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酢酸フェニル水銀

酢酸フェニル水銀 化学構造式
62-38-4
CAS番号.
62-38-4
化学名:
酢酸フェニル水銀
别名:
酢酸フェニル水銀;PMA【殺菌剤】;ニメラート;酢酸フェニルメルクリオ(II);フェニル水銀(II)アセタート;アセトキシフェニル水銀(II);フェニル水銀(II)=アセタート;リキフェン;酢酸フェニル水銀(II);フィックス;ガロトックス;メルソリト;アセタト(フェニル)水銀( II );酢酸フェニル水;酢酸フェニル第二水銀;酢酸フェニル水銀(Ⅱ);(アセタト-κO)(フェニル)水銀;酢酸フェニル水銀 STANDARD;酢酸フェニル水銀 Standard, 100 µg/mL in MeOH;酢酸フェニル水銀, 98%
英語化学名:
PHENYLMERCURIC ACETATE
英語别名:
phix;pmas;bufen;femma;scutl;PMA(R);UNISAN;celmer;hl-331;riogen
CBNumber:
CB6703824
化学式:
C8H8HgO2
分子量:
336.74
MOL File:
62-38-4.mol

酢酸フェニル水銀 物理性質

融点 :
148-151 °C(lit.)
比重(密度) :
2,4 g/cm3
貯蔵温度 :
APPROX 4°C
溶解性:
Slightly soluble in water, soluble in acetone and in alcohol.
外見 :
Powder
色:
white
比重:
2.4
水溶解度 :
Soluble in alcohol, benzene and glacial acetic acid. Slightly soluble in water.
Merck :
14,7300
安定性::
Stable. Incompatible with strong oxidizing agents.
CAS データベース:
62-38-4(CAS DataBase Reference)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T,N
Rフレーズ  25-34-48/24/25-50/53
Sフレーズ  23-24/25-37-45-60-61
RIDADR  UN 1674 6.1/PG 2
WGK Germany  3
RTECS 番号 OV6475000
8
TSCA  Yes
国連危険物分類  6.1
容器等級  II
HSコード  28521000
化審法 9-1255
安衛法 57,57-2
PRTR法 第1種指定化学物質
毒劇物取締法 II
絵表示(GHS)
注意喚起語
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 P264, P270, P301+P310, P321, P330,P405, P501
H314 重篤な皮膚の薬傷?眼の損傷 皮膚腐食性/刺激性 1A, B, C 危険 P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 重篤な眼の損傷 眼に対する重篤な損傷性/眼刺激 性 1 危険 P280, P305+P351+P338, P310
H372 長期にわたる、または反復暴露により臓器の障 害 特定標的臓器有害性、単回暴露 1 危険 P260, P264, P270, P314, P501
H400 水生生物に強い毒性 水生環境有害性、急性毒性 1 警告 P273, P391, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P303+P361+P353 皮膚(または髪)に付着した場合:直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P405 施錠して保管すること。

酢酸フェニル水銀 価格

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入

酢酸フェニル水銀 化学特性,用途語,生産方法

用途

防カビ剤、殺菌剤

効能

抗菌性保存剤

化学的特性

white crystalline powder

化学的特性

Phenylmercury acetate is a white or yellow crystalline solid.

化学的特性

Phenylmercuric acetate occurs as a white to creamy white, odorless or almost odorless, crystalline powder or as small white prisms or leaflets.

使用

antiulcer

使用

Herbicide; fungicide.

調製方法

Phenylmercuric acetate is readily formed by heating benzene with mercuric acetate.

一般的な説明

Small lustrous prisms. Toxic by ingestion, inhalation and skin absorption. May severely irritate skin and eyes. Used as an herbicide and fungicide. as such, is mixed with organic solvent for the purpose of application.

反応プロフィール

PHENYLMERCURIC ACETATE may react with strong oxidizing agents .

健康ハザード

Extremely toxic. The probable oral lethal dose for humans is 5-50 mg/kg, between 7 drops and 1 teaspoonful for a 70 kg (150 lb.) person.

火災危険

Fire may produce irritating or poisonous gases. When heated to decomposition, very toxic mercuric fumes may be given off. Phenylmercuric ion is incompatible with halides, with which precipitates are formed.

応用例(製薬)

Phenylmercuric acetate is used as an alternative antimicrobial preservative to phenylmercuric borate or phenylmercuric nitrate in a limited range of cosmetics (in concentrations not exceeding 0.007% of mercury calculated as the metal) and pharmaceuticals. It may be used in preference to phenylmercuric nitrate owing to its greater solubility.
Phenylmercuric acetate is also used as a spermicide;

安全性プロファイル

Poison by ingestion, intravenous, intraperitoneal, subcutaneous, and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also MERCURY COMPOUNDS. When heated to decomposition it emits toxic fumes of Hg.

