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ヘキサメチルりん酸トリアミド

ヘキサメチルりん酸トリアミド 化学構造式
680-31-9
CAS番号.
680-31-9
化学名:
ヘキサメチルりん酸トリアミド
别名:
ヘキサメチルりん酸トリアミド;ヘキサメチルホスホリックトリアミド;ヘキサメチルオルトりん酸トリアミド;ヘキサメチルトリアミドホスファート;りん酸ヘキサメチルトリアミド;トリス(N,N-ジメチルアミノ)ホスフィンオキシド;イーストマンインヒビターHPT;ヘキサメタポール;ヘンパ;トリス(ジメチルアミノ)ホスフィンオキシド;ヘキサメチルホスホルアミド;ヘキサメチルホスホロトリアミド;トリ(ジメチルアミノ)ホスフィンオキシド;ホスホリルヘキサメチルトリアミド;N,N,N',N',N'',N''-ヘキサメチルりん酸トリアミド;ヘキサメチルホスホラミド;ヘキサメチルホスホルトリアミド;リン酸トリス(ジメチルアミド);ヘキサメチルホスホルアミド STANDARD
英語化学名:
Hexamethylphosphoramide
英語别名:
HPT;HMPA;HMPTA;HEMPA;ent50882;ENT 50882;ent50,882;ENT 50,882;hexamethyl;HEXAMETAPOL
CBNumber:
CB1177006
分子式:
C6H18N3OP
分子量:
179.2
MOL File:
680-31-9.mol

ヘキサメチルりん酸トリアミド 物理性質

融点 :
7 °C(lit.)
沸点 :
230-232 °C740 mm Hg(lit.)
比重(密度) :
1.03 g/mL at 25 °C(lit.)
蒸気密度:
6.18 (vs air)
蒸気圧:
0.07 mm Hg ( 25 °C)
屈折率 :
n20/D 1.459(lit.)
闪点 :
222 °F
外見 :
liquid
水溶解度 :
Miscible
凝固点 :
7℃
Merck :
14,4725
安定性::
Stable. Incompatible with strong acids, strong oxidizing agents.
InChIKey:
GNOIPBMMFNIUFM-UHFFFAOYSA-N
CAS データベース:
680-31-9(CAS DataBase Reference)
NISTの化学物質情報:
N,N,N',N',N",N'-Hexamethylphosphorotriamide(680-31-9)
EPAの化学物質情報:
Phosphoric triamide, hexamethyl-(680-31-9)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T
Rフレーズ  45-46
Sフレーズ  53-45-99
RIDADR  2810
WGK Germany  3
RTECS 番号 TD0875000
8
国連危険物分類  6.1(b)
容器等級  III
HSコード  29299090
有毒物質データの 680-31-9(Hazardous Substances Data)
毒性 LD50 in male, female rats (mg/kg): 2650, 3360 orally (Gaines)
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H340 遺伝性疾患のおそれ 生殖細胞変異原性 1A, 1B 危険
H350 発がんのおそれ 発がん性 1A, 1B 危険
注意書き
P201 使用前に取扱説明書を入手すること。
P308+P313 暴露または暴露の懸念がある場合:医師の診断/手当てを 受けること。

ヘキサメチルりん酸トリアミド 価格 もっと(20)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-205N ヘキサメチルホスホルアミド
Hexamethylphosphoramide
680-31-9 10mg ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-205NB-250 ヘキサメチルホスホルアミド
Hexamethylphosphoramide
680-31-9 250mg ¥11100 2018-12-26 購入
東京化成工業 H0095 ヘキサメチルりん酸トリアミド >98.0%(GC)(T)
Hexamethylphosphoric Triamide >98.0%(GC)(T)
680-31-9 25g ¥3100 2018-12-04 購入
東京化成工業 H0095 ヘキサメチルりん酸トリアミド >98.0%(GC)(T)
Hexamethylphosphoric Triamide >98.0%(GC)(T)
680-31-9 100g ¥7900 2018-12-04 購入
Sigma-Aldrich Japan 52730 ヘキサメチルホスホルアミド purum, ≥98.0% (GC)
Hexamethylphosphoramide purum, ≥98.0% (GC)
680-31-9 25ml-f ¥6800 2018-12-25 購入

ヘキサメチルりん酸トリアミド 化学特性,用途語,生産方法

化学的特性

colourless or light amber liquid with an aromatic spicy odour

化学的特性

Hexamethylphosphoric triamide is a colorless liquid with a spicy odor.

