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Methyl 2-bromo-5-nitrobenzoate

Methyl 2-bromo-5-nitrobenzoate structure

CAS No.: 6942-36-5

Chemical Name:: Methyl 2-bromo-5-nitrobenzoate

Synonyms: METHYL 2-BROMO-5-NITROBENZOATE;METHYL 2-BROMO-5-NITROBENZOIC ACID;Methyl 2-Bromo-5-nitrobenzoate >Methyl 2-bromo-5-nitrobenzoate 97%;Methyl 2-bromo-5-nitrobenzoate, 98+%;2-BROMO-5-NITROBENZOIC ACID METHYL ESTER;Benzoic acid, 2-bromo-5-nitro-, methyl ester;Methyl 2-bromo-5-nitrobenzoate ISO 9001：2015 REACH

CBNumber:: CB8722100

Molecular Formula:: C8H6BrNO4

Molecular Weight:: 260.04

MDL Number:: MFCD00010867

MOL File:: 6942-36-5.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-24 14:58:46

Product description	Number	Pack Size	Price
Methyl 2-bromo-5-nitrobenzoate 99%	300217	1g	$55.7
Methyl 2-Bromo-5-nitrobenzoate >98.0%(GC)	B1916	5g	$18
Methyl 2-Bromo-5-nitrobenzoate >98.0%(GC)	B1916	25g	$63
2-Bromo-5-nitrobenzoicAcidMethylEster	B687295	50mg	$1550
Methyl 2-bromo-5-nitrobenzoate	F179	1g	$14
More product size

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Methyl 2-bromo-5-nitrobenzoate Properties

Melting point	79-81 °C (lit.)
Boiling point	326.7±22.0 °C(Predicted)
Density	1.673±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform, DCM. Ethyl Acetate
form	Crystalline Powder
color	Yellow
BRN	2617575
InChI	1S/C8H6BrNO4/c1-14-8(11)6-4-5(10(12)13)2-3-7(6)9/h2-4H,1H3
InChIKey	VSEYYEKRZNRECT-UHFFFAOYSA-N
SMILES	COC(=O)c1cc(ccc1Br)[N+]([O-])=O
CAS DataBase Reference	6942-36-5(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

HS Code

29163990

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	1
2		0

Methyl 2-bromo-5-nitrobenzoate price More Price(34)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	300217	Methyl 2-bromo-5-nitrobenzoate 99%	6942-36-5	1g	$55.7	2023-01-07	Buy
TCI Chemical	B1916	Methyl 2-Bromo-5-nitrobenzoate >98.0%(GC)	6942-36-5	5g	$18	2026-04-30	Buy
TCI Chemical	B1916	Methyl 2-Bromo-5-nitrobenzoate >98.0%(GC)	6942-36-5	25g	$63	2026-04-30	Buy
TRC	B687295	2-Bromo-5-nitrobenzoicAcidMethylEster	6942-36-5	50mg	$1550	2021-12-16	Buy
AK Scientific	F179	Methyl 2-bromo-5-nitrobenzoate	6942-36-5	1g	$14	2021-12-16	Buy

Product number	Packaging	Price	Buy
300217	1g	$55.7	Buy
B1916	5g	$18	Buy
B1916	25g	$63	Buy
B687295	50mg	$1550	Buy
F179	1g	$14	Buy

Methyl 2-bromo-5-nitrobenzoate Chemical Properties,Uses,Production

Chemical Properties

yellow crystalline powder

Uses

Methyl 2-bromo-5-nitrobenzoate may be used in chemical synthesis.

Synthesis

67-56-1

943-14-6

6942-36-5

Methyl 2-bromo-5-nitrobenzoate was synthesized by esterification reaction using methanol and 2-bromo-5-nitrobenzoic acid as raw materials. The specific steps are as follows: in a dry reaction flask, 2-bromo-5-nitrobenzoic acid was dissolved in an appropriate amount of methanol, and a catalytic amount of concentrated sulfuric acid was added. The reaction mixture was stirred under reflux conditions for 6 hours. Upon completion of the reaction, the mixture was cooled to room temperature, poured into ice water and neutralized with sodium bicarbonate solution to pH=7. Subsequently, the product was extracted with dichloromethane, the organic phase was dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate=10:1) to afford methyl 2-bromo-5-nitrobenzoate in white crystalline form in 81% yield. The structure of the product was confirmed by 1H NMR and 13C NMR: 1H NMR (400 MHz, CDCl3) δ 4.00 (s, 3H), 7.88 (d, J = 8.76 Hz, 1H), 8.18 (dd, J = 2.76 Hz, 1H), 8.66 (d, J = 2.74 Hz, 1H); 13C NMR (100 MHz, CDCl3) δ 53.12, 126.33, 126.61, 129.24, 133.12, 135.71, 146.70, 164.48.

References

[1] Journal of the American Chemical Society,
[2] Journal of the American Chemical Society, 2009, vol. 131, p. 54 - 55
[3] Synthesis, 1999, # 7, p. 1246 - 1250
[4] Patent: US2009/131527, 2009, A1. Location in patent: Page/Page column 8
[5] Tetrahedron Letters, 2012, vol. 53, # 46, p. 6245 - 6249,5

Methyl 2-bromo-5-nitrobenzoate Preparation Products And Raw materials

Raw materials

Methanol 2-BROMO-5-NITROBENZOIC ACID

Preparation Products

4,4'-Dinitrodiphenic acid

Methyl 2-bromo-5-nitrobenzoate Suppliers

Global( 216)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20124	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29819	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58

Supplier	Advantage
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58
Fuxin Pharmaceutical	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from Methyl 2-bromo-5-nitrobenzoate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-09-25	Methyl 2-bromo-5-nitrobenzoate 6942-36-5	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2020-02-26	Methyl 2-bromo-5-nitrobenzoate 6942-36-5	US $0.00-0.00 / Kg	1KG	99.0%	100 tons	Shaanxi Dideu Medichem Co. Ltd
2019-07-10	Methyl 2-bromo-5-nitrobenzoate 6942-36-5	US $8.80 / KG	1KG	97%-99%	100kg	Career Henan Chemical Co

Methyl 2-bromo-5-nitrobenzoate
6942-36-5
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

Methyl 2-bromo-5-nitrobenzoate
6942-36-5
US $0.00-0.00 / Kg
99.0%
Shaanxi Dideu Medichem Co. Ltd

Methyl 2-bromo-5-nitrobenzoate
6942-36-5
US $8.80 / KG
97%-99%
Career Henan Chemical Co

Methyl 2-bromo-5-nitrobenzoate Spectrum

Methyl 2-bromo-5-nitrobenzoate(6942-36-5)MS Methyl 2-bromo-5-nitrobenzoate(6942-36-5)¹HNMR Methyl 2-bromo-5-nitrobenzoate(6942-36-5)¹³CNMR Methyl 2-bromo-5-nitrobenzoate(6942-36-5)IR1 Methyl 2-bromo-5-nitrobenzoate(6942-36-5)IR2 Methyl 2-bromo-5-nitrobenzoate(6942-36-5)Raman

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