安全性

Phenylmercuric acetate is mainly used as an antimicrobial preservative in topical pharmaceutical formulations. A number of adverse reactions to mercury-containing preservatives have been reported; see Phenylmercuric Nitrate.
LD50 (chicken, oral): 60 mg/kg
LD50 (mouse, IP): 13 mg/kg
LD50 (mouse, IV): 18 mg/kg
LD50 (mouse, oral): 13 mg/kg
LD50 (mouse, SC): 12 mg/kg
LD50 (rat, oral): 41 mg/kg

職業ばく露

Phenylmercury acetate is used as an antiseptic, fungicide; for fungal and bacterial control; herbicide and control of crabgrass; mildewcide for paints; slimicide in paper mills. It was also used in contraceptive gels and foams.

貯蔵

As for other phenylmercuric salts; see Phenylmercuric Nitrate.
Phenylmercuric acetate should be stored in a well-closed container, protected from light, in a cool, dry place.

輸送方法

UN1674 Phenylmercuric acetate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

純化方法

It forms small colourless lustrous prisms from EtOH. Its solubility in H2O is 0.17%, but it is more soluble in EtOH, Me2CO and *C6H6. [Maynard J Am Chem Soc 46 1510 1925, Coleman et al. J Am Chem Soc 59 2703 1937, J Am Pharm Assoc 25 752 1936, Beilstein 16 IV 1720.] See PhHgOH below.

不和合性

A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, halogens.

不和合性

As for other phenylmercuric salts; see Phenylmercuric Nitrate.
Incompatible with: halides; anionic emulsifying agents and suspending agents; tragacanth; starch; talc; sodium metabisulfite; sodium thiosulfate; disodium edetate; silicates; aluminum and other metals; amino acids; ammonia and ammonium salts; sulfur compounds; rubber; and some plastics.
Phenylmercuric acetate is reported to be incompatible with cefuroxime and ceftazidime.

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. React to produce soluble nitrate form, precipitate as mercuric sulfide. Return to supplier.

規制状況(Regulatory Status)

Included in the FDA Inactive Ingredients Database (ophthalmic ointments; topical emulsions/creams; vaginal emulsions/creams). Included in the Canadian List of Acceptable Non-medicinal Ingredients (ophthalmic, nasal and otic preparations up to 0.004%; there must be no other suitable alternative preservative available).
Phenylmercuric acetate is no longer permitted to be used as a pesticide in the USA. Its use in cosmetic products in the USA is limited to eye area cosmetics at not more than 0.0065% provided that there is no other suitable available preservative. It is specifically prohibited in vaginal contraceptive drug products and antimicrobial diaper rash drug products in the USA. Phenylmercuric compounds are prohibited from use in cosmetic products in Canada.
In Europe, use in cosmetic products is limited to eye makeup and eye makeup remover at concentrations not exceeding 0.007% mercury alone or in combination with other permitted mercurial compounds.In France, a maximum concentration of 0.01% is permitted for use in pharmaceuticals. The use of mercurial compounds in cosmetics in Japan is limited to concentrated shampoo or cream at not more than 0.003% Hg and eye makeup at not more than 0.0065% Hg.

酢酸フェニル水銀 上流と下流の製品情報

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酢酸フェニル水銀 生産企業

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62-38-4(酢酸フェニル水銀)キーワード:


  • 62-38-4
  • GALLOTOX(R)
  • METASOL 30(R)
  • MERCURY PHENYL ACETATE
  • MERCURI PHENYL ACETATE
  • LABOTEST-BB LT00085754
  • LIQUIPHENE(R)
  • (ACETOXYMERCURI)BENZENE
  • ACETOXYPHENYLMERCURY
  • (ACETATO)PHENYL MERCURY
  • TAG HL-331(R)
  • TAC FUNGICIDE(R)
  • SCUTL(R)
  • RIOGEN(R)
  • NYLMERATE(R)
  • (acetato-o)phenyl-mercur
  • (Acetato-O)phenylmercury
  • (acetato-O)phenyl-Mercury
  • (aceto)phenyl-mercur
  • (acetoxymercuri)-benzen
  • PHIX(R)
  • PHENYLMERCURIC ACETATE
  • PHENYLMERCURY(II) ACETATE
  • PHENYLMERCURY(+2)ACETATE
  • PHENYLMERCURY ACETATE
  • PM ACETATE
  • PMAC(R)
  • PMA(R)
  • PMAS(R)
  • UNISAN
  • Sanmicron
  • 酢酸フェニル水銀
  • PMA【殺菌剤】
  • ニメラート
  • 酢酸フェニルメルクリオ(II)
  • フェニル水銀(II)アセタート
  • アセトキシフェニル水銀(II)
  • フェニル水銀(II)=アセタート
  • リキフェン
  • 酢酸フェニル水銀(II)
  • フィックス
  • ガロトックス
  • メルソリト
  • アセタト(フェニル)水銀( II )
  • 酢酸フェニル水
  • 酢酸フェニル第二水銀
  • 酢酸フェニル水銀(Ⅱ)
  • (アセタト-κO)(フェニル)水銀
  • 酢酸フェニル水銀 STANDARD
  • 酢酸フェニル水銀 Standard, 100 µg/mL in MeOH
  • 酢酸フェニル水銀, 98%
  • 構造分類
  • 金属別化合物
  • 遷移金属化合物
  • 水銀化合物
  • 除草剤
  • 抗真菌薬
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