눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405
밀봉하여 저장하시오.
P501
...에 내용물 / 용기를 폐기 하시오.
NFPA 704
1
2
0
1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE C화학적 특성, 용도, 생산
용도
1,3-Benzodithiolylium tetrafluoroborate may be used in the synthesis of the following:
Dibenzotetrathiafulvalene by reacting with 1,8-diazabicyclo[5.4.0]undec-7-ene.
Substituted arylcarbenium ions by reacting with boronic derivatives.
α-(1,3-benzodithiol-2-ylidene) ketones and 1,3-benzodithiole by reacting with ketones.
2-styryl-1,3-benzodithioles by reacting with styryl-type cobaloximes.
2-(3-indolyl)-1,3-benzodithiolylium tetrafluoroborate by reacting with indole.
2-(1,3-benzodithiol-2-ylidene)-3,5-cyclohexadien-1-ones and 4-(1,3-benzodithiol-2-ylidene)-2,5-cyclohexadien-1-ones by reacting with 2,4- and 2,6-disubstituted phenols.
일반 설명
1,3-Benzodithiolylium tetrafluoroborate is a carbenium ionic compound. It has been synthesized by reacting 1,3-benzodithiole with trityl tetrafluoroborate. It is widely used as an α-alkylating agent for the enantioselective α-alkylation of aldehydes., The nature of adsorption of 1,3-benzodithiolylium tetrafluoroborate on various carbon nanotubes (CNTs) has been studied. 1,3-Benzodithiolylium tetrafluoroborate reacts with different nucleophilic reagents at the 2-position to form the respective 1,3-benzodithioles.
1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE 준비 용품 및 원자재
