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아족시스트로빈

아족시스트로빈
아족시스트로빈 구조식 이미지
카스 번호:
131860-33-8
한글명:
아족시스트로빈
동의어(한글):
아족시스트로빈
상품명:
Azoxystrobin
동의어(영문):
Abound;QUADRIS;AMISTAR;HERITAGE;ICI A5504;AZOXYSTROBIN;pyroxystrobin;AZOXYSTROBIN, TC 95%;Azoxystrobin (free acid);AZOXYSTROBIN PESTANAL, 100 MG
CBNumber:
CB2189631
분자식:
C22H17N3O5
포뮬러 무게:
403.39
MOL 파일:
131860-33-8.mol

아족시스트로빈 속성

녹는점
118-119°
밀도
1.33
증기압
1.1 x 10-10 Pa (25 °C)
저장 조건
0-6°C
수용성
6 mg l-1 (20 °C)
물리적 상태
neat
색상 색인 번호
23860
InChIKey
WFDXOXNFNRHQEC-GHRIWEEISA-N
CAS 데이터베이스
131860-33-8(CAS DataBase Reference)
NIST
Azoxystrobin(131860-33-8)
EPA
Benzeneacetic acid, 2-[[6-(2-cyanophenoxy)-4-pyrimidinyl] oxy]-.alpha.-(methoxymethylene)-, methyl ester, (.alpha.E)-(131860-33-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T;N,N,T
위험 카페고리 넘버 23-50/53
안전지침서 22-45-60-61
유엔번호(UN No.) UN 2811
WGK 독일 2
유해 물질 데이터 131860-33-8(Hazardous Substances Data)
독성 LD50 in rats (mg/kg): >5000 orally; >2000 dermally (Godwin)
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P311 의료기관(의사)의 진찰을 받으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

아족시스트로빈 MSDS


Azoxystrobin

아족시스트로빈 C화학적 특성, 용도, 생산

화학적 성질

White to beige crystalline solid or powder.

용도

Strobilurin fungicide; inhibits mitochondrial respiration by blocking electron transfer between cytochromes b and c1. Agricultural fungicide.

용도

Agricultural fungicide.

용도

Azoxystrobin has a very broad spectrum of activity and is active against fungal pathogens from all four taxonomic groups, the Oomycetes, Ascomycetes, Deuteromycetes and Basidiomycetes. It controls diseases on cereals, rice, vines, apples, peaches, bananas, citrus, curcurbits, potatoes, tomatoes, peanuts, coffee and turf.

정의

ChEBI: An aryloxypyrimidine having a 4,6-diphenoxypyrimidine skeleton in which one of the phenyl rings is cyano-substituted at C-2 and the other carries a 2-methoxy-1-(methoxycarbonyl)vinyl substituent, also at C-2. An inhibitor of mitochondrial respiration by b ocking electron transfer between cytochromes b and c1, it is used widely as a fungicide in agriculture.

위험도

Moderately toxic by inhalation.

농업용

Fungicide: Azoxystrobin has been processed as a Reduced Risk pesticide for Turf uses. Azoxystrobin is a systemic, broad-spectrum fungicide that was first introduced in 1998. It inhibits spore germination and is used on grape vines, cereals, potatoes, apples, bananas, citrus, tomatoes and other crops. Largest crop uses in California are on almonds, rice, pistachios, wine grapes, raisins and garlic. Among the diseases it controls are rusts, downey and powdery mildew, rice blast and apple scab. A U.S. EPA restricted Use Pesticide (RUP)

상품명

ABOUND®; AMISTAR®; AMISTAR OPTI; AMISTAR PRO; BANKIT®; HERITAGE®; ICIA5504 80WG®; OLYMPUS®; ORTIVA®; PROTEGE®; PROTEGE-ALLEGIANCE WP®;PROTEGE-FL SEED APPLIED FUNGICIDE®; QUADRIS OPTI®; QUILT®; SOYGARD WITH PROTEGE®

잠재적 노출

A β-methyoxyacrylate, Strobilurin is an agricultural fungicide.

신진 대사 경로

Azoxystrobin is a recently developed fungicide with a novel mode of action (see Overview for relevant references). It was first registered in 1996. It has been and is being subjected to the full range of studies to meet current regulatory requirements for toxicology, metabolism and environmental fate. Information on its metabolism and environmental fate was presented as a lecture at the 9th International Congress of Pesticide Chemistry (IUPAC) in 1998 and this will be published in the Proceedings. The information presented below is derived from this source (Joseph, 1998).
Azoxystrobin is a carboxylic acid methyl ester and one of its pathways of metabolism is via hydrolysis to its carboxylic acid. The latter is not biologically active (see Overview) and the favourable selective toxicity of the fungicide is due to this and other metabolic reactions in non-target species. Azoxystrobin is readily degraded in soil and ultimately mineralised and it is metabolised in plants and animals. Metabolism is complex because the molecule possesses several functional groups. Five different pathways have been identified in plants and animals. Biotransformations occurring on the parent molecule include hydrolysis, aromatic hydroxylation, cleavage of both phenoxy linkages, nitrile to amide hydrolysis and fragmentation of the acrylate double bond. Some photo-induced changes also occur, including conversion to the (Z)-isomer.

운송 방법

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Degradation

Azoxystrobin is degraded under conditions of aqueous photolysis with a DT50 of 11-17 days (PM).
Soil surface photolysis of azoxystrobin (14C-labelled separately in each of the three rings) was studied on a sandy loam for a period of 30 days. The fungicide was degraded with a DT50 measured as a mean of the three radiolabels, of 11 days in natural summer sunlight. The degradation was complex, affording many initial products, all at 40% of the applied radiocarbon. These products were themselves readily photolysed and no product accumulated during the course of the experiment. The yield of 14CO2 in 30 days was between 17% (phenylacrylate label) and 29% (cyanophenyl label). Thus soil surface photodegradation is likely to be an important mechanism for the removal of azoxystrobin from the environment.

비 호환성

Combustible; dust may form explosive with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

폐기물 처리

Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Dispose of contents and container to an approved waste disposal plant. Use a licensed professional waste disposal service to dispose of this material. Ultimate disposal of the chemical, product, and waste containers must consider: the material’s impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with public health, local, state, and federal health and environmental regulations. Never reuse or recycle used product containers unless the recycling program specifically accepts pesticide containers and you follow the program’s instructions for preparing the empty containers for collection

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원자재

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