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POTASSIUM CYANIDE

POTASSIUM CYANIDE
POTASSIUM CYANIDE structure
CAS No.
151-50-8
Chemical Name:
POTASSIUM CYANIDE
Synonyms
KCN;Feratox;Cyanides;ai3-28749;kaliumcyanid;Kalium-cyanid;caswellno688a;POTSSIUM CYANIDE;POTASSIUM CYANIDE;cyanideofpotassium
CBNumber:
CB9387427
Molecular Formula:
CKN
Formula Weight:
65.12
MOL File:
151-50-8.mol

POTASSIUM CYANIDE Properties

Melting point:
634 °C(lit.)
Boiling point:
1625 °C
Density 
1.00 g/mL at 20 °C
Flash point:
1625°C
storage temp. 
Poison room
solubility 
H2O: 1 M at 20 °C, clear, colorless
form 
Solid
Specific Gravity
1.52
color 
White
PH
11-12 (20g/l, H2O, 20°C)
Water Solubility 
Highly soluble in water. Soluble in methanol, glycerol, and formamide. Slightly soluble in ethanol.
Sensitive 
Hygroscopic
Merck 
14,7626
BRN 
4652394
Exposure limits
TLV-TWA (measured as CN) skin 5 mg CN/m3 (ACGIH and OSHA); 5 mg CN/m3/ 10 min ceiling (NIOSH).
Stability:
Stable. Incompatible with a variety of materials, including acids, iodine, peroxides, permanganates, alkaloids, chloral hydrate, metallic salts. Light and moisture sensitive. Contact with acid generates extremely toxic HCN gas.
CAS DataBase Reference
151-50-8(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T+,N
Risk Statements  26/27/28-32-50/53
Safety Statements  7-28-29-45-60-61
RIDADR  UN 1680 6.1/PG 1
WGK Germany  3
RTECS  TS8750000
3-8-10-23
TSCA  Yes
HS Code  2837 19 00
HazardClass  6.1
PackingGroup  I
Toxicity LD50 orally in rats: 10 mg/kg (Hayes)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P405 Store locked up.

NFPA 704

Diamond Hazard Value Description
0
3 0
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

POTASSIUM CYANIDE price

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POTASSIUM CYANIDE Chemical Properties,Uses,Production

Chemical Properties

KCN is a white solid or colourless water solution with a faint bitter almond odour. As a solution, it is slightly soluble in ethanol. It is a poison that reacts with acid or acid fumes to emit deadly HCN. When heated to decomposition, it emits very toxic fumes. As a solid, KCN is incompatible with nitrogen trichloride, perchloryl fluoride, sodium nitrite, acids, alkaloids, chloral hydrate, and iodine. A synonym for KCN is potassium salt of hydrocyanic acid.

Chemical Properties

Potassium cyanide are white lumps, granular powder, or colorless solution. It may be shipped as capsules, tablets, or pellets. Toxic hydrogen cyanide gas released by potassium cyanide has a distinctive, weak bitter almond odor, but many people cannot detect it; the odor does not provide adequate warning of hazardous concentrations.

Uses

Potassium cyanide is a white granular salt made by the absorption of hydrogen cyanide in potassium hydroxide. It is soluble in both water and alcohol and a lethal poison. If mixed with acids it produces highly toxic hydrogen cyanide gas. This was the preferred fixing chemical for collodion positives because it contained no sulfides to darken the highlight silver. As a fixing agent cyanide was particularly effective. After dissolving the unexposed silver halides cyanide would also remove nonimage fog producing very clean shadow areas. Prolonged fixing would eventually remove image silver. Tincture of iodine was added to dilute solutions of potassium cyanide and used to remove unwanted non-image silver in photographic materials and to remove silver stains.

Uses

Extracting gold and silver from ores; electroplating baths; silver plating; case hardening steel by liquid nitriding; reagent in analytical chemistry.

