounds Bisphenol AF type Compounds (for High-Performance Polymer Research) Reagent for High-Performance Polymer Research Building Blocks Amino Alcohols fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, Organic Building Blocks Bisphenol AF type Compounds (for High-Performance Polymer Research) Functional Materials Reagent for High-Performance Polymer Research Amino Alcohols Organic Building Blocks Oxygen Compounds fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials 83558-87-6