使用

Aprotic solvent in organic synthesis. Solvent for polymers, gases; polymerization catalyst; thermal stabilizer in polystyrene; protective additive for polyvinyl and polyolefin resins against uv light degradation. De-icing additive for jet fuels. Chemosterilant for a number of insect pests; chemical mutagen.

一般的な説明

Clear colorless to light amber liquid with a spicy odor.

空気と水の反応

Water soluble.

反応プロフィール

Hexamethylphosphoramide may react with strong oxidizing agents and strong acids . Susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

危険性

Possible carcinogen. Toxic by skin contact. Combustible.

健康ハザード

The acute toxicity of hexamethylphosphoramide is low. HMPA can cause irritation upon contact with the skin and eyes. Hexamethylphosphoramide has been found to cause cancer in laboratory animals exposed by inhalation and meets the criteria for classification as an OSHA "select carcinogen." Chronic exposure to HMPA can cause damage to the lungs and kidneys. Reproductive effects in male animals treated with hexamethylphosphoramide have been observed. HMPA should be regarded as a substance with poor warning properties.

火災危険

Combustible liquid. Its decomposition at high temperatures or in a fire can produce phosphine, phosphorus oxides, and oxides of nitrogen, which are extremely toxic. Carbon dioxide or dry chemical extinguishers should be used for HMPA fires.

火災危険

Hexamethylphosphoramide is combustible.

職業ばく露

Hexamethylphosphoric triamide is a material possessing unique properties and is widely used as a solvent in small quantities, in organic and organometallic reactions in laboratories. This is the major source of occu pational exposure to HMPA in the United States. It is also used as a processing solvent in the manufacture of aramid fibers. HMPA has been evaluated for use as an ultraviolet light absorber or inhibitor in polyvinylchloride formulations; as an additive for antistatic effects; as a flame retardant; and as a deicing additive for jet fuels. Hexamethylphosphoric triamide has also been extensively investigated as an insect chemosterilant.

応急処置

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immedi ately with soap and water. Seek medical attention immedi ately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precau tions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quanti ties of water and induce vomiting. Do not make an uncon scious person vomit.

輸送方法

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required

純化方法

The industrial synthesis is usually by treatment of POCl3 with excess of dimethylamine in isopropyl ether. Impurities are water, dimethylamine and its hydrochloride. It is purified by refluxing over BaO or CaO at about 4mm pressure in an atmosphere of nitrogen for several hours, then distilled from sodium at the same pressure. The middle fraction (b ca 90o) is collected, refluxed over sodium under reduced pressure under nitrogen and distilled. It is kept in the dark under nitrogen, and stored in solid CO2. It can also be stored over 4A molecular sieves. Alternatively, it is distilled under vacuum from CaH2 at 60o and is crystallised twice in a cold room at 0o, seeding the liquid with crystals obtained by cooling in liquid nitrogen. After about two-thirds are frozen, the remaining liquid is drained off [Fujinaga et al. Pure Appl Chem 44 117 1975]. For tests of purity see Fujinaga et al. in Purification of Solvents, Coetzee Ed., Pergamon Press, Oxford, 1982. For efficiency of desiccants in drying HMPA see Burfield and Smithers [J Org Chem 43 3966 1978, Sammes et al. J Chem Soc, Faraday Trans 1 281 1986]. [Beilstein 4 IV 284.] CARCINOGEN.

不和合性

Incompatible (possibly violent reaction; fire and explosions) with oxidizers (chlorates, nitrates,peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.). Keep away from alkaline materials, chemi cally active metals, strong acids, strong bases.