Uses

Potassium cyanide is used for electrolytic refining of platinum; fine silver plating; as an electrolyte for the separation of gold, silver, and copper from platinum; and for metal coloring.

General Description

White amorphous lumps or a crystalline mass with a faint odor of bitter almonds. Density 1.52 g / cm3 Toxic by skin absorption through open wounds, by ingestion. Heating to decomposition produces toxic fumes. Used for gold and silver extraction, in chemical analysis, to make other chemicals, and as an insecticide.

Air & Water Reactions

Deliquescent. Soluble in water. Dissolution releases some poisonous hydrogen cyanide gas. The amount is not hazardous except in an enclosed space. If the water is acidic, dangerous amounts of hydrogen cyanide form at once.

Reactivity Profile

POTASSIUM CYANIDE is a basic salt and a reducing agent. Reacts with acids of all kinds to generate poisonous hydrogen cyanide gas. Can react violently with oxidizing agents: fusion with metal chlorates, perchlorates, nitrates, or nitrites can cause explosions [Bretherick 1979. p. 101]. A mixture with perchloryl fluoride may explode above 100°C. A mixture with nitrite salts may cause an explosion [Pieters 1957. p. 30]. Incompatible with iodine. Initiates the explosive decomposition of nitrogen trichloride.

Hazard

A poison as absorbed by skin.

Health Hazard

POTASSIUM CYANIDE is classified as super toxic. Probable oral lethal dose in humans is less than 5 mg/kg or less than a taste (7 drops) for a 150 lb. person. It is an eye and skin irritant. Poisonous in very small quantities; a taste is lethal.

Health Hazard

Potassium cyanide is a dangerous poison; toxicity comparable to that of sodium cyanide. Ingestion of 100–150 mg of this compound could be fatal to humans. Similar toxicity is observed when KCN is absorbed through skin or eyes. Intake of the quantity above can cause collapse and cessation of breathing.
At lower concentrations the acute toxic symptoms are nausea, vomiting, headache, confusion, and muscle weakness. KCN administered in test animals by the intramuscular, intravenous, intraperitoneal, ocular, and oral routes exhibited LD50 values within the range of 3–9 mg/kg; the acute toxic effects were ataxia, respiratory stimulation, paralysis, and seizure.
Smith and Heath (1979) observed the effect of temperature on KCN toxicity of freshwater fish. When the temperature of exposure was lowered from 15 (59) to 5°C (41°F) the toxicity of KCN to goldfish decreased by a factor of 5.
LD50 value, intraperitoneal (rats): 4 mg/kg
LD50 value, oral (rats): 10 mg/kg
LD50 value, oral (humans): 2.86 mg/kg
Potassium cyanide caused reproductive damage in test animals, producing harmful effects on fertility and embryo.

Health Hazard

Potassium cyanide is a white solid or colorless water solution with a faint bitter almond odor. As a solution, it is slightly soluble in ethanol. It is a poison that reacts with acid or acid fumes to emit deadly hydrogen cyanide. When heated to decomposition, it emits very toxic fumes. As a solid, potassium cyanide is incompatible with nitrogen trichloride, perchloryl fl uoride, sodium nitrite, acids, alkaloids, chloral hydrate, and iodine. A synonym for potassium cyanide is potassium salt of hydrocyanic acid

Health Hazard

Ingestion of KCN or exposure to the salts or their aqueous solutions by eye or skin contact can be fatal; exposure to as little as 50 to 150 mg can cause immediate collapse and death. Poisoning can occur by inhalation of mists of cyanide solutions and by inhalation of HCN produced by the reaction of metal cyanides with acids and with water. Symptoms of nonlethal exposure to cyanide include weakness, headache, dizziness, rapid breathing, nausea, and vomiting. These compounds are not regarded as having good warning properties.
Effects of chronic exposure to sodium cyanide or potassium cyanide are nonspecific and rare.

Fire Hazard

Potassium cyanide is noncombustible solid. Reaction with acids liberates flammable HCN.

