Methyl 2-bromobenzoate
- CAS No.
- 610-94-6
- Chemical Name:
- Methyl 2-bromobenzoate
- Synonyms
- Pramipexol 65;Methyl2-obenzoate;RARECHEM AL BF 0014;Methyl 2-broMobenzo;Methyl o-broMophenyl;Methyl 2-bromobenzoa;METHYL O-BROMOBENZOATE;METHYL 2-BROMOBENZOATE;METHYL 2-BROMOBENZPATE;Methyl2-bromobenzoate,99%
- CBNumber:
- CB0327815
- Molecular Formula:
- C8H7BrO2
- Molecular Weight:
- 215.04
- MDL Number:
- MFCD00016328
- MOL File:
- 610-94-6.mol
- MSDS File:
- SDS
| Melting point | 252°C |
|---|---|
| Boiling point | 252 °C (lit.) |
| Density | 1.532 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | Liquid |
| Specific Gravity | 1.532 |
| color | Clear light yellow |
| Water Solubility | insoluble |
| BRN | 1862501 |
| InChI | 1S/C8H7BrO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3 |
| InChIKey | SWGQITQOBPXVRC-UHFFFAOYSA-N |
| SMILES | COC(=O)c1ccccc1Br |
| CAS DataBase Reference | 610-94-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Methyl-2-bromobenzoate(610-94-6) |
| EPA Substance Registry System | Benzoic acid, 2-bromo-, methyl ester (610-94-6) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H361 | |||||||||
| Precautionary statements | P501-P202-P201-P280-P308+P313-P405 | |||||||||
| PPE | Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | TSCA listed | |||||||||
| HS Code | 29163990 | |||||||||
| Storage Class | 10 - Combustible liquids | |||||||||
| NFPA 704 |
|
Methyl 2-bromobenzoate price More Price(57)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 387851 | Methyl 2-bromobenzoate 98% | 610-94-6 | 5ml | $34.1 | 2026-04-30 | Buy |
| Sigma-Aldrich | 387851 | Methyl 2-bromobenzoate 98% | 610-94-6 | 25ml | $65.6 | 2026-04-30 | Buy |
| TCI Chemical | B0555 | Methyl 2-Bromobenzoate >98.0%(GC) | 610-94-6 | 25g | $42 | 2026-04-30 | Buy |
| TCI Chemical | B0555 | Methyl 2-Bromobenzoate >98.0%(GC) | 610-94-6 | 250g | $240 | 2026-04-30 | Buy |
| Biosynth | FM36905 | Methyl 2-bromobenzoate | 610-94-6 | 1kg | $150 | 2026-06-04 | Buy |
Methyl 2-bromobenzoate Chemical Properties, Uses, Production
Chemical Properties
CLEAR LIGHT YELLOW LIQUID
Uses
Methyl 2-bromobenzoate under Heck reaction with acrylonitrile results in lactonization to give the benzofuran-2-one 3-(cyanomethyl)-2-coumaranone. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals
Synthesis
Preparation of methyl o-bromobenzoate: In a 250 ml three-necked flask, add 0.04 mol of methyl benzoate and 100 ml of acetic acid, stir to dissolve, and then cool to 0 C using an ice-salt bath. Dissolve 0.05 mol of Br2 in 50 ml of acetic acid, and slowly add the bromine-acetic acid solution dropwise to the above reaction system. After the addition is complete, control the temperature at 20-25 C and stir the reaction for 12 hours. Take a sample for TLC; no raw material I1-3 remains. After the reaction is complete, add NaOH aqueous solution to neutralize the reaction solution, add dichloromethane for extraction, separate the layers, filter the organic phase, distill the filtrate under reduced pressure until no fraction remains, and pass it through a neutral silica gel column to obtain the intermediate methyl o-bromobenzoate.
Purification Methods
A solution of the ester in ether is washed with 10% aqueous Na 2CO3, water, then dried and distilled. [Beilstein 9
Methyl 2-bromobenzoate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuxi Nanfang Chemistry Additives Co.,Ltd. | 0510-85580939 18261593783 | nanfangchem@126.com | China | 34 | 58 |
| Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd. | 13396369453 18678026865 | sdfantai@163.com | China | 904 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| future industrial shanghai co., ltd | 400-0066400 13621662912 | sales@jonln.com | China | 1989 | 65 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TAIYUAN RHF CO.,LTD. | +86 351 7031519 | sales@RHFChem.com | China | 2334 | 56 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
View Latest Price from Methyl 2-bromobenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-05-28 | Methyl 2-bromobenzoate
610-94-6
|
$10.00-20.00 | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
 |
2026-03-20 | Methyl 2-bromobenzoate
610-94-6
|
$10.00 | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-05-26 | Methyl 2-bromobenzoate
610-94-6
|
$3.00 | 1kg | 0.99 | 10000 | Hebei Fengjia New Material Co., Ltd |
-
- Methyl 2-bromobenzoate
610-94-6
- $10.00-20.00
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- Methyl 2-bromobenzoate
610-94-6
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Methyl 2-bromobenzoate
610-94-6
- $3.00
- 0.99
- Hebei Fengjia New Material Co., Ltd