用途

両極性溶媒、有機?無機金属化合物の反応や重合反応への応用、感材、加硫促進剤

ヘキサメチルりん酸トリアミド 上流と下流の製品情報

原材料

準備製品


ヘキサメチルりん酸トリアミド 生産企業

Global( 265)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Hangzhou Bayee Chemical Co., Ltd.
0086-571-86990109; 0086-18605816692
0086-571-85775919 rachelhoo@bayeechem.com China 99 55
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19958 60
Mainchem Co., Ltd.
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+86-0592-6210733 sales@mainchem.com CHINA 32764 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
Zhejiang ZETian Fine Chemicals Co. LTD
+86-18957127338
sales@zetchem.com CHINA 1259 58
Shanghai Record Pharmaceuticals Limited Company 86-21-62506791
86-21-63636419 record@recordpharm.com China 38 73
Chengdu HuaXia Chemical Reagent Co. Ltd 400-1166-196 QQ:800101999
028-84555506 QQ:800101999 cdhxsj@163.com China 9720 58
klamar reagent 4001650900
021-64897811 sales-wang@klamar-reagent.com China 1997 55
Jinan Taihua Chemical Co., Ltd. 13553165615
574737201@qq.com CHINA 12 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76

680-31-9(ヘキサメチルりん酸トリアミド)キーワード:


  • 680-31-9
  • TRIS(DIMETHYLAMINO)PHOSPHINE OXIDE
  • Eastman Inhibitor HPT
  • eastmaninhibitorhpt
  • ENT 50,882
  • ENT 50882
  • Hexmethylphosphoramide
  • HMPTA
  • HPT
  • Phosphoric acid hexamethyltriamide
  • Phosphoric hexamethyltriamide
  • Phosphoric triamide, hexamethyl-
  • Phosphoric Tris(dimethylamide)
  • phosphoricacidhexamethyltriamide
  • Phosphorictriamide,hexamethyl-
  • phosphorictris(dimethylamide)
  • Phosphoryl hexamethyltriamide
  • phosphorylhexamethyltriamide
  • Tri(dimethylamino)phosphineoxide
  • Tris-(dimethylamid) kyseliny fosforecne
  • tris-(dimethylamid)kyselinyfosforecne
  • HEXAMETHYL PHOSPHORAMID
  • Hexamethylphosphoriv triamid
  • N,N,N',N',N'',N''-Hexamethylphosphoric triamide, Tris(dimethylamino)phosphine oxide, HMPA
  • HEXANETHYLPHOSPHORAMIDE
  • hexamethylphosphoric triamide hexamethylphosphoramide
  • Hexamethylphosphoric acid triamide, HMPA, Tris(dimethylamino)phosphine oxide
  • Hexamethylphosphoramide,98%
  • Hexamethylphosphoramide,99%
  • Hexamethyl phosphoryl triamide ,99%
  • Hexamethylphosphoramide,HMPA, Hexamethylphosphoric acid triamide, Tris(dimethylamino)phosphine oxide
  • ヘキサメチルりん酸トリアミド
  • ヘキサメチルホスホリックトリアミド
  • ヘキサメチルオルトりん酸トリアミド
  • ヘキサメチルトリアミドホスファート
  • りん酸ヘキサメチルトリアミド
  • トリス(N,N-ジメチルアミノ)ホスフィンオキシド
  • イーストマンインヒビターHPT
  • ヘキサメタポール
  • ヘンパ
  • トリス(ジメチルアミノ)ホスフィンオキシド
  • ヘキサメチルホスホルアミド
  • ヘキサメチルホスホロトリアミド
  • トリ(ジメチルアミノ)ホスフィンオキシド
  • ホスホリルヘキサメチルトリアミド
  • N,N,N',N',N'',N''-ヘキサメチルりん酸トリアミド
  • ヘキサメチルホスホラミド
  • ヘキサメチルホスホルトリアミド
  • リン酸トリス(ジメチルアミド)
  • ヘキサメチルホスホルアミド STANDARD
  • 昆虫不妊剤
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