Fire Hazard

Contact with acid releases highly flammable hydrogen cyanide gas. Moisture may cause POTASSIUM CYANIDE to volatilize as hydrogen cyanide. When heated to decomposition, POTASSIUM CYANIDE emits very toxic fumes of cyanide and nitrogen oxides. Reacts with acids to produce hydrogen cyanide gas. Reacts with strong oxidizers such as nitrates and chlorates, nitrogen trichloride; perchloryl fluoride; sodium nitrate; acids; alkaloids; chloral hydrate; iodine. Avoid contact with acids.

Industrial uses

A white amorphous or crystalline solid of the composition KCN, potassium cyanide is employed for carbonizing steel for case hardening and for electroplating. For cyaniding steel the latter is immersed in a bath of molten cyanide and then quenched in water, or the cyanide is rubbed on the red-hot steel.
Commercial potassium cyanide is likely to contain a proportion of sodium cyanide. Potassium ferrocyanide, or yellow prussiate of potash, can also be used for case-hardening steel. It has the compositionK4Fe(CN)6and comes in yellow crystals or powder. The nitrogen as well as the carbon enters the steel to form the hard case. Potassium ferricyanide, or red prussiate of potash, is a bright-red granular powder of the composition K3Fe(CN)6, used in photographic reducing solutions, in etching solutions, in blueprint paper, and in silvering mirrors. Redsol crystals is the name of this chemical for use as a reducer and mild oxidizing agent, or toner, for photography.

Safety Profile

A deadly human poison by ingestion. A experimental poison by ocular, subcutaneous, intravenous, intramuscular, and intraperitoneal routes. Experimental teratogenic and reproductive effects. Human systemic effects by ingestion: convulsions, pulse rate increase. Mutation data reported. Reacts with acids or acid fumes to liberate deadly HCN. When heated to decomposition it emits very toxic fumes of K2O , CN-, and NOx. See also CYANIDE.

Potential Exposure

Used in electroplating, steel hardening; extraction of precious metals form ores; as a fumigant; in insecticides; a reagent in analytical chemistry

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Speed in removing material from skin is of extreme importance. Shampoo hair promptly if contaminated. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Keep under observation for 2448 hours as symptoms may return. Use amyl nitrate capsules if symptoms develop. All area employees should be trained regularly in emergency measures for cyanide poisoning and in CPR. A cyanide antidote kit should be kept in the immediate work area and must be rapidly available. Kit ingredients should be replaced every 12 years to ensure freshness. Persons trained in the use of this kit; oxygen use, and CPR must be quickly available.

Shipping

UN1680 Potassium cyanide, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

A saturated solution in H2O-ethanol (1:3) at 60o is filtered and cooled to room temperature. Absolute EtOH is added, with stirring, until crystallisation ceases. The solution is again allowed to cool to room temperature (during 2-3hours), then the crystals are filtered off, washed with absolute EtOH, and dried, first at 70-80o for 2-3hours, then at 105o for 2hours [Brown et al. J Phys Chem 66 2426 1962]. It has also been purified by melting in a vacuum and by zone refining. HIGHLY POISONOUS.

Incompatibilities

A strong reducing agent; keep away from oxidizers. Potassium cyanide decomposes on contact with water, humidity, carbon dioxide, strong acids (such as hydrochloric, sulfuric, and nitric acids), and acid salts, producing highly toxic and highly flammable hydrogen cyanide gas. Potassium cyanide absorbs water from air (is hygroscopic or deliquescent); the aqueous solution is a strong base. Incompatible with organic anhydrides; isocyanates, alkylene oxides; epichlorohydrin, aldehydes, alcohols, glycols, phenols, cresols, caprolactum, strong oxidizers; nitrogen trichloride; sodium chlorate. Attacks aluminum, copper, zinc in the presence of moisture.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Add strong alkaline hypochlorite and react for 24 hours. Then flush to sewer with large volumes of water.

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