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PHENYLMERCURIC ACETATE

PHENYLMERCURIC ACETATE
PHENYLMERCURIC ACETATE
CAS No.
62-38-4
Chemical Name:
PHENYLMERCURIC ACETATE
Synonyms
phix;pmas;bufen;femma;scutl;PMA(R);UNISAN;celmer;hl-331;riogen
CBNumber:
CB6703824
Molecular Formula:
C8H8HgO2
Formula Weight:
336.74
MOL File:
62-38-4.mol

PHENYLMERCURIC ACETATE Properties

Melting point:
148-151 °C(lit.)
Density 
2,4 g/cm3
storage temp. 
APPROX 4°C
solubility 
Slightly soluble in water, soluble in acetone and in alcohol.
form 
Powder
color 
white
Water Solubility 
Soluble in alcohol, benzene and glacial acetic acid. Slightly soluble in water.
Merck 
14,7300
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
62-38-4(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N
Risk Statements  25-34-48/24/25-50/53
Safety Statements  23-24/25-37-45-60-61
RIDADR  UN 1674 6.1/PG 2
WGK Germany  3
RTECS  OV6475000
8
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  28521000
Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

PHENYLMERCURIC ACETATE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar 037125 Phenylmercury acetate, 98% 62-38-4 10g $18.8 2018-11-16 Buy
Alfa Aesar 037125 Phenylmercury acetate, 98% 62-38-4 50g $45.4 2018-11-16 Buy
Strem Chemicals 93-8025 Phenylmercury acetate, 97.5% 62-38-4 50g $79 2018-11-13 Buy
Strem Chemicals 93-8025 Phenylmercury acetate, 97.5% 62-38-4 250g $316 2018-11-13 Buy
Alfa Aesar 037125 Phenylmercury acetate, 98% 62-38-4 250g $178 2018-11-16 Buy

PHENYLMERCURIC ACETATE Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Chemical Properties

Phenylmercury acetate is a white or yellow crystalline solid.

Uses

antiulcer

Uses

Herbicide; fungicide.

General Description

Small lustrous prisms. Toxic by ingestion, inhalation and skin absorption. May severely irritate skin and eyes. Used as an herbicide and fungicide. as such, is mixed with organic solvent for the purpose of application.

Reactivity Profile

PHENYLMERCURIC ACETATE may react with strong oxidizing agents .

Health Hazard

Extremely toxic. The probable oral lethal dose for humans is 5-50 mg/kg, between 7 drops and 1 teaspoonful for a 70 kg (150 lb.) person.

Fire Hazard

Fire may produce irritating or poisonous gases. When heated to decomposition, very toxic mercuric fumes may be given off. Phenylmercuric ion is incompatible with halides, with which precipitates are formed.

Safety Profile

Poison by ingestion, intravenous, intraperitoneal, subcutaneous, and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also MERCURY COMPOUNDS. When heated to decomposition it emits toxic fumes of Hg.

Potential Exposure

Phenylmercury acetate is used as an antiseptic, fungicide; for fungal and bacterial control; herbicide and control of crabgrass; mildewcide for paints; slimicide in paper mills. It was also used in contraceptive gels and foams.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Keep victim quiet and maintain normal body temperature. Effects may be delayed; keep victim under observation.
Antidotes and Special Procedures for medical personnel: The drug NAP (n-acetyl penicillamine) has been used to treat mercury poisoning, with mixed success.

Shipping

UN1674 Phenylmercuric acetate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

It forms small colourless lustrous prisms from EtOH. Its solubility in H2O is 0.17%, but it is more soluble in EtOH, Me2CO and *C6H6. [Maynard J Am Chem Soc 46 1510 1925, Coleman et al. J Am Chem Soc 59 2703 1937, J Am Pharm Assoc 25 752 1936, Beilstein 16 IV 1720.] See PhHgOH below.

Incompatibilities

A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, halogens.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. React to produce soluble nitrate form, precipitate as mercuric sulfide. Return to supplier.

PHENYLMERCURIC ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products


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