산화납(Ⅳ)
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산화납(Ⅳ) 속성
- 녹는점
- 290 °C
- 밀도
- 9,38 g/cm3
- 물리적 상태
- 가루
- Specific Gravity
- 9.38
- 색상
- 갈색에서 검정색으로
- 수용성
- 불용성
- Merck
- 14,5407
- crystal system
- Nogata
- Space group
- Pbcn
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.4948 0.5951 0.5497 90 90 90 0.1619
- 노출 한도
- ACGIH: TWA 0.05 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.050 mg/m3
- CAS 데이터베이스
- 1309-60-0(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | O,T,N | ||
---|---|---|---|
위험 카페고리 넘버 | 61-8-20/22-33-50/53-62 | ||
안전지침서 | 53-45-60-61 | ||
유엔번호(UN No.) | UN 1872 5.1/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | OG0700000 | ||
TSCA | Yes | ||
위험 등급 | 5.1 | ||
포장분류 | III | ||
HS 번호 | 28249090 | ||
유해 물질 데이터 | 1309-60-0(Hazardous Substances Data) | ||
독성 | LD50 i.p. in guinea pigs: 220 mg/kg (Venugopal, Luckey) | ||
기존화학 물질 | KE-21908 | ||
유해화학물질 필터링 | 97-1-9 | ||
중점관리물질 필터링 | 별표1-102 | ||
함량 및 규제정보 | 물질구분: 유독물질; 혼합물(제품)함량정보: 사산화납(lead tetraoxide), 황산납(lead sulfate), 염기성탄산납(basic lead carbonate)을 제외한 납화합물(Lead compounds) 및 이를 25% 이상 함유한 혼합물. 다만, 초산납(lead acetate), 알킬화납(lead alkyls), 아지드화납(lead azide), 이초산납(lead di(acetate)), 메탄술폰산납(lead(Ⅲ) methansulfonate), 인산납(lead phosphate(3:2)), 스티핀산납(lead styphate)의 경우는 이를 0.5% 이상 함유한 혼합물 |
산화납(Ⅳ) C화학적 특성, 용도, 생산
개요
Lead dioxide, PbO2, also plumbic oxide, is an odorless dark-brown crystalline powder which is nearly insoluble in water. It exists in two crystalline forms. The a phase has orthorhombic symmetry, lattice constants a=0.497 nm, b=0.596 nm, c= 0.544 nm, Z=4 (four formula units per unit cell).화학적 성질
Lead dioxide is a dark brown crystalline solid or powder.물리적 성질
Red tetragonal crystals or brown powder; density 9.64 g/cm3; decomposes on heating at 290°C; practically insoluble in water; also insoluble in alkalis; moderately soluble in hydrochloric acid and also, in nitric acid-hydrogen peroxide mixture; slowly dissolves in acetic acid.출처
Lead dioxide occurs in nature as the mineral plattnerite. It is used as an oxidizing agent in manufacturing dyes and intermediates. It also is used as a source of oxygen in matches, pyrotechnics, and explosives. In matches, the oxide is combined with amorphous phosphorus as an ignition surface. It also is used in making lead pigments, liquid polysulfide polymers and rubber substitutes. Lead dioxide electrodes are used in lead storage batteries in which lead dioxide accumulates on positive plates.용도
Lead dioxide occurs in nature as the mineral plattnerite. It is used as an oxidizing agent in manufacturing dyes and intermediates. It also is used as a source of oxygen in matches, pyrotechnics, and explosives. In matches, the oxide is combined with amorphous phosphorus as an ignition surface. It also is used in making lead pigments, liquid polysulfide polymers and rubber substitutes. Lead dioxide electrodes are used in lead storage batteries in which lead dioxide accumulates on positive plates.제조 방법
Lead dioxide is produced by oxidizing an alkaline slurry of lead monoxide with chlorine, sodium hypochlorite, or bleaching powder. Alternatively, it is obtained by passing chlorine into a hot aqueous suspension of lead sulfate and magnesium hydroxide. The ionic reaction is:Pb(OH)3ˉ +ClOˉ → PbO2 + Clˉ+ OHˉ + H2O
It also is produced by electrolysis of acidic solutions of lead salts using a lead or platinum electrode. In such electrolytic process, lead dioxide is deposited on the anode of the cell.
Insoluble powdered lead dioxide also may be obtained when lead tetroxide is heated with nitric acid:
Pb3 O4 + 4HNO3 → 2Pb(N)3)2 + PbO2 + 2H2O
Lead dioxide also can be prepared by fusing lead monoxide with a mixture of sodium nitrate and sodium chlorate.
일반 설명
Brown, hexagonal crystals. Insoluble in water. Used in matches, explosives, electrodes.반응 프로필
Noncombustible but accelerates the burning of combustible material. Reacts violently with hydrogen sulfide [Bretherick 1979. p. 977-978]. Ignites with hydroxylamine [Mellor 8:291. 1946-47]. Reacts violently with hydrogen peroxide [Mellor 1:937 1946-47], with phenylhydrazine [Mellor 7:637 1946-47], or with sulfuryl chloride [Mellor 10:676. 1946-47]. Reacts with incandescence with sulfur dioxide [Mellor, 1941, Vol. 7, 689]. Explodes when ground with boron or yellow phosphorus [Mellor, 1946, Vol. 5, 17]. Mixtures with sulfur and red phosphorus ignite [Mellor, 1941, Vol. 7, 689]. Reacts vigorously when heated with calcium sulfide, strontium sulfide or barium sulfide [Mellor, 1941, Vol. 3, 745].건강위험
Toxic by ingestion. Inhalation of dust is toxic. Fire may produce irritating, corrosive and/or toxic gases. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.화재위험
These substances will accelerate burning when involved in a fire. May explode from heat or contamination. Some may burn rapidly. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.잠재적 노출
This material is used in electrodes for lead-acid batteries; in matches; explosives, and as a curing agent for polysulfide elastomers운송 방법
UN1872 Lead dioxide, Hazard Class: 5.1; Labels: 5.1-Oxidizer.비 호환성
Lead dioxide is a powerful oxidizer. Violent reaction with many compounds, including reducing agents; chemically active metals; combustible materials, strong acids, alkaline earth sulfides, aluminum carbides, aluminum, amines, calcium sulfide, carbides, chlorine trifluoride, glycerin, hydrides, hydrochloric acid, hydrogen peroxide, hydrogen sulfide, hydroxylamine, magnesium, metal powders, metal sulfides, molybdenum, phenylhydrazine, phosphorous red/friction, phosphorous trichloride, silicon, sulfides, sulfur, sulfur dioxide, sulfur/friction, sulfuric acid, tungsten, hydrogen trisulfide폐기물 처리
Conversion to soluble salt, precipitation as sulfide and return to supplier. Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.산화납(Ⅳ) 준비 용품 및 원자재
원자재
준비 용품
산화납(Ⅳ) 공급 업체
글로벌( 233)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Shenyang Simchoice Chemical Co.,Ltd | +86-024-23769576 +86-15040101888 |
sales@simchoicechem.com | China | 255 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21667 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29888 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39916 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34571 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 |
eric@witopchemical.com | China | 23555 | 58 |
sgtlifesciences pvt ltd | +8617013299288 |
dj@sgtlifesciences.com | China | 12382 | 58 |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 |
1026@dideu.com | China | 8672 | 58 |
GLR Innovations | +91 9891111994 |
info@glrgroup.in | India | 4542 | 58 |