몰리브덴산 암모늄

몰리브덴산 암모늄
몰리브덴산 암모늄 구조식 이미지
카스 번호:
13106-76-8
한글명:
몰리브덴산 암모늄
동의어(한글):
몰리브덴산암모늄;몰리브데이트(MoO42-),암모늄(1:2),(T-4)-;몰리브덴산암모늄;다이암모늄 몰리브데이트;다이암모늄 몰리브데이트 ((NH4)2MoO4);다이암모늄 테트라옥소몰리브데이트(2-);몰리브데이트 (MoO42-), 다이암모늄, (T-4)-;몰리브데이트 (MoO42-), 암모늄 (1:2), (T-4)-;몰리브드산 (H2MoO4), 다이암모늄 염;몰리브드산, 다이암모늄 염;암모늄 몰리브데이트;암모늄 몰리브데이트 [(NH4)2MoO4];암모늄 몰리브데이트(VI)
상품명:
Ammonium molybdate
동의어(영문):
AMMONIUN MOLYBDATE;Ammonium orthomolybdate;molybdicacid,diammoniumsalt;AMMoniuM Molybdate 99.98% trace Metals basis;ybdate;AMMONIUM MOLYBDATE;AMMONIUM MOLYBDATE;AMMONIUM MOLYBDATE;AMMONIUM MOLYBDATE;AMMONIUM MOLYBDATE
CBNumber:
CB5309999
분자식:
H4MoNO4-
포뮬러 무게:
177.99
MOL 파일:
13106-76-8.mol
MSDS 파일:
SDS

몰리브덴산 암모늄 속성

밀도
2.498
저장 조건
Inert atmosphere,Room Temperature
용해도
에탄올: 불용성(lit.)
물리적 상태
가루
색상
하얀색
수용성
물, 산, 알칼리에는 용해되지만 알코올에는 용해되지 않습니다.
노출 한도
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 1000 mg/m3
CAS 데이터베이스
13106-76-8(CAS DataBase Reference)
EPA
Molybdate (MoO42-), ammonium (1:2), (T-4)- (13106-76-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36
WGK 독일 1
RTECS 번호 QA4900000
TSCA Yes
HS 번호 28417010
독성 LD50 orl-rat: 333 mg/kg 28ZLA8 -,214,61
기존화학 물질 KE-01707
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
1
2 0

몰리브덴산 암모늄 C화학적 특성, 용도, 생산

화학적 성질

Ammonium molybdate is a colorless, white or slightly greenish-yellow powder. It is used in chemical analysis for the determination of phosphorus. From a nitric acid solution it precipitates phosphorus in the form of ammonium phosphomolybdate having the formula (NH4)3PO4-12MoO3 after drying at 110 °C(230°F). Some of the phosphomolybdic acids are used as reagents for the alkaloids and in the analysis and separation of the alkali metals.

용도

Ammonium molybdate has been used to prepare phosphomolybdates. (NH4)2MoO4 was used as an analytical reagent for quantitative analysis of phosphates, silicates, arsenates and lead in their aqueous solutions. At saturated concentration, (NH4)2MoO4 was used to perform cryo-negative staining and as a negative stain in biological electron microscopy. Ammonium molybdate was used in study of crystallisation of cell-free-expressed membrane proteins.

생산 방법

Pure molybdic oxide (99.95% MoO3) is prepared by sublimation of technical oxide or by calcining ammonium molybdate. Metallic molybdenum powder is prepared commercially by hydrogen reduction of either pure molybdic oxide or ammonium molybdate in a two-step process.

정의

ChEBI: Ammonium molybdate is an ammonium salt composed of ammonium and molybdate ions in a 2:1 ratio. It has a role as a poison. It contains a molybdate.

일반 설명

Ammonium molybdate can be prepared by dissolving molybdenum trioxide in ammonia.

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by other routes. An irritant. See also MOLYBDENUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NH3 and NOx.

잠재적 노출

It is used as an analytical reagent, in pigments and in the production of molybdenum metal and ceramics.

운송 방법

There are no known UN/DOT restrictions.

Purification Methods

Crystallise the salt from water (2.5mL/g) by partial evaporation in a desiccator. [Sturdivant J Am Chem Soc 59 630 1937, Grüttner & Jauder in Handbook of Preparative Inorganic Chem (Ed. Brauer) Academic Press Vol II p 1711 1965.]

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides; chemically active metals (such as potassium, sodium, magnesium and zinc) may cause a violent reaction.

몰리브덴산 암모늄 준비 용품 및 원자재

원자재

준비 용품


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