피콜리아민
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피콜리아민 속성
- 녹는점
- −21 °C(lit.)
- 끓는 점
- 73-74 °C1 mm Hg(lit.)
- 밀도
- 1.062 g/mL at 25 °C(lit.)
- 굴절률
- n
20/D 1.551(lit.)
- 인화점
- 213 °F
- 저장 조건
- Keep in dark place,Sealed in dry,Room Temperature
- 용해도
- soluble in Chloroform, Ethyl Acetate, Methanol
- 물리적 상태
- 투명한 액체
- 산도 계수 (pKa)
- 8.34±0.29(Predicted)
- 색상
- 무색~연황색
- 수소이온지수(pH)
- 11-12 (100g/l, H2O, 20℃)
- 수용성
- 자유롭게 용해되는
- 감도
- Air Sensitive
- BRN
- 108056
- Henry's Law Constant
- 4.3×102 mol/(m3Pa) at 25℃, Du et al. (2017)
- InChI
- 1S/C6H8N2/c7-4-6-2-1-3-8-5-6/h1-3,5H,4,7H2
- InChIKey
- HDOUGSFASVGDCS-UHFFFAOYSA-N
- SMILES
- NCc1cccnc1
- CAS 데이터베이스
- 3731-52-0(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | C,Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 34-37-36/37/38 | ||
| 안전지침서 | 26-36/37/39-45-25-36 | ||
| 유엔번호(UN No.) | UN 2735 8/PG 2 | ||
| WGK 독일 | 3 | ||
| 위험 참고 사항 | Irritant | ||
| TSCA | TSCA listed | ||
| 위험 등급 | 8 | ||
| 포장분류 | III | ||
| HS 번호 | 29333999 | ||
| 스토리지 클래스 | 8A - Combustible corrosive hazardous materials | ||
| Hazard Classifications | Eye Dam. 1 Met. Corr. 1 Skin Corr. 1B |
피콜리아민 C화학적 특성, 용도, 생산
화학적 성질
CLEAR COLOURLESS TO SLIGHLY YELLOW LIQUIDSynthesis
Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts. A natural product inspired rapid access of 3-(aminomethyl)pyridine by one-pot reaction of 1-amidopyridin-1-ium salt with aminal followed by reductive cleavage of the N–N bond is developed. This C3-selective formal C–H activation of pyridine features a traceless umpolung of the 1-amidopyridin-1-ium salt toward a Mannich type C–C bond formation of the in situ generated 1-amido-2-dialkylamino-1,2-dihydropyridine intermediate[1].피콜리아민 준비 용품 및 원자재
원자재
수소화 리튬알미늄
3-시아노피린딘
3-피리딘메탄올
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
암모니아(가스)
9,9- 디메틸 -4,5- 비스 (디 페닐 포스 피노) 크 산텐
삼차-아밀알코올
준비 용품
피리미닐
3-Pyridinemethanamine 1-oxide
3-(아미노메틸)-1-메틸피페리딘
3-N-Boc-아미노메틸피페리딘
1,3-Dioxo-2-pyridin-3-ylmethyl-2,3-dihydro-1H-isoindole-5-carboxylic acid
2-시아노-N-(3-피리디닐메틸)아세트아미드
(4-브로모-벤질)-피리딘-3-일메틸-아민
4-nitro-N-(pyridin-3-ylmethyl)benzenesulfonamide
Methyl 3-[(3-pyridinylmethyl)amino]propanoate
2-Bromo-4-methyl-N-(pyridin-3-ylmethyl)thiazole-5-carboxamide
4-(프로프-2-이닐라미노)-N-(피리딘-3-일메틸)벤자미드
피콜리아민 공급 업체
글로벌( 403)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Weifang Siyuan Chemical Co., Ltd. | 0536-8888106 17663601818 |
2354379876@qq.com | China | 244 | 58 |
| Changzhou Jintan Maosheng Chemical Plant | 13382827140 |
maoshengchem@126.com | China | 70 | 58 |
| Hunan Daolin Biotechnology Co. , Ltd. | 18974846212 |
1876969603@qq.com | China | 57 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 |
jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 |
market03@meryer.com | China | 40202 | 62 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 18930552037 |
3bsc@sina.com | China | 15813 | 69 |
| Alfa Aesar | 400-6106006 |
saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 |
Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 |
sales.bj@hwrkchemical.com | China | 9409 | 55 |
| Energy Chemical | 400-0056266 18918157536; |
sales8178@energy-chemical.com | China | 45000 | 